Sustainable refugee migration:a rethink towards a positive capability approach

A major challenge facing many countries around the world is how to sustainably address the issues of increased numbers of refugee migrants. The refugee migrant “issue” is often heavily political as a high density of migrants in local areas impacts communities (e.g., disrupting local employment, service and culture). Different migrants come with different “baggage” and needs which can be a significant draw on the hosting communities’ resources. This paper argues that sustainable long-term solutions to refugee migrants will require a rethink to the existing dominant models of containment and charity. The paper draws upon insights from a study of a large refugee camp in Jordan over a three-and-a-half-year period, and historical cases of refugee migration. The paper presents a sustainable model that develops long-term capability for the various stakeholder groups

Molybdenum (VI) imido complexes derived from chelating phenols : Synthesis, characterization and ɛ-Caprolactone ROP capability

Reaction of the bulky bi-phenols 2,2′-RCH[4,6-(t-Bu)₂C₆H₂OH]₂ (R = Me L¹ᵐᵉH₂, Ph L¹ᵖʰH₂) with the bis(imido) molybdenum(VI) tert-butoxides [Mo(NR¹)(NR²)(Ot-Bu)₂] (R¹ = R² = 2,6-C₆H₃-i-Pr₂; R¹ = t-Bu, R² = C₆F₅) afforded, following the successive removal of tert-butanol, the complexes [Mo(NC₆H₃ᵢ-Pr₂-2,6)₂L¹ᵐᵉ] (1), [Mo(NC₆H₃i-Pr₂-2,6)₂L¹ᵖʰ] (2) and [Mo(Nt-Bu)(μ-NC₆F₅)(L¹ᵐᵉ)]₂ (3). Similar use of the tri-phenol 2,6-bis(3,5-di-tert-butyl-2-hydroxybenzyl)-4-methylphenol (L²H₃) with [Mo(NC₆H₃ᵢ-Pr₂-2,6)₂(Ot-Bu)₂] afforded the oxo-bridged product [Mo(NC₆H₃i-Pr₂-2,6)(NCMe)(μ-O)L2H]₂ (4), whilst use of the tetra-phenols α,α,α′,α′-tetrakis(3,5-di-tert-butyl-2-hydroxyphenyl)-p- or -m-xylene L³ᵖH₄/L³ᵐH₄ led to {[Mo(NC₆H₃ᵢ-Pr₂-2,6)₂]₂(μ-L³ᵖ)} (5) or {[Mo(NC₆H₃ᵢ-Pr₂-2,6)₂]₂(μ-L³ᵐ)} (6), respectively. Similar use of [Mo(NC₆F₅)₂(Ot-Bu)₂] with L³ᵖH₄ afforded, after work-up, the complex {[Mo(NC₆F₅)(Ot-Bu)₂]₂(μ-L³ᵖ)}·6MeCN (7·6MeCN). Molecular structures of 1, 2·CH₂Cl₂, 3, 4·6MeCN, 6·2C₆H₁₄, and 7·6MeCN are reported and these complexes have been screened for their ability to ring open polymerize (ROP) ε-caprolactone; for comparative studies the precursor complex [Mo(NC₆H₃ᵢ-Pr₂-2,6)₂Cl₂(DME)] (DME = 1,2-dimethoxyethane) has also been screened. Results revealed that good activity is only achievable at temperatures of ≥100 °C over periods of 1 h or more. Polymer polydispersities were narrow, but observed molecular weights (Mn) were much lower than calculated values

Multimetallic lithium complexes derived from the acids Ph₂C(X)CO₂H (X = OH, NH₂) : synthesis, structure and ring opening polymerization of lactides and lactones

