Study on the antibacterial performance of perovskite LaCoO_3 under visible light illumination

作者简介: 吴维维(1987 ~ ),女, 本科,主要研究方向为抗菌材料。联系人: 贾立山( 1964 ~ ), 男, 博士, 副教授, 主要研究方向为光催化材料。[中文文摘]采用柠檬酸配合法制备纳米钙钛矿型LaCoO3及Sr掺杂的La0.9Sr0.1CoO3。在可见光下考察了催化剂浓度、菌液浓度对LaCoO3杀菌性能的影响。结果表明,在以30W日光灯为光源,距光源20cm处,辐照30min时,当菌液浓度为102～104cfu/mL,对大肠杆菌的杀菌率达90%以上,金黄色葡萄球菌46%。Sr掺杂后La0.9Sr0.1CoO3杀菌率分别可达98%,52%。通过XRD、SEM、DRS表征分析表明,催化剂粒径为60～80nm,在大于400nm的可见光区均有较好的吸收,Sr掺杂有助于提高杀菌效果。通过溶胶提拉法在瓷砖上附着钙钛矿膜,膜表面的杀菌率仍可保持在80%,40%以上。[英文文摘]Perovskite LaCoO3 and La0.9Sr0.1CoO3 were prepared by citrate complex method. Under the visible light,the influence of the photocatalysis activity was studied to some factors,such as the amount of catalyst,the strength of bacterial. The result showed that when the concentration of bacteria was 102-104cfu/ml and the intensity of illumination was 30W (20 cm away from the lamp),the bactericidal rate to E.coli was over 90%,while 46% to Staphylococcus aureus. Even when Sr doped the bactericidal rate of La0.9Sr0.1 CoO3 was able to reach 95% , 52%. The XRD、SEM、DRS were adopted to characterize the catalysts,which showed that they both had perovsk ite-sype and the diameter of the particle were 60~ 80 nm. Whats' more they had good absorption of the wavelength of visiblelight greater than 400 nm, especially La0.9 Sr0.1 CoO3.福建省科技计划项目(2005Y21022); 厦门大学创新实验计划项目支

Study on the antibacterial performance of perovskite LaCoO_3 under visible light illumination

作者简介: 吴维维(1987 ~ ),女, 本科,主要研究方向为抗菌材料。联系人: 贾立山( 1964 ~ ), 男, 博士, 副教授, 主要研究方向为光催化材料。[中文文摘]采用柠檬酸配合法制备纳米钙钛矿型LaCoO3及Sr掺杂的La0.9Sr0.1CoO3。在可见光下考察了催化剂浓度、菌液浓度对LaCoO3杀菌性能的影响。结果表明,在以30W日光灯为光源,距光源20cm处,辐照30min时,当菌液浓度为102～104cfu/mL,对大肠杆菌的杀菌率达90%以上,金黄色葡萄球菌46%。Sr掺杂后La0.9Sr0.1CoO3杀菌率分别可达98%,52%。通过XRD、SEM、DRS表征分析表明,催化剂粒径为60～80nm,在大于400nm的可见光区均有较好的吸收,Sr掺杂有助于提高杀菌效果。通过溶胶提拉法在瓷砖上附着钙钛矿膜,膜表面的杀菌率仍可保持在80%,40%以上。[英文文摘]Perovskite LaCoO3 and La0.9Sr0.1CoO3 were prepared by citrate complex method. Under the visible light,the influence of the photocatalysis activity was studied to some factors,such as the amount of catalyst,the strength of bacterial. The result showed that when the concentration of bacteria was 102-104cfu/ml and the intensity of illumination was 30W (20 cm away from the lamp),the bactericidal rate to E.coli was over 90%,while 46% to Staphylococcus aureus. Even when Sr doped the bactericidal rate of La0.9Sr0.1 CoO3 was able to reach 95% , 52%. The XRD、SEM、DRS were adopted to characterize the catalysts,which showed that they both had perovsk ite-sype and the diameter of the particle were 60~ 80 nm. Whats' more they had good absorption of the wavelength of visiblelight greater than 400 nm, especially La0.9 Sr0.1 CoO3.福建省科技计划项目(2005Y21022); 厦门大学创新实验计划项目支

