Many-Spin Effects and Tunneling Properties of Magnetic Molecules

Spin tunneling in molecular magnets has attracted much attention, however theoretical considerations of this phenomenon up to now have not taken into account the many-spin nature of molecular magnets. We present, to our knowledge, the first successful attempt of a realistic calculation of tunneling splittings for Mn$_{12}$ molecules, thus achieving a quantitatively accurate many-spin description of a real molecular magnet in the energy interval ranging from about 100 K down to 10$^{-12}$ K. Comparison with the results of the standard single-spin model shows that many-spin effects affect the tunneling splittings considerably. The values of ground state splitting given by single-spin and many-spin models differ from each other by a factor of five.Comment: 3REVTeX pages, 2 figure

Hyperfine interaction induced decoherence of electron spins in quantum dots

We investigate in detail, using both analytical and numerical tools, the decoherence of electron spins in quantum dots (QDs) coupled to a bath of nuclear spins in magnetic fields or with various initial bath polarizations, focusing on the longitudinal relaxation in low and moderate field/polarization regimes. An increase of the initial polarization of nuclear spin bath has the same effect on the decoherence process as an increase of the external magnetic field, namely, the decoherence dynamics changes from smooth decay to damped oscillations. This change can be observed experimentally for a single QD and for a double-QD setup. Our results indicate that substantial increase of the decoherence time requires very large bath polarizations, and the use of other methods (dynamical decoupling or control of the nuclear spins distribution) may be more practical for suppressing decoherence of QD-based qubits.Comment: Rev. Tex, 5 pages, 3 eps color figures, submitted to Phys. Rev.

Effect of ligand substitution on the exchange interactions in {Mn12}-type single-molecule magnets

We investigate how the ligand substitution affects the intra-molecular spin exchange interactions, studying a prototypal family of single-molecule magnets comprising dodecanuclear cluster molecules [Mn12O12(COOR)16]. We identify a simple scheme based on accumulated Pauling electronegativity numbers (a.e.n.) of the carboxylate ligand groups (R). The redistribution of the electron density, controlled by a.e.n. of a ligand, changes the degree of hybridization between 3d electrons of manganese and 2p electrons of oxygen atoms, thus changing the exchange interactions. This scheme, despite its conceptual simplicity, provides a strong correlation with the exchange energies associated with carboxylate bridges, and is confirmed by the electronic structure calculations taking into account the Coulomb correlations in magnetic molecules.Comment: 18 pages, 1 table, 4 figures. Accepted to "Inorganic Chemistry

Abnormal ECG Findings in Athletes: Clinical Evaluation and Considerations.

PURPOSE OF REVIEW: Pre-participation cardiovascular evaluation with electrocardiography is normal practice for most sporting bodies. Awareness about sudden cardiac death in athletes and recognizing how screening can help identify vulnerable athletes have empowered different sporting disciplines to invest in the wellbeing of their athletes. RECENT FINDINGS: Discerning physiological electrical alterations due to athletic training from those representing cardiac pathology may be challenging. The mode of investigation of affected athletes is dependent on the electrical anomaly and the disease(s) in question. This review will highlight specific pathological ECG patterns that warrant assessment and surveillance, together with an in-depth review of the recommended algorithm for evaluation

Sinais clínicos associados a um caso de envenenamento iatrogênico de um equino com três dias de idade por um produto comercial baseado em terebintina

O objetivo deste estudo é relatar um caso de intoxicação iatrogênica por um produto comercial a base de terebentina em um potro de três días de idade e o sucesso do tratamento dessa condição. Um potro de três dias de idade foi apresentou um colapso cardiorrespiratório agudo, choque anafilático, desconforto respiratório grave, dispnéia e edema pulmonar. A história incluiu a administração prévia de um produto veterinário comercial (UNITIPAN). Ao exame clínico: temperatura: (39,9 °C), pulso: 135 bpm, respiração 51 bpm, membranas mucosas, congestionamento úmido, tempo de enchimento capilar: três segundos ou menos. O potro foi tratado com hidratação de emergência, duphalyte, anti-inflamatório esteroidal, sulfato de atropina e antibiótico. Após seis horas de tratamento, o potro foi estabilizado e os sinais vitais foram normalizados depois de oito horas do inicio do tratamento. O presente trabalho relata um caso de intoxicação iatrogênica por um produto à base de terebintina comercial em um potro de três dias de idade com rápido desenvolvimento de sinais de toxicidade aguda e uma resposta muito favorável ao tratamento sintomático.The aim of this study is to report a case of iatrogenic poisoning by a turpentine-based commercial product in a 3-day-old foal and the successful treatment of this condition. A 3-day-old male foal presented with acute cardio-respiratory collapse, anaphylactic shock, severe respiratory distress, dyspnea and pulmonary edema. The animal’s history included previous administration of a commercial veterinary product (UNITIPAN). Clinical examination revealed: temperature: (39.9 °C), pulse: 135 bpm, respiration: 51 bpm, mucous membranes: moist and congested, capillary refill time: 3 sec or less. The foal was treated with emergency hydration, duphalyte, steroidal anti-inflammatory, atropine sulphate and antibiotic. After 6 h of treatment, the foal was stabilized and vital signs were normalized 8 h after treatment start.El objetivo de este estudio es informar un caso de envenenamiento iatrogénico por un producto comercial basado en la trementina en un potro de 3 días y el tratamiento exitoso de esta afección. Se presentó un potro de 3 días de edad que mostraba colapso cardiorrespiratorio agudo, shock anafiláctico, dificultad respiratoria grave, disnea y edema pulmonar. La historia incluía la administración previa de un producto veterinario comercial (UNITIPAN). En el examen clínico: temperatura: (39.9 ° C), pulso: 135 lpm, respiración 51 lpm, membranas mucosas, congestión húmeda, tiempo de llenado capilar: tres segundos o menos. El potro fue tratado con hidratación de emergencia, duphalito, antiinflamatorio esteroideo, sulfato de atropina y antibiótico. Después de 6 horas de tratamiento, el potro se estabilizó y los signos vitales se normalizaron 8 después. En conclusión, informamos sobre un caso de intoxicación iatrogénica por un producto comercial a base de trementina en un potro de 3 días con un rápido desarrollo de signos de toxicidad aguda y una respuesta muy favorable al tratamiento sintomático