Reaction of LiOR (R=t-Bu, Ph) with the acids 2,2/-Ph₂C(X)(CO₂H), X=OH (benzH), NH₂ (dpgH) was investigated. For benzH, one equivalent LiOt-Bu in THF afforded [Li(benz)]2⋅2THF (1⋅2THF), which adopts a 1D chain structure. If acetonitrile is used (mild conditions), another polymorph of 1 is isolated; LiOPh also led to 1. Robust work-up afforded [Li₇(benz)₇(MeCN)] 2MeCN THF (2⋅2MeCN⋅THF). Use of LiOt-Bu (2 equivalents) led to {Li₈(Ot-Bu)₂[(benz)](OCPh₂CO₂CPh₂CO2t-Bu)₂(THF)₄} (3), the core of which comprises two open cubes linked by benz ligands. For dpgH, two equivalents of LiOt-Bu in THF afforded [Li6(Ot-Bu)₂(dpg)₂(THF)₂] (4), which contains an Li₂Ov 6-step ladder. Similar reaction of LiOPh afforded [Li₈(PhO)₄(dpg)₄(MeCN)₄] (5). Complexes 1–5 were screened for their potential as catalysts for ring opening polymerization (ROP) of ϵ-caprolactone (ϵ-CL), rac-lactide (rac-LA) and δ-valerolactone (δ-VL). For ROP of ϵ-CL, conversions > 70 % were achievable at 110 °C with good control. For rac-LA and δ-VL, temperatures of at least 110 °C over 12 h were necessary for activity (conversions > 60 %). Systems employing 2 were inactiv

Aspirator Separation of Corn-fines Mixtures

A study was conducted to determine physical and chemical characteristics of com fines removed by a Kice Mini-Aspirator. Five air velocities were used to separate mixtures of com fines and whole kernels into heavies and liftings. As aspirator air velocity was increased, removal efficiency of every size fraction increased; starch content of liftings decreased, whereas oil content increased and protein content was unchanged

Measurement of Corn Mechanical Damage Using Dielectric Properties

Dielectric measurements between 10 Hz to 13 MHz were obtained using an HP 4192A Impedance Analyzer for two types of artificially damaged corn samples: medium and severe damage. For each damage type, the measurements were obtained at two moisture content levels (11 and 19 percent, W.B.) and five damage levels (0, 10, 25, 50, and 100 percent). Each sample was also compressed to produce another bulk density. The results showed that dielectric properties were able to measure moisture content, bulk density, and mechanical damage level. Using dielectric variables only, medium damaged level was predicted with R 2 = 0.95 and RMSE =8.8 percent, while severe damage level was predicted with R 2 = 0.97 and RMSE = 6.96 percent. However, when the actual moisture content and bulk density were used along with dielectric variables, the severe damage level prediction was slightly improved with R 2 = 0.98 and RMSE = 5.97percent, and medium damage was also improved with R 2 = 0.98 and RMSE = 5.77 percent. The results showed that dielectric measurements had a good potential for measuring corn mechanical damage. However, further investigation is required to test combine- damaged corn using the same technique

Second Stage String Fragmentation Model

A string model, advocated by Bowler, provides a physical and intuitive picture of heavy quark fragmentation. When supplemented by an ad hoc factor of (1-z), to suppress fragmentation near z=1, it supplies an excellent fit to the data. We extend Bowler's model by accounting for the further decay of the massive mesonic states produced by the initial string breaking. We find that each subsequent string break and cascade decay beyond the first, introduces a factor of (1-z). Furthermore we find that including a finite mass for the quarks, which pop out of the vacuum and split the string, forces the first string breaking to produce massive states requiring further decay. This sequence terminates at the second stage of fragmentation where only relatively "light" heavy meson systems are formed. Thus we naturally account for the phenomenologically required factor of (1-z). We also predict that the ratio of (primary) fragments-vector/(vector plus scalar) should be .61. Our second stage string fragmentation model provides an appealing picture of heavy quark fragmentation.Comment: 15 page

Monolithic Integration of a Plasmonic Sensor with CMOS Technology

Monolithic integration of nanophotonic sensors with CMOS detectors can transform the laboratory based nanophotonic sensors into practical devices with a range of applications in everyday life. In this work, by monolithically integrating an array of gold nanodiscs with the CMOS photodiode we have developed a compact and miniaturized nanophotonic sensor system having direct electrical read out. Doing so eliminates the need of expensive and bulky laboratory based optical spectrum analyzers used currently for measurements of nanophotonic sensor chips. The experimental optical sensitivity of the gold nanodiscs is measured to be 275 nm/RIU which translates to an electrical sensitivity of 5.4 V/RIU. This integration of nanophotonic sensors with the CMOS electronics has the potential to revolutionize personalized medical diagnostics similar to the way in which the CMOS technology has revolutionized the electronics industry