SO2 on Io: A thermodynamic perspective

The presence of condensed SO2 on Io mandates a finite abundance of SO2 vapor which must be present, regardless of plume activity. The absorption of SO2 was measured on particulate sulfur and the equilibrium between absorbed SO2, SO2 vapor, and SO2 ice examined, based upon measurements and simple thermodynamic considerations

The Phoenix TECP Relative Humidity Sensor: Revised Results

The original calibration function of the RH sensor on the Phoenix mission's Thermal and Electrical Conductivity Sensor (TECP), has been revised to correct the erroneously-published original calibration equation, to demonstrate the value of this unique data set, and to improve characterization of H2O exchange between the martian regolith and atmosphere. TECP returned two data streams, the temperature of the electronics analog board (Tb) and the digital 12-bit output of the RH sensor (DN), both of which are required to uniquely specify the H2O abundance. Because the original flight instrument calibration was performed against a pair of hygrometers that measured frost point (Tf), the revised calibration equation is also cast in terms of frost point. The choice of functional form for the calibration function is minimally constrained. A series of profiles across the calibration data cloud at constant DN and Tb does not reveal any evidence of a complex functional form. Therefore, a series of polynomials in both DN and Tb was investigated, along with several non-linear functions of DN and Tb

A Historical Search for the Occurrence of Habitable Ground Ice at the Phoenix Landing Site

A numerical model of the thermal history of Martian ground ice at the approximate location of the planned Phoenix landing site has been developed and used to identify instances of relatively warm ground ice over the last 10 Ma. Many terrestrial organisms are adapted to life at or below the freezing temperature of water, and we will use the approximate doubling time of terrestrial microbial populations as a function of temperature, is used as a metric against which to assess the "habitability" of Martian ground ice

Atmospheric H2O and the search for Martian brines

Abundant martian brines would have important implication for current theories of volatile migration on Mars, since, although the presence of metastable brines is quite plausible, any brine in the reasonably near-surface should be completely depleted on a timescale short in relation to the age of Mars. It is important to determine whether brines exist in the martian subsurface, for the current paradigm for understanding martian volatile regime requires substantial alteration if they are found to exist. It is determined, however, that the prospect for detection of a subsurface brine via atmospheric water vapor measurements is marginal. Four reasons are given for this conclusion

Pascal: A Mars Climate Network Mission

A viewgraph presentation on Pascal: A Mars Climate Network Mission is shown

CO2: Adsorption on palagonite and the Martian regolith

Possible scenarios for the evolution of the Martian climate are discussed. In the interest of determining an upper limit on the absorptive capacity of the Martian regolith, researchers examined the results of Fanale and Cannon (1971, 1974) for CO2 adsorption on nontronite and basalt. There appeared to be a strong proportionality between the capacity of the absorbent and its specific surface area. A model of the Martian climate is given that allows the researchers to make some estimates of exchangeable CO2 abundances

Climatological targets for Mars Pathfinder

Four areas fit within the elevation and latitude constraints: Chryse, Elysium, Amazonis, and Isidis. There is geomorphic evidence that all have supported standing water. In some cases it would be difficult to pick a landing site that had no hope of teaching us about the climatic history of Mars. The southeast Elysium Basin provides an optimal target in which a variety of materials may be accessible in a near-shore environment. The albedo of the region is moderately low, and the thermal inertia is indicative of moderate rock coverage or some consolidation of fines, arguing that the site has not been covered with eolian dust deposits

Simultaneous adsorption of CO2 and H2O under Mars-like conditions and application to the evolution of the Martian climate

