Simple Combustion Production and Characterization of Octahydro[60]fullerene with a Non-IPR C-60 Cage

1. Xiamen Univ, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China 2. Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 3. Xiamen Univ, Sch Life Sci, Xiamen 361005, Peoples R ChinaFor the first time an easier, operable combustion method is employed for the synthesis of non-IPR fullerene, and an octahydro[60)fullerene with a non-IPA C-60 cage (C-60 isomer C-#1809(60)) produced by combustion is isolated and characterized by MS, UV vis, IR, and NMR spectroscopies in combination with DFT calculations. This finding shows that, in addition to chlorine, hydrogen can be an ample cataloreactant for the production of non-IPR fullerene derivatives under such conditions as arc-burning and diffusion combustion.NSFC 20525103 20673088 20973137 20721001 20423002 21031004 973 projects 2007CB815301 2007CB81530

Combustion Synthesis and Electrochemical Properties of the Small Hydrofullerene C50H10

通讯作者地址: Xie, SY (通讯作者),Xiamen Univ, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 2. Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Peoples R China 3. Xiamen Univ, Sch Life Sci, Xiamen 361005, Peoples R China 电子邮件地址: [email protected]; [email protected] hydrofullerene C50H10 is synthesized by low-pressure benzeneoxygen diffusion combustion. The structure of C50H10 is identified through NMR, mass spectrometry, and IR and Raman spectroscopy as a D5h symmetric closed-cage molecule with five pairs of fused pentagons stabilized by ten hydrogen atoms. UV/Vis and fluorescence spectrometric analyses disclose its optical properties as comparable with those of its chloride cousin (C50Cl10). Cyclic and square-wave voltammograms reveal that the first reduction potential of C50H10 is more negative than that of C50Cl10 as well as C60, with implications for the utilization of C50H10 as a promising electron acceptor for photovoltaic applications.973 projects 2011CB935901 NSFC 21031004 21021061 2077310

Two I-h-symmetry-breaking C-60 isomers stabilized by chlorination

通讯作者地址: Xie, SY (通讯作者), Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 2. Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 电子邮件地址: [email protected] abiding surprise in fullerene science is that I-h-symmetric buckminsterfullerene C-60 (ref. 1) (I-h-C-60 or C-#1,812(60), the nomenclature specified by symmetry or by Fowler's spiral algorithm(2)) remains the sole C-60 species experimentally available. Setting it apart from the other 1,811 topological isomers (isobuckminsterfullerenes) is its exclusive conformity with the isolated-pentagon rule(3), which states that stable fullerenes have isolated pentagons. Although gas-phase existence of isobuckminsterfullerenes has long been suspected(4-7), synthetic efforts have yet to yield successful results. Here, we report the realization of two isobuckminsterfullerenes by means of chlorination of the respective C-2v-and C-s-symmetric C-60 cages. These chlorinated species, (C60Cl8)-C-#1,809(1) and (C60Cl12)-C-#1,804(2), were isolated in experimentally useful yields. Structural characterization by crystallography unambiguously established the unique pentagon-pentagon ring fusions. These distinct structural features are directly responsible for the regioselectivity observed in subsequent substitution of chlorines, and also render these unprecedented derivatives of C60 isomers important for resolving the long-standing puzzle of fullerene formation by the Stone-Wales transformation scheme(8-11).NNSF of China,20525103 ,20531050 ,20721001 , 20571062 ,20425312 973 Program 2007CB81530

Determination of Trace-amounts of Chloride ion in Acidic-Copper Plating Solution by Ion Chromatography

采用碳酸钡沉淀法去除酸性镀铜液中 SO42 -、Cu2 + 的干扰 ,建立用离子色谱法检测酸性镀铜液中微量氯离子的测定方法 ,在实际检测中表明该方法灵敏度高 ,结果准确In this paper, the quantitative method for trace amounts of chloride ion in acidiccopper plating solution by ion chromatography is described. The acidiccopper plating solution contains large amounts of SO 4 2- and Cu 2+ , and trace amounts of chloride ion and so on. To minimize the interfering by sulfate ion and to avoid the damage to anionseparator column by copper ion, a pretreatment using barium carbonate as precipitator is required. Samples were separated completely by this system. The experiment results indicate that the pretreatment method is successful and determination for chloride ion is sensitive and accurate.福建省自然科学基金资助项目!(D990 001);; 厦门大学自选课题基金资助项

大城市郊区农户要素投入特征及差异分析——以北京市平谷区为例

农户生产要素投入的方向和强度不仅反映了农户的经济行为特征,也在一定程度上决定了区域农业的发展方向。本文以北京市平谷区2003年的116个农户调查问卷为基础,对大城市郊区农户生产要素投入特征及其差异进行了分析。结果表明,由于预期收益不同,农户在各产业的劳动力投入数量、质量、物质投入水平和组合结构具有很大差异。在劳动力质量和数量投入方面,根据建立的劳动力质量投入模型进行计算,平谷区农户劳动力质量投入水平非农产业要高于农业产业,经济作物要高于大田作物,具体从高到低的顺序依次是非农产业、其他经济作物、畜牧业、菜地、果园、大田作物,同时劳动力从农业向非农产业、在农业内部从大田作物向经济作物转移的趋势明显;在农户物质投入水平和组合结构方面,资本投入水平从高到低的顺序是:果园、菜地、大田,要素投入组合结构从好到差的顺序是:菜地、果园、大田,两个排序中经济作物都要高于或好于大田作物。分析认为稳定市场预期对于大城市郊区农业的健康发展具有十分重要的意义

法兰攻丝高强度螺栓连接攻丝板牙体强度理论研究

与传统高强度螺栓连接不同,法兰攻丝高强度螺栓连接中因为攻丝板的存在易造成因攻丝板厚度不足导致的牙体弯剪破坏,使得连接强度显著降低。为此,基于能量强度理论和攻丝板的几何特征,研究了不同角度下攻丝板牙体的复合受力和破坏特征,提出了最不利受力状态下攻丝板牙体复合受力分析模型,建立了基于弯剪破坏的攻丝板牙体强度理论公式。为充分发挥法兰攻丝高强度螺栓受拉连接强度,提出了基于高强度螺栓颈缩破坏的最小攻丝板厚度公式。通过建立法兰攻丝高强度螺栓受拉连接的精细化有限元分析模型,研究了不同攻丝板厚度下M16和M20等常见高强度螺栓连接的破坏形态、峰值承载力及变形等参数,最终确定的最小攻丝板厚度分别为14 mm和18 mm,与理论公式计算结果基本吻合,验证了公式的正确性,可供实际工程应用参考