Study on the Heat Transfer Adhesive and Heat Transfer Membrane Coating Material

热转印技术自二十世纪八十年代引入我国以来，因其自身具有转印涂层附着力好、经久耐用，图案鲜艳美观、层次丰富，转印工艺简单，而且对于多类材质、多种形状均有很好的转印性等优点，在各类塑料、金属、皮革、陶瓷、木材等制品的包装领域中广泛应用。但目前热转印膜的各层材料仍主要依赖进口，价格较高。本文着力于自主开发热转印离型层材料和热转印胶，有助于减轻成本压力，增强国内热转印行业的竞争力。 首先，本文以甲基丙烯酸甲酯（MMA）、丙烯酸甲酯（MA）为共聚单体，进行溶液共聚反应，用简便的方法合成性能良好的热转印离型层。通过调节BPO用量可控制产物数均相对分子质量在2.0万~3.5万，适用于热转印离型层。通过加入...Since heat transfer printing(HTP) technology was introduced into China in 1980s, it had been widely applied in package printing of plastic, metal, leather, ceramic, wood product, etc, owing to its strong adhesion, good durability, wonderful appearance, simple and convenient transfer printing process, and excellent applicability of various materials and shapes. Unfortunately, most of the HTP membr...学位：理学硕士院系专业：材料学院_高分子化学与物理学号：2072012115005

Syntheses and magnetic properties of 3d metal compounds

分子基磁性材料作为一种新型的材料,近十年来,在化学家和物理学家的努力下,在很多方面已经取得了突破性的进展,迅速发展成为一门材料学科的前沿领域。分子磁体有自己的特性,在器件的小型化、低能耗、高速响应、生物联结的相容性方面都有其独特的优势。这些优势使其在磁性信息材料、纳米机器和药物磁性导入方面有很大的应用前景。所以，合成具有新颖的并具有预期磁性的分子磁体就显得非常重要。本文就着力在用不同的端基配体合成新颖的分子磁体方面。 (1)选用叠氮根作为桥连配体，用不同的端基配体与Mn(Ⅱ),Co(Ⅱ)离子，以合理的设计为指导，尝试了不同的合成方法，合成了新颖的叠氮根桥连的化合物。在这些化合物中叠氮根会以E...Molecular materials have been attracted great attentions for a new type of materials, and great progess have been made under the effort of chemist and physicist in recent 10 years. Molecular magnet have its special properties and advantages, such as miniaturization, low power, high speed response, compatibility of biology junction. All of these characteristics determine that there are great potent...学位：理学硕士院系专业：化学化工学院化学系_无机化学学号：X20042500

Study on Electrocatalytic Oxidation of sec-Butyl Alcohol on Pt Electrode Modified with Adatoms

运用电化学循环伏安和石英晶体微天平研究了HClO4溶液中仲丁醇在Pt电极及以Sb和S吸附原子修饰的Pt(Pt/Sbad和Pt/Sad)电极上的电催化氧化过程 .从电极表面质量变化可以看出 ,仲丁醇的氧化与电极表面的氧物种有着极其密切的关系 .Pt电极表面Sb吸附原子可在较低的电位下吸附氧 ,明显提高仲丁醇的氧化活性 .与Pt电极相比 ,Sb吸附原子修饰的Pt电极使仲丁醇氧化的峰电位负移约 10 0mV .相反 ,Pt电极表面S吸附原子的氧化会消耗表面氧物种 ,抑制仲丁醇的氧化 .从电极表面质量变化提供了吸附原子电催化作用的数据The processes of adsorption and oxidation of sec butyl alcohol on Pt electrode and Pt electrodes modified with Sb and S (Pt/Sb ad and Pt/S ad ) were studied by using cyclic voltammetry and electrochemical quartz crystal microbalance (EQCM). The results demonstrated that the oxidation of sec butyl alcohol depends strongly on oxidation states of electrode surface. Sb adatoms on Pt surface can adsorb oxygen at relatively low potentials, and exhibit catalytic effects for sec butyl alcohol oxidation. In comparison with the case of Pt electrode, the oxidation peak potential of sec butyl alcohol on Pt surface modified with Sb was negatively shifted about 100 mV. On the contrary, the oxidation of S adatoms consumes oxygen species on Pt electrode surface. As a consequence, the oxidation of sec butyl alcohol was inhibited by the presence of S ad . The EQCM studies provided quantitative results of surface mass changes during sec butyl alcohol oxidation, and have thrown new light on elucidating different effects of adatoms Sb ad and S ad on Pt electrode towards sec butyl alcohol oxidation.国家自然科学基金 (2 983 3 0 60 );; 教育部博士点专项科研基金 (19990 3 840 3 );; 福建省教委科研基金资助项目 (K2 0 0 110 1

肌萎缩侧索硬化症SOD1基因突变特点

【目的】 探讨中国南方人群肌萎缩侧索硬化症铜锌超氧化物岐化酶（CulZnsuperoxidedismutase；SOD1）基因突变的特点。【方法】 采用SOD1基因的5对引物对4个家系的15例家族性肌萎缩侧索硬化症（FALS）患者、56例散发性肌萎缩侧索硬化症（SALS）患者和46例正常对照DNA进行PCR扩增，重复三次应用单链构象多态性方法分析各外显子的多态性。【结果】 SOD1基因的5个外显子未发现异常泳动。【结论】 中国南方人群肌萎缩侧索硬化症患者可能不存在SOD1基因第1-5号外显子突变或突变率极低，可能存在其他位点的基因突变