热处理对C/SiC复合材料纤维束中微裂纹扩展行为的影响

利用透射电镜(TEM)观察了湿氧气氛热处理对3D C/SiC复合材料纤维束中微裂纹扩展的影响规律。研究表明,在未经热处理的3D C/SiC纤维束中,微裂纹传播主要为沿纤维/界面相脱粘的单一模式;热处理后纤维束中的微裂纹形成了多种扩展模式。在经历了长达100h的保温之后,热解碳的部分有序化及其层状结构的形成是导致裂纹能量耗散模式增加的主要因素,有序结构的形成也增加了裂纹的联通和长裂纹形成的几率

化学气相沉积SiC–B_xC涂层在高温模拟环境中的微观结构

将化学气相沉积在石墨基片上的SiC-BxC复合涂层在O2(8kPa)/H2O(14kPa)/Ar(78kPa)的模拟气氛中,分别加热到700,1000℃和1200℃处理10h。利用扫描电镜、X射线衍射、能谱分析、显微Raman和Fourier变换红外光谱仪研究其微观结构。结果表明:复合涂层中的BxC层在700～1000℃的模拟环境中会被完全氧化成B2O3和H3BO3;在1000～1200℃的模拟环境中,BxC层的氧化产物迅速挥发。经高温模拟环境处理后,复合涂层中生成了硼硅酸盐玻璃,且各氧化产物和SiC层的结晶度随处理温度的升高而下降。基于微观分析结果,对SiC-BxC复合涂层的自愈合抗氧化性能进行了分析

Influence of Resveratrol on Performance of Long-Term Storage’s Lithium-Ion Battery Electrolyte

锂离子电池电解液从制造完成到使用,一般都会经历灌装、运输和贮存的过程,了解长期贮存过程对锂离子电池电解液性能的影响,对锂离子电池的生产具有一定的理论指导意义。本文运用电化学阻抗谱(EIS)测试并结合循环伏安法(CV)测试、充放电测试、扫描电子显微镜(SEM)等研究了1 mol·L-1 LiPF6-EC:EMC基础电解液中添加不同浓度白藜芦醇(RES)时,在长期贮存过程中对石墨电极性能的影响及机制。研究结果表明,新鲜的基础电解液在经历6个月的贮存后,石墨电极在其中无论是可逆循环容量还是循环稳定性(容量保持率)均出现大幅度的下降。这主要是由于在经历6个月贮存后的基础电解液中,石墨电极表面形成的 SEI 膜较厚,进而导致锂离子嵌入过程的不稳定造成的。在基础电解液中添加不同浓度的白藜芦醇均能有效抑制电解液长期贮存造成的石墨电极在其中电化学性能的下降,当基础电解液中含有200 ppm白藜芦醇经历6个月贮存后,石墨电极无论是可逆容量还是循环性能稳定性甚至优异于在新鲜的电解液中。Electrolyte of lithium-ion battery usually goes through processes of filling, transportation and storage from the completion of manufacture to the use. Understanding the influence of long-term storage process on performance of lithium-ion battery electrolyte is of theoretical significance for production of lithium-ion battery. Scanning electron microscope (SEM) images showed that the solid electrolyte interface (SEI) film formed on the surface of the graphite electrode was thicker in the base electrolyte after 6 months of storage. The charge/discharge test results showed that the reversible cycle capacity and cycle stability (capacity retention rate) of graphite electrode decreased significantly after 6 months of storage. This might be due to the thicker SEI film formed on the surface of the graphite electrode, which in turn led to the instability of the lithium-ion intercalation process. When the base electrolyte containing 200 ppm resveratrol was stored for 6 months, the reversible capacity and cycle performance stability of the graphite electrode were even better than those in fresh base electrolyte. The results of electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) idicated that adding 200 ppm resveratrol to the base electrolyte could effectively suppress the decline in the electrochemical performance of the graphite electrode caused by long-term storage of the base electrolyte.国家自然科学基金项目(U1730136);中央高校基本科研业务费(2017XKQY062)通讯作者:庄全超E-mail:[email protected]:Quan-ChaoZhuangE-mail:[email protected]中国矿业大学材料与物理学院,江苏 徐州 221116Lithium ion battery lab, School of Materials & Physics, China University of Mining & Technology, Xuzhou 221116, Jiangsu, Chin

