684 research outputs found
Effect of ZnF2 Coating on Performance of LiNi0.5Mn1.5O4 Cathode Material for Lithium-ion Batteries
采用溶胶-凝胶法制备了LiNi0.5Mn1.5O4正极材料,并利用Zn F2对其表面进行包覆改性。XRD、SEM和TEM测试表明,包覆处理不影响材料的晶体结构,2%(质量分数,以LiNi0.5Mn1.5O4质量计,下同)的Zn F2在LiNi0.5Mn1.5O4表面形成了约7 nm厚均匀包覆层。对未包覆的LiNi0.5Mn1.5O4和1%、2%、3%的Zn F2包覆后的LiNi0.5Mn1.5O4的电化学性能进行了考察,发现Zn F2包覆能够减弱电解液与LiNi0.5Mn1.5O4正极材料之间的相互作用,稳定电极表面,提高材料的电化学性能。其中,2%Zn F2包覆样品表现出最佳的循环性能和倍率性能,0.2C电流倍率下循环200圈后,其放电比容量维持在109.0 m A·h/g,保持率为79.7%;5 C电流倍率下循环500圈后,放电比容量维持在94.2 m A·h/g,保持率为85.6%
EFFECT OF STRUCTURAL RELAXATION ON THE DEFORMATION BEHAVIOR OF A Zr64.13Cu15.75Ni10.12Al10 BULK METALLIC GLASS UNDER NANOINDENTATION
Structural relaxation by isothermal annealing below the glass transition temperature is conducted on a Zr64.13Cu15.75Ni10.12Al10 bulk metallic glass. The effect of structural relaxation on thermal and mechanical properties was investigated by differential scanning calorimetry and instrumented nanoindentation. The recovery of the enthalpy in the DSC curves indicates that thermally unstable defects were annihilated through structural relaxation. During nanoindentation, the structural relaxation did not have a significant influence on the serrated plastic flow behavior. However, Structural relaxation shows an obvious effect in increasing both the hardness and elastic modulus, which is attributed to the annihilation of thermally unstable defects that resulted from the relaxation
Effect of ZnO on Cu/ZnO/Al_2O_3 catalysts for methanol synthesis
[中文文摘]用高速碰撞共沉淀法制备m(CuO) /m(ZnO) /m(Al2 O3 )比分别为 60 /3 0 /1 0和 3 0 /60 /1 0的 1 #和 2 #催化剂 ,结果表明高ZnO的 2 #催化剂活性较好 ,分散度较大。XPS测试表明 2 #催化剂表面ZnO吸附的中间体 (CHx 或CHxO)较多且表面的Cu+1浓度较高 ,从而促进CO加氢合成甲醇的活性。[英文文摘]Cu/ZnO/Al_2O_3 catalysts with ratios of 60/30/10 and 30/60/10 have been prepared by high speed collision coprecipitation method. The performance of the catalyst with the higher ZnO content shows the higher activity in methanol synthesis. The characterization results indicated that the catalyst with the higher ZnO content has higher dispersion. On the surface of the higher ZnO content catalyst, there was more Cu+1 and more intermediate (CH_x and CH_xO) adsorpted. It is beneficial for the CO hydrogenating to produce methanol
某工程桩基质量问题的一种处理方法
据统计,国内灌注桩施工中桩身出现质量缺陷的概率达20%。一旦发生桩基质量事故,应及时进行事故原因分析评判,对事故进行处理,以保证建筑物的正常使用,并尽量减少经济损失。通过对一起桩基事故的分析和处理,说明其处理的方法及其原理,为今后相关处理提供经验借鉴
基于EESM的车载网络仿真建模
车载自组织网(VAnET)作为智能交通系统的重要技术,受到越来越多的关注,本文提出一个新的基于指数有效SInr映射(EESM)的车载网络仿真平台,仿真结果表明,新的建模能够精确再现链路级误包率性能,比传统平台有更高的精确度
砌体防倒塌钢桁架加固方法研究
上世纪后30年,我国建造了大量砌体结构,而现用中小学校舍占有其中相当的比例。对于砌体结构的改造与加固在现时代仍具有十分重要的意义。本文提出了一种利用钢桁架对砌体结构进行防倒塌加固的方法,包括计算假定以及设计理论,并且给出了该加固方法的设计流程。分析表明,防倒塌钢桁架加固方法,在提高结构系统的安全储备方面可以发挥重要作用,是一种经济可行的对砌体结构加固的新方法
雷帕霉素对血管平滑肌细胞增殖影响的实验研究
【目的】观察雷帕霉素(rapamycin)对体外培养的大鼠胸主动脉平滑肌细胞(SMC)增殖的作用。【方法】组织贴块法体外原代培养大鼠胸主动脉平滑肌细胞,取对数生长期细胞(第6-10代)用作实验,MTr法检测不同浓度雷帕霉素对平滑肌细胞增殖的效果,并用RT-PCR法检测其对平滑肌细胞增殖细胞核抗原(proliferating cell nuclear antigen,PCNA)mRNA表达情况的影响。【结果】①MTT法检测显示雷帕霉素呈剂量依赖性抑制体外培养的大鼠平滑肌细胞增殖,各组吸光值似)分别为:对照组0.902±0.106;0.1ng/mL组0.873±0.079;1ng/mL组0.797±0.046;10ng/mL组0.692±0.061;100ng/mL组0.624±0.075。方差分析差异有显著性。F=28.85,P〈0.001;两两比较1ng/mL以上浓度组与对照组间差异均有显著性,不同浓度间差异显著。0.1ng/mL组与对照组相比差异无显著性。②RT-PCR显示雷帕霉素以浓度依赖模式抑制大鼠平滑肌细胞PCNA-mRNA合成。各组校正后光密度值分别为:对照组219.35±7.20;0.1ng/mL组212.39±6.56;1ng/mL组113.15±10.09;10ng/mL组97.17±12.25;100ng/mL组84.38±8.66。方差分析F=195.49,P〈0.001。两两比较与MTT检测相同。【结论】雷帕霉素呈剂量依赖性显著抑制大鼠平滑肌细胞的增殖,1ng/mL时即可明显起效。雷帕霉素有望成为治疗内支架术后再狭窄的理想药物之一
Environmental economic policy designed to control watershed agricultural non-point pollution——A case study from Jiulong River Watershed of Fujian Province
阐述了环境经济手段在我国农业非点源污染控制中应用的必要性和可行性。并结合福建省九龙江流域农业非点源污染的主要问题,提出“畜禽养殖税(费)、排污权交易,化肥和农药施用税(费)、补贴、促险,退耕补贴、水保押金,流域共同治理基金、排污配额交易”等环境经济手段及其应用形式,并分析论证了其实施后的费用效果和可行性。
【英文摘要】 The necessity and feasibility of special environmental economic policies to control agricultural non-point source pollution were briefly analyzed.Facing serious non-point pollution in Jiulong River,several kinds and formats of economic policies were put forward,i.e.feeding taxes,emission taxes,and tradable permits on livestock and poultry;taxes,charges,subsidies and insurance of using fertilizer and pesticide;subsidies of quitting cultivation and deposits for soil and water conservation;funds and tradable p...“十五”福建省重大科技攻关项目(2002H009);; 福建省发展与计划委员会项目(2003)资
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