An unrealistic image of science

Many UK secondary schools (ages 11-18) host Open Days for pupils in their final year of primary school education (age 10). At these events science teachers try, through the judicious use of a select number of practical tasks, to portray science as being a fun, exciting and essentially a „hands on‟ activity. Whilst this approach generates short-term situational interest amongst pupils it is ultimately an unrealistic, and arguably unsustainable, image of science

Non-exponential relaxation and hierarchically constrained dynamics in a protein

A scaling analysis within a model of hierarchically constrained dynamics is shown to reproduce the main features of non-exponential relaxation observed in kinetic studies of carbonmonoxymyoglobin.Comment: 4 pages, 3 figures in text. Reference errors have been correcte

On nonlinear viscoelastic deformations - a reappraisal of Fung's quasilinear viscoelastic model

This article offers a reappraisal of Fung's method for quasilinear viscoelasticity. It is shown that a number of negative features exhibited in other works, commonly attributed to the Fung approach, are merely a consequence of the way it has been applied. The approach outlined herein is shown to yield improved behaviour, and offers a straightforward scheme for solving a wide range of models. Results from the new model are contrasted with those in the literature for the case of uniaxial elongation of a bar: for an imposed stretch of an incompressible bar, and for an imposed load. In the last case, a numerical solution to a Volterra integral equation is required to obtain the results. This is achieved by a high order discretisation scheme. Finally, the stretch of a compressible viscoelastic bar is determined for two distinct materials: Horgan-Murphy and Gent

Near IR luminescent rare earth 3,4,5,6-tetrafluoro-2-nitrophenoxide complexes: Synthesis, X-ray crystallography and spectroscopy

NOTICE: this is the author’s version of a work that was accepted for publication in Near IR luminescent rare earth 3,4,5,6-tetrafluoro-2-nitrophenoxide complexes: Synthesis, X-ray crystallography and spectroscopy. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Near IR luminescent rare earth 3,4,5,6-tetrafluoro-2-nitrophenoxide complexes: Synthesis, X-ray crystallography and spectroscopy, [VOL27, ISSUE5, (2008)] DOI: 10.1016/j.poly.2008.01.02

Analytical realization of finite-size scaling for Anderson localization. Does the band of critical states exist for d>2?

An analytical realization is suggested for the finite-size scaling algorithm based on the consideration of auxiliary quasi-1D systems. Comparison of the obtained analytical results with the results of numerical calculations indicates that the Anderson transition point is splitted into the band of critical states. This conclusion is supported by direct numerical evidence (Edwards and Thouless, 1972; Last and Thouless, 1974; Schreiber, 1985; 1990). The possibility of restoring the conventional picture still exists but requires a radical reinterpretetion of the raw numerical data.Comment: PDF, 11 page

Seasonal dynamics of terrestrial vertebrate abundance between Amazonian flooded and unflooded forests

The flood pulse is the main factor structuring and differentiating the ecological communities of Amazonian unflooded (terra firme) and seasonally-flooded (várzea) forests as they require unique adaptations to survive the prolonged annual floods. Therefore, várzea and terra firme forests hammer out a spatio-temporal mosaic of resource availability, which may result in landscape scale seasonal movements of terrestrial vertebrates between adjacent forest types. Yet the lateral movements of terrestrial vertebrates between hydrologically distinct neighbouring forest types exhibiting staggered resource availability remains poorly understood, despite the important implications of this spatial dynamic for the ecology and conservation of forest wildlife. We examined the hypothesis of terrestrial fauna seasonal movements between two adjacent forest types at two contiguous sustainable-use forest reserves in Western Brazilian Amazonia. We used camera trapping data on the overall species richness, composition, and abundance of nine major vertebrate trophic guilds to infer on terrestrial vertebrate movements as a function of seasonal changes in floodplain water level. Species richness differed in neighboring terra firme forests between the high-and low-water phases of the flood pulse and terra firme forests were more species rich than várzea forests. There were clear differences in species composition between both forest types and seasons. Generalized Linear Models showed that water level was the main factor explaining aggregate abundance of all species and three trophic guilds. Our results indicate that the persistence of viable populations of large terrestrial vertebrates adjacent to major Amazonian rivers requires large, well-connected forest landscapes encompassing different forest types to ensure large-scale lateral movements by forest wildlife

Galerkin Method in the Gravitational Collapse: a Dynamical System Approach

We study the general dynamics of the spherically symmetric gravitational collapse of a massless scalar field. We apply the Galerkin projection method to transform a system of partial differential equations into a set of ordinary differential equations for modal coefficients, after a convenient truncation procedure, largely applied to problems of turbulence. In the present case, we have generated a finite dynamical system that reproduces the essential features of the dynamics of the gravitational collapse, even for a lower order of truncation. Each initial condition in the space of modal coefficients corresponds to a well definite spatial distribution of scalar field. Numerical experiments with the dynamical system show that depending on the strength of the scalar field packet, the formation of black-holes or the dispersion of the scalar field leaving behind flat spacetime are the two main outcomes. We also found numerical evidence that between both asymptotic states, there is a critical solution represented by a limit cycle in the modal space with period $\Delta u \approx 3.55$.Comment: 9 pages, revtex4, 10 ps figures; Phys. Rev. D, in pres

The wiener-hopf technique and discretely monitored path-dependent option pricing

Fusai, Abrahams, and Sgarra (2006) employed the Wiener-Hopf technique to obtain an exact analytic expression for discretely monitored barrier option prices as the solution to the Black-Scholes partial differential equation. The present work reformulates this in the language of random walks and extends it to price a variety of other discretely monitored path-dependent options. Analytic arguments familiar in the applied mathematics literature are used to obtain fluctuation identities. This includes casting the famous identities of Baxter and Spitzer in a form convenient to price barrier, first-touch, and hindsight options. Analyzing random walks killed by two absorbing barriers with a modified Wiener-Hopf technique yields a novel formula for double-barrier option prices. Continuum limits and continuity correction approximations are considered. Numerically, efficient results are obtained by implementing Padé approximation. A Gaussian Black-Scholes framework is used as a simple model to exemplify the techniques, but the analysis applies to Lévy processes generally

31P nuclear magnetic resonance and X-ray diffraction study of Na-Sr-phosphate glass-ceramics

A set of Na-Sr-phosphate glass and glass-ceramic samples, with general formula xSrO:(0.55-x)Na2O:0.45P2O5, were prepared and analysed by solid state 31P nuclear magnetic resonance spectroscopy and X-ray powder diffraction. The results show the presence of Q1 and Q2 phosphate species in all samples. At low concentrations of Sr2+ (x £ 0.20) the strontium is preferentially incorporated in Sr2+-Q1 crystalline phases, and only at higher Sr2+ concentrations are crystalline phases present which