连续含铝SiC自由膜的制备与发光特性研究

通过自制喷膜装置对聚铝碳硅烷(PACS)进行脱泡处理、熔融纺膜,并对其进行氧化交联、高温预烧及高温裂解终烧可制得连续含铝SiC自由薄膜。用扫描电镜(SEM)分析薄膜的形貌,通过红外光谱(FT-IR)分析氧化交联后薄膜的结构变化,通过电子探针(EPMA)、拉曼光谱(Raman)、X射线衍射(XRD)与场发射高分辨透射电子显微镜(HRTEM)对薄膜进行成分及微观结构分析,采用光致发光谱(PL)对薄膜的光学带隙和发光特性进行了研究。结果表明,熔融纺膜法与PACS先驱体法相结合可制得均匀、致密的耐高温连续含铝SiC自由薄膜,室温下表现出了320~440nm宽谱带发光,其发光峰可分别归因于-αSiC和C簇,且随着烧结温度的提高,发光强度增大

先驱体法制备连续SiC自由薄膜及其发光性能

以聚碳硅烷(polycarbosilane,PCS)为先驱体,熔融纺出连续PCS自由原膜,并在190℃下对其进行1,2,3h和6h氧化交联,在900℃预烧及最终分别在1200℃和1300℃烧成,制得系列SiC自由薄膜。采用红外光谱、Raman光谱、X射线衍射、透射电镜与扫描电镜对薄膜进行微观结构与形貌分析。测量了薄膜的室温光致发光特性。结果表明:连续SiC自由膜均匀致密,含有β-SiC微晶、无定形SiOxCy及C簇;薄膜在410～450nm范围内有较强的蓝光发射,1200℃烧结的薄膜随交联时间增加,发光强度增大;而1300℃烧结的薄膜的发光强度相对下降,且交联时间越长强度下降越明显。412nm发光峰可归结于C簇发光;而435nm附近的峰则是薄膜中富含的Si—O,Si—C等键中的缺陷态构成的发光中心,在β-SiC晶粒中电子受到激发与缺陷态产生辐射复合引起发光以及量子表面效应共同作用的结果

CVI B-C基体改性2D C/SiC在低温湿氧中的自愈合行为

针对C/SiC低温氧化易失效的不足,研究了CVI B-C基体改性2D C/SiC在700℃湿氧中100MPa下加载至60h的氧化行为,利用SEM和TEM观察了改性材料不同服役时间的微结构特征,揭示了演变规律.研究表明,CVI B-C基体改性使C/SiC低温抗氧化能力显著提升.基体裂纹及其在应力加载下的开裂均为氧化气体提供进入通道,而后可被B-C氧化产物B2O3封填,抑制内部C消耗.CVI B-C与其氧化产物一同参与缺陷愈合.在60h内,B-C改性层愈合能力尚未完全发挥,可服役更长时间

连续陶瓷纤维的制备、结构、性能和应用:研究现状及发展方向

连续陶瓷纤维是纤维增强陶瓷基复合材料的增强体,对提高陶瓷基复合材料的强度和韧性起关键作用,高损伤容限和高强度陶瓷纤维是阻止裂纹扩展实现陶瓷基复合材料强韧化的保障。本文对碳化硅、氮化硅、氮化硼、氧化铝和氧化锆等几种陶瓷纤维的制备方法、结构、性能和应用等方面进行了全面的综述,指出了今后的发展方向,期望为未来陶瓷纤维的研究、开发及应用提供参考。国家高技术研究发展计划(863)(2003AA305630);;国家自然科学基金(51472144);;山东省科技重大专项(2015ZDZX11003);;山东省青年学者未来计划(2016WLJH27

C/SiC表面SiC涂层氧化的显微CT无损检测与分析

对C/SiC复合材料表面SiC涂层在1300℃干氧和湿氧环境中退火处理60 h,利用显微CT技术对高温氧化后的SiC涂层进行无损检测。通过重构SiC涂层不同深度的氧化形貌,并利用SEM、EDS和XRD进行辅助验证,得到沿SiC涂层表面和厚度方向的氧化形貌。结果表明:显微CT能有效地检测氧化后SiC涂层中存在的氧化产物SiO2及其氧化深度,其在表面及深度方向均呈非均匀分布;在干氧环境中SiC涂层的氧化面积沿着涂层的深度方向呈减少趋势,而在湿氧环境中SiC涂层的氧化面积沿着涂层的深度方向呈先增加后递减的趋势,验证了C/SiC复合材料表面SiC涂层在干氧和湿氧中不同的氧化机制