3,954 research outputs found

    Effect of electric load and dual atmosphere on the properties of an alkali containing diopside-based glass sealant for solid oxide cells

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    © 2019 Elsevier B.V. All rights reserved.A new alkali-containing diopside based glass-ceramic sealant for solid oxide cells was synthesized, characterized and tested. The composition was designed to match the coefficient of thermal expansion (CTE) of Crofer22APU interconnect. The sealant has a glass transition temperature of 600°C, a crystallization peak temperature of 850°C and a maximum shrinkage temperature of 700°C, thus suggesting effective densification prior to crystallization. The CTE of the glass-ceramic is 11.5 10-6 K-1, a value which is compatible with the CTE for Crofer22APU stainless steel. Crofer22APU/glass-ceramic/Crofer22APU joined samples were tested in simulated real-life operating conditions at 800°C in dual atmosphere under an applied voltage, monitoring the electrical resistivity. The effect of two different applied voltages (0.7V and 1.3V) was evaluated. A voltage of 1.3V led to a rapid decrease in the electrical resistivity during the test;such a drop was due to the formation of Cr2O3 “bridges” that connected the two Crofer22APU plates separated by the sealant. There was no decrease in the resistivity when a voltage of 0.7V was applied. Instead,resistivity value remained stable at around 105 Ω cm for the 100h test duration. The degradation mechanisms, due to both the alkali content and the applied voltage, are investigated and discussed.Peer reviewe

    Henri Temianka (Miscellaneous Items)

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    This collection contains material pertaining to the life, career, and activities of Henri Temianka, violin virtuoso, conductor, music teacher, and author. Materials include correspondence, concert programs and flyers, music scores, photographs, and books.https://digitalcommons.chapman.edu/temianka_ephemera/1170/thumbnail.jp

    Aging characterization of metals for exhaust systems

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    The mechanical characteristics of four materials used in automotive exhaust systems have been compared after an aging treatment to evaluate the combined effects of thermo-mechanical fatigue and corrosion. For this purpose, an experimental aging procedure has been developed. This procedure is composed of chemical, thermal and mechanical cycles, which are combined and repeated to simulate the actual operating conditions of automotive exhaust systems. Three austenitic steels (AISI 309, AISI 316Ti, and AISI 321) and a nickel-based alloy (Inconel 625) are tested. The results show that Inconel 625 and AISI 309 are less affected by the aging process than the other material

    The validation of the association between gene polymorphisms and the cytogenetic abnormalities frequency in the cohort of radiation facility employees

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    The results from the research into the association between polymorphisms of genes-candidates for individual radiosensitivity and the frequency and spectrum of cytogenetic abnormalities are analyzed. These polymorphisms have been previously identified in our microarray studies using “Cancer_SNP_Panel GT-17- 211” (“Illumina”, USA) in 2013. The study was conducted among Siberian Group of Chemical Enterprises healthy employees (n = 158) exposed to professional irradiation in a dose range of 100-300 mSv. We have found that 16 SNPs are associated with the frequency of dicentric and ring (the radiation exposure markers). We have found that 9 SNPs are confirmed to be associated with the frequency of dicentric (INSR rs1051690, TNKS rs33945943, CYP24A1 rs751087, GSK3B rs4624596, GSK3B rs4688046, GSK3B rs10934500, GSK3B rs1574154, GSK3B rs2873950, VCAM1 rs2392221) and 14 SNPs are confirmed to be associated with the frequency of ring (ESR1 rs488133, PIN1 rs889162, PIN1 rs2233679, CYP2С19 rs4986894, CYP24A1 rs751087, APAF1 rs2288729, MPDU1 rs4227, GSK3B rs4624596, GSK3B rs4688046, GSK3B rs10934500, GSK3B rs10934503, GSK3B rs1574154, GSK3B rs2873950, VCAM1 rs2392221)

    Ferro-metals processing can be hazardous to your health

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    Ferro-metals (or Ferro-alloys) are used in making steel, to add different characteristics to the steel. The ferro-metals are often in the form of rocks. The ferro-metals are produced by heating the ore of the needed additive with iron ore. This ferro-metal is then taken to a steel works, where it is used in the furnaces

    Mine closure of pit lakes as terminal sinks: best available practice when options are limited?

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    In an arid climate, pit lake evaporation rates can exceed influx rates, causing the lake to function as a hydraulic terminal sink, with water levels in the pit remaining below surrounding groundwater levels. We present case studies from Western Australia for two mines nearing closure. At the first site, modelling indicates that waste dump covers for the potentially acid forming (PAF) material would not be successful over the long term (1,000 years or more). The second site is a case study where PAF management is limited by the current waste rock dump location and suitable cover materials. Pit lake water balance modelling using Goldsim software indicated that both pit lakes would function as hydraulic terminal sinks if not backfilled above long-term equilibrium water levels. Poor water quality will likely develop as evapoconcentration increases contaminant concentrations, providing a potential threat to local wildlife. Even so, the best current opportunity to limit the risk of contaminant migration and protect regional groundwater environments may be to limit backfill and intentionally produce a terminal sink pit lake

    Energy-efficient casting processes

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    Metal casting is one of the most energy-intensive manufacturing processes that have developed along the evolution of mankind. Although nowadays its scientific and technological aspects are well established, in the context of future resource scarcity and environmental pollution pressures, new studies appear necessary to describe the “foundry of the future” where energy and material efficiency are of great importance to guarantee competitiveness alongside environmental protection. In this chapter, both managerial and technical good practices aimed at implementing energy-efficient casting processes are presented alongside a few examples. The “Small is Beautiful” philosophy is presented as a systematic approach towards energy resilient manufacturing and, potentially, sustainability in the long term. Thus, this chapter aims at providing an overview of the different aspects comprising the state of the art in the industry and examples of research themes in academia about energy-efficient casting processes
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