The Martian regolith is the most substantial volatile reservoir on the planet; it holds CO2 as adsorbate, and can exchange that CO2 with the atmosphere-cap system over timescales of 10(exp 5) to 10(exp 6) years. The climatic response to insolation changes caused by obliquity and eccentricity variations depends in part on the total reservoir of adsorbed CO2. Previous estimates of the adsorbate inventory have been made by measuring the adsorptive behavior of one or more Mars-analyog materials, and deriving an empirical equation that described that adsorption as a function of the partial pressure of CO2 and the temperature of the regolith. The current CO2 inventory is that which satisfies adsorptive equilibrium, observed atmospheric pressure, and no permanent CO2 caps. There is laboratory evidence that H2O poisons the CO2 adsorptive capacity of most materials. No consideration of CO2 - H2O co-adsorption was given in previous estimates of the Martian CO2 inventory, although H2O is present in the vapor phase, and so as adsorbate, throughout the regolith

A Revised Calibration Function and Results for the Phoenix Mission TECP Relative Humidity Sensor

The original calibration function of the R(sub H) sensor on the Phoenix Thermal and Electrical Conductivity Sensor (TECP) has been revised in order to extend the range of the valid calibration, and to improve accuracy. The original function returned non-physical R(sub H) values at the lowest temperatures. To resolve this, and because the original calibration was performed against a pair of hygrometers that measured frost point (T(sub f)), the revised calibration equation is also cast in terms of frost point. Because of the complexity of maintaining very low temperatures and high R(sub H) in the laboratory, no calibration data exists at T is greater than 203K. However, sensor response during the mission was smooth and continuous down to 181 K. Therefore we have opted to include flight data in the calibration data set; selection was limited to data acquired during periods when the atmosphere is known to have been saturated. T(sub f) remained below 210 K throughout the mission(P is greater than 0.75 Pa). R(sub H), conversely, ranged from 1 to well under 0.01 diurnally, due to approximately 50 K temperature variations. To first order, both vapor pressure and its variance are greater during daylight hours. Variance in overnight humidity is almost entirely explained by temperature, while atmospheric turbulence contributes substantial variance to daytime humidity. Likewise, data gathered with the TECP aloft reflect higher H2O abundances than at the surface, as well as greater variance. There is evidence for saturation of the atmosphere overnight throughout much of the mission. In virtually every overnight observation, once the atmosphere cooled to T(sub f), water vapor begins to decrease, and tracks air temperature. There is no evidence for substantial decreases in water vapor prior to saturation, as expected for adsorptive exchange. Likewise, there is no evidence of local control of vapor by phases such as perchlorate hydrates hydrated minerals. The daytime average H2O pressure does not change substantially over the course of the mission, although the H2O column abundance varies by a factor of 2. Column abundances calculated from TECP data are lower than orbital measurements if one assumes that H2O is uniformly mixed through a single scale height. These results argue that the vertical distribution of H2O begins to change well in advance of surface concentrations as northern autumn approaches

The Thermal Electrical Conductivity Probe (TECP) for Phoenix

The Thermal and Electrical Conductivity Probe (TECP) is a component of the Microscopy, Electrochemistry, and Conductivity Analyzer (MECA) payload on the Phoenix Lander. TECP will measure the temperature, thermal conductivity and volumetric heat capacity of the regolith. It will also detect and quantify the population of mobile H2O molecules in the regolith, if any, throughout the polar summer, by measuring the electrical conductivity of the regolith, as well as the dielectric permittivity. In the vapor phase, TECP is capable of measuring the atmospheric H2O vapor abundance, as well as augment the wind velocity measurements from the meteorology instrumentation. TECP is mounted near the end of the 2.3 m Robotic Arm, and can be placed either in the regolith material or held aloft in the atmosphere. This paper describes the development and calibration of the TECP. In addition, substantial characterization of the instrument has been conducted to identify behavioral characteristics that might affect landed surface operations. The greatest potential issue identified in characterization tests is the extraordinary sensitivity of the TECP to placement. Small gaps alter the contact between the TECP and regolith, complicating data interpretation. Testing with the Phoenix Robotic Arm identified mitigation techniques that will be implemented during flight. A flight model of the instrument was also field tested in the Antarctic Dry Valleys during the 2007-2008 International Polar year.