Study on electrocatalytic oxidation of sec-butyl alcohol on pt electrode modified with adatoms

The processes of adsorption and oxidation of sec-butyl alcohol on Pt electrode and Pt electrodes modified with Sb and S (Pt/Sb-ad and Pt/S-ad) were studied by using cyclic voltammetry and electrochemical quartz crystal microbalance (EQCM). The results demonstrated that the oxidation of sec-butyl alcohol depends strongly on oxidation states of electrode surface. Sb adatoms on Pt surface can adsorb oxygen at relatively low potentials, and exhibit catalytic effects for sec-butyl alcohol oxidation, In comparison with the case of Pt electrode, the oxidation peak potential of sec-butyl alcohol on Pt surface modified with Sb was negatively shifted about 100 mV. On the contrary, the oxidation of S adatoms consumes oxygen species on Pt electrode surface. As a consequence, the oxidation of sec-butyl alcohol was inhibited by the presence of S-ad. The EQCM studies provided quantitative results of surface mass changes during sec-butyl alcohol oxidation, and have thrown new light on elucidating different effects of adatoms Sb-ad and S-ad on Pt electrode towards sec-butyl alcohol oxidation

佐久地域の事業所における健康管理等に関する実態調査について

要旨：佐久地域の事業所における労働者の定期健康診断及び保健指導、被扶養者の特定健診、受動喫煙防止対策、労働者の昼食のそれぞれの状況について調査した。その結果、定期健康診断実施後のフォローアップや保健指導の実施に課題がみられた。被扶養者は、特定健診を受診しやすい環境にあるとは言えない状況がうかがえ、受動喫煙防止対策については一層の推進が必要であった。また、労働者は昼食として市販の弁当を利用している状況が明らかとなった。事業所における健康づくりが向上するよう、今後、佐久地域保健・職域保健連携推進協議会で対策を検討し、活動につなげていきたい。Article信州公衆衛生雑誌 10(1): 22-23(2015)journal articl

「“さく”っとうす味みんなでキャンペーン」の取組について

要旨：減塩をより一層推進するため、地域の関係機関・団体と連携して減塩キャンペーンを実施した。関係機関・団体の積極的な活動により目標を上回る実施ができた。今回の取組の中で働き盛り世代への取組の必要性が明らかとなったが十分なアプローチができていなかったため、今後は働き盛り世代を意識しながら、引き続き関係者一丸となった取組を進めていく。Article信州公衆衛生雑誌 11(1): 44-45(2016)journal articl

Ferromagnetic interactions in a bis(mu-end-on azido)cobalt(II) linear trimer

通讯作者地址: Tao, J (通讯作者), Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 2. Zhangzhou Inst Technol, Dept Food & Bioengn, Zhangzhou, Fujian Peoples R ChinaA linear trinuclear Co(II) compound, [Co-3(mu(1,1)-N-3)(4)(N-3)(2)(H2O)(2)(bpbp)(2)] center dot 2H(2)O (1, bpbp = 3,3'-bis-Dimethytamino-1,1'-pyridine-2,6-diyl-bispropenone), is reported. The central Co(II) ion is bridged to Co(II) ions on both sides by four end-on azide (mu(1,1)-N-3(-)) ligands resulting in a centrosymmetric trimer with adjacent Co center dot center dot center dot Co distance of 3.233 angstrom. Each Co(II) ion possesses distorted octahedral geometry, the central one is coordinated by two aqua ligands and four mu(1,1)-N-3(-) nitrogen atoms and each terminal Co(II) is coordinated by two mu(1,1)-N-3(-) nitrogen atoms, one terminal N-3(-) nitrogen atom and capped by terminal tridentate bpbp ligand. Variable temperature magnetic studies indicate ferromagnetic coupling between adjacent Co(II) ions within the trimer. Crown Copyright (C) 2008 Published by Elsevier B.V. All rights reserved

Ferromagnetic interactions in a bis(mu-end-on azido)cobalt(II) linear trimer

通讯作者地址: Tao, J (通讯作者), Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 地址: 1. Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China 2. Zhangzhou Inst Technol, Dept Food & Bioengn, Zhangzhou, Fujian Peoples R ChinaA linear trinuclear Co(II) compound, [Co-3(mu(1,1)-N-3)(4)(N-3)(2)(H2O)(2)(bpbp)(2)] center dot 2H(2)O (1, bpbp = 3,3'-bis-Dimethytamino-1,1'-pyridine-2,6-diyl-bispropenone), is reported. The central Co(II) ion is bridged to Co(II) ions on both sides by four end-on azide (mu(1,1)-N-3(-)) ligands resulting in a centrosymmetric trimer with adjacent Co center dot center dot center dot Co distance of 3.233 angstrom. Each Co(II) ion possesses distorted octahedral geometry, the central one is coordinated by two aqua ligands and four mu(1,1)-N-3(-) nitrogen atoms and each terminal Co(II) is coordinated by two mu(1,1)-N-3(-) nitrogen atoms, one terminal N-3(-) nitrogen atom and capped by terminal tridentate bpbp ligand. Variable temperature magnetic studies indicate ferromagnetic coupling between adjacent Co(II) ions within the trimer. Crown Copyright (C) 2008 Published by Elsevier B.V. All rights reserved