64 research outputs found
Economic Interdependence: the Causes of the Improvement of Relations Between China and its Neighbor Countries——An Empirical Study From 1981-2007
改革开放后中国与周边国家的关系在整体上为何提升?经过寻找理论工具,发现自由主义所持的经济相互依赖理论可能更适合解释这一现象。自由主义认为,相互依赖有助于减少和缓解国家间的冲突,增进国际和平。不过,经济相互依赖理论的研究,尤其是实证研究,只从经济相互依赖对冲突的影响这一维度来考虑,忽略了对合作的影响。而国家间的双边关系恰恰是由冲突与合作两方面共同构成,用传统的理论理解国家间双边关系仍然力有不逮。基于原来的缺陷,在原有的理论基础上,本文增加了经济相互依赖对合作的影响这一维度进行研究。以此为基础,提出并论证了三个理论命题:(1)经济相互依赖促进合作。(2)经济相互依赖抑制冲突。(3)经济相互依赖提升...Why the relationship between China and its neighboring countries has been improved overall since reform and opening-up? The theory of economic interdependence held by liberalism is better to explain this situation after we resort to theories. Liberalism holds that interdependence reduces the conflicts between two countries and promotes peace. The research of economic interdependence theory, especi...学位:法学博士院系专业:公共事务学院_政治学理论学号:1382013015370
Laser welding of superalloy K418 to 42CrMo steel
进行了K418高温合金和42CrMo钢的激光焊接实验,分别采用OM、SEM、XRD和EDS等手段分析了焊缝的金相组织和物相组成,评价了焊缝的显微硬度和拉伸强度。结果表明:焊缝主要由树枝状非平衡凝固的FeCrNiC(力固溶体组成,此外,还有少量细小、弥散的Ni_3Al(γ′)相、Laves颗粒和少量MC碳化物分布在树枝晶间区域。由于主要强化相γ′在激光辐照后的部分溶解和随后快速凝固的抑制作用,焊缝的硬度虽分布较均匀但低于母材。由于没有获得穿透的焊接接头,焊接接头的强度约只有母材的88.5%,焊缝的断裂机制是塑性和脆性断裂的混合机制。由于在焊缝中存在一些Laves颗粒,这促进了微裂纹和微孔的形成和扩展,降低了焊接接头的抗拉强度
Successive modification of polydentate complexes gives access to planar carbon-and nitrogen-based ligands
以碳和氮为键合原子的多齿螯合物是配合物家族中非常重要的一类。具有更高齿数的平面构型NC螯合物实例相对较少,代表性的例子为四齿金属碳卟啉类化合物,这类螯合物以其独特的结构和丰富的物理化学性质引起广泛关注。然而平面五齿、六齿的NC螯合物由于几何构型“拥挤”导致合成难度高,该工作从含三元环内金属卡宾结构的CCCC型碳龙配合物出发,利用经典有机反应(炔烃对金属卡宾的插入反应),成功地实现了CCCCN/NCCCN型平面五齿螯合物的合成。这一研究为高配位型螯合物的合成提供了新思路并为平面五齿螯合物家族添加新成员。特别是,这些高配位型螯合物在可见光和近红外区域均有较好的吸收,表现出良好的光声成像、光热转换及声动力学性能。
该研究工作在张弘教授指导下完成,第一作者为iChEM博士后周小茜。该工作充分体现了多学科协同研究优势:相关化合物的合成、表征及理论计算工作由周小茜博士完成;声动力学性能研究由厦门大学公共卫生学院庞鑫博士及刘刚教授完成;光声成像研究由厦门大学公共卫生学院聂立铭教授完成。iChEM fellow卓庆德博士、博士生卓凯玥、陈志昕参与了部分实验工作。夏海平教授、香港科技大学林振阳教授和南京大学朱从青教授对研究工作给予了大力支持。【Abstract】Polydentate complexes containing combinations of nitrogen and carbon (N and C) ligating atoms are among the most fundamental and ubiquitous molecules in coordination chemistry, yet the formation of such complexes with planar high-coordinate N/C sites remains challenging. Herein, we demonstrate an efficient route to access related complexes with tetradentate CCCN and pentadentate CCCCN and NCCCN cores by successive modification of the coordinating atoms in complexes with a CCCC core. Combined experimental and computational studies reveal that the rich reactivity of metal-carbon bonds and the inherent aromaticity of the metallacyclic skeletons play key roles in these transformations. This strategy addresses the paucity of synthetic approaches to mixed N/C planar pentadentate chelating species and provides valuable insights into the synthesis of carbon-based high-coordinate complexes. Furthermore, the resulting complexes are the examples of organometallic species with combined photoacoustic, photothermal, and sonodynamic properties, which makes them promising for application in related areas.This research was supported by the National Natural Science Foundation of China (Nos. 21572185, 21561162001, and 81571744), the Research Grants Council of Hong Kong (N_HKUST603/15), the Excellent Youth Foundation of Fujian Scientific Committee (2018J06024), and the Fundamental Research Funds for the Central Universities (20720170065).该工作得到国家自然科学基金委、香港研究资助局、福建省自然科学基金、厦门大学校长基金的资助
Microscopic Characteristic Analysis and Crack Suppression of Laser-Surface Remelting of Vermicular-Graphite Cast-Iron Valve Seats
Influence of Laser Scanning Speed on Structure Evolution and Performance of Melted Magnesium Alloy
Effects of Scanning Speed on Microstructure and Performances of Laser Direct Metal Deposition Airport Oil Pipeline Network Materials
Microstructure and mechanical properties of K418 and 42CrMo dissimilar metal laser welding
试验研究了额定功率为3kW的连续波Nd:YAG激光焊接热输入对激光焊接K418与42CrMo异种金属焊缝形貌的影响。通过光学显微镜、扫描电镜、能谱分析仪、硬度仪、万能试验机及X衍射对激光焊接K418与42CrMo异种金属焊缝接头组织、元素分布、相组成及接头的力学性能进行分析。结果表明,在焊接热输入恒定的条件下,高功率、高焊速的匙孔焊接比低功率、低焊速的热传导焊接更能增加焊缝熔深。通过扫描电镜在焊缝区域观察到了颗粒状物和针状物,能谱分析表明,颗粒状物Nb,Ti,Mo元素聚集,Fe,Ni元素减少;针状物Ti,Nb元素聚集。K418与42CrMo异种金属激光焊接工艺参数优化后的焊缝抗拉强度高于42CrMo母材
Numerical Simulation of Stress Field of Laser Phase Transformation Hardening Vermicular Graphite Cast Iron Based on Beam Discretization
K418与42CrMo异种金属激光深熔焊接
研究了连续波Nd:YAG激光焊接功率、速度、离焦量和侧吹保护气流量对激光深熔焊接K418与42CrMo异种金属焊缝形貌、焊缝熔深的影响,讨论了焊缝区热裂纹产生机制。结果表明,额定功率为3kW的Nd:YAG激光深熔焊接K418与42CrMo异种金属,由于它们的物理化学性质的差异,焊缝靠近42CrMo侧易出现未熔合;激光光斑向42CrMo侧偏移可以减少焊缝靠近42CrMo侧未熔合量;通过优化侧吹保护气流量和离焦量可以增加熔深。由于K418液态金属的流动性差,导致焊缝靠近K418侧对流传热不充分,使焊缝靠近K418侧熔合线呈现锯齿形。焊缝区热裂纹的产生主要是由于焊缝区元素偏析形成的低熔物导致
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