Clinical signs associated with a case of iatrogenic poisoning by a turpentine-based commercial product in a 3-day-old foal

The aim of this study is to report a case of iatrogenic poisoning by a turpentine-based commercial product in a 3-day-old foal and the successful treatment of this condition. A 3-day-old male foal presented with acute cardio-respiratory collapse, anaphylactic shock, severe respiratory distress, dyspnea and pulmonary edema. The animal’s history included previous administration of a commercial veterinary product (UNITIPAN). Clinical examination revealed: temperature: (39.9 °C), pulse: 135 bpm, respiration: 51 bpm, mucous membranes: moist and congested, capillary refill time: 3 sec or less. The foal was treated with emergency hydration, duphalyte, steroidal anti-inflammatory, atropine sulphate and antibiotic. After 6 h of treatment, the foal was stabilized and vital signs were normalized 8 h after treatment start

Intelligent Systems Research in the Construction Industry

YesWith the increasing complexity of problems in the construction industry, researchers are investigating computationally rigorous intelligent systems with the aim of seeking intelligent solutions. The purpose of this paper is therefore to analyse the research published on ‘intelligent systems in the construction industry’ over the past two decades. This is achieved to observe and understand the historical trends and current patterns in the use of different types of intelligent systems and to exhibit potential directions of further research. Thus, to trace the applications of intelligent systems to research in the construction industry, a profiling approach is employed to analyse 514 publications extracted from the Scopus database. The prime value and uniqueness of this paper lies in analysing and compiling the existing published material by examining variables (such as yearly publications, geographic location of each publication, etc.). This has been achieved by synthesising existing publications using 14 keywords2 ‘Intelligent Systems’, ‘Artificial Intelligence’, ‘Expert Systems’, ‘Fuzzy Systems’, ‘Genetic Algorithms’, ‘Knowledge-Based Systems’, ‘Neural Networks’, ‘Context Aware Applications’, ‘Embedded Systems’, ‘Human–Machine Interface’, ‘Sensing and Multiple Sensor Fusion’, ‘Ubiquitous and Physical Computing’, ‘Case-based Reasoning’ and ‘Construction Industry’. The prime contributions of this research are identified by associating (a) yearly publication and geographic location, (b) yearly publication and the type of intelligent systems employed/discussed, (c) geographic location and the type of research methods employed, and (d) geographic location and the types of intelligent systems employed. These contributions provide a comparison between the two decades and offer insights into the trends in using different intelligent systems types in the construction industry. The analysis presented in this paper has identified intelligent systems studies that have contributed to the development and accumulation of intellectual wealth to the intelligent systems area in the construction industry. This research has implications for researchers, journal editors, practitioners, universities and research institutions. Moreover, it is likely to form the basis and motivation for profiling other database resources and specific types of intelligent systems journals in this area

A megbocsátás pszichológiája: kialakulása, hatásai és fejlesztése

A megbocsátás az interperszonális sérelmekre adott egyik lehetséges válasznak tekinthető, melynek fókuszában a sérelmet elszenvedő személy kognitív, érzelmi és viselkedéses válaszaiban bekövetkező proszociális változás áll. A megbocsátás mentális és fizikai egészségre kifejtett pozitív hatása jól dokumentált. Magas szintje alacsony szorongás- és depressziószinttel társul, illetve sikeresen csökkenti a stresszre adott fizikai választ (kortizol és kardiovaszkuláris reaktivitás). A megbocsátást - hatásai alapján - olyan emóció fókuszú megküzdési módként definiálhatjuk, mely sikeresen csökkenti az interperszonális sérelem nyomán kialakult stresszreakciót. Az utóbbi években számos intervenciós technikát dolgoztak ki, melyek a megbocsátás támogatását, illetve fejlesztését tűzték ki célként. Ezek a módszerek általában sikeresen növelik a megbocsátásra való hajlandóságot.</o:p