Effect of Grain Size on Differential Desorption of Volatile Species and on Non-ideal MHD Diffusivity

We developed a chemical network for modeling the chemistry and non-ideal MHD effects from the collapsing dense molecular clouds to protostellar disks. First, we re-formulated the cosmic-ray desorption rate by considering the variations of desorption rate over the grain size distribution. We find that the differential desorption of volatile species is amplified by the grains larger than 0.1 $\mu$m, because larger grains are heated to a lower temperature by cosmic-rays and hence more sensitive to the variations in binding energies. As a result, atomic nitrogen N is $\sim$2 orders of magnitude more abundant than CO; N$_2$H$^+$ also becomes a few times more abundant than HCO$^+$ due to the increased gas-phase N$_2$. However, the changes in ionization fraction due to freeze-out and desorption only have minor effects on the non-ideal MHD diffusivities. Our chemical network confirms that the very small grains (VSGs: below a few 100 $\AA$) weakens the efficiency of both ambipolar diffusion and Hall effect. In collapsing dense cores, a maximum ambipolar diffusion is achieved when truncating the MRN size distribution at 0.1 $\mu$m, and for a maximum Hall effect, the truncation occurs at 0.04 $\mu$m. We conclude that the grain size distribution is crucial to the differential depletion between CO and N$_2$ related molecules, as well as to the non-ideal MHD diffusivities in dense cores.Comment: 15 pages, 11 figures; Submitted to MNRA

Electroneutrality Breakdown and Specific Ion Effects in Nanoconfined Aqueous Electrolytes Observed by NMR

Ion distribution in aqueous electrolytes near the interface plays critical roles in electrochemical, biological and colloidal systems and is expected to be particularly significant inside nanoconfined regions. Electroneutrality of the total charge inside nanoconfined regions is commonly assumed a priori in solving ion distribution of aqueous electrolytes nanoconfined by uncharged hydrophobic surfaces with no direct experimental validation. Here, we use a quantitative nuclear magnetic resonance approach to investigate the properties of aqueous electrolytes nanoconfined in graphitic-like nanoporous carbon. Substantial electroneutrality breakdown in nanoconfined regions and very asymmetric responses of cations and anions to the charging of nanoconfining surfaces are observed. The electroneutrality breakdown is shown to depend strongly on the propensity of anions toward the water-carbon interface and such ion-specific response follows generally the anion ranking of the Hofmeister series. The experimental observations are further supported by numerical evaluation using the generalized Poisson-Boltzmann equationComment: 26 pages, 3 figure

Spectrum Structure of Fermion on Bloch Branes with Two Scalar-fermion Couplings

It is known that the Bloch brane is generated by an odd scalar field $\phi$ and an even one $\chi$. In order to localize a bulk fermion on the Bloch brane, the coupling between the fermion and scalars should be introduced. { There are two localization mechanisms in the literature, the Yukawa coupling $-\eta \bar{\Psi} F_1(\phi,\chi) \Psi$ and non-Yukawa coupling $\lambda \bar \Psi \Gamma^M \partial_M F_2(\phi,\chi) \gamma^5 \Psi$. The Yukawa coupling has been considered.} In this paper, we consider { both couplings between the fermion and the scalars with $F_1=\chi^m\phi^{2p+1}$ and $F_2=\chi^n\phi^{2q}$}, and investigate the localization and spectrum structure of the fermion on the Bloch brane. { It is found that the} left-handed fermion zero mode can be localized on the Bloch brane under some conditions, and the effective potentials have { rich} structure and may be volcano-like, finite square well-like, and infinite potentials. As a result, the spectrum { consists of} a series of resonant Kaluza-Klein fermions, finite or infinite numbers of bound Kaluza-Klein fermions. { Especially, we find a new feature of the introduction of both couplings: the spectrum for the case of finite square well-like potentials contains discrete quasi-localized and localized massive KK modes simultaneously.Comment: 22 pages, 13 figure

In-situ cosmogenic ³⁶Cl denudation rates of carbonates in Guizhou karst area

This study quantifies surface denudation of carbonate rocks by the first application of in-situ cosmogenic <sup>36</sup>Cl in China. Concentrations of natural Cl and in-situ cosmogenic <sup>36</sup>Cl in bare carbonates from Guizhou karst areas were measured with isotope dilution by accelerator mass spectrometer. The Cl concentration varied from 16 to 206 ppm. The <sup>36</sup>Cl concentrations were in range of (0.8–2.4)×106 atom g−1, resulting in total denudation rates of 20–50 mm ka−1 that averaged over a 104–105 a timescale. The <sup>36</sup>Cl-denudation rates showed roughly a negative correlation with the local mean temperature. This preliminary observation may suggest the variations of proportions of chemical weathering and physical erosion in denudation process, depending upon local climatic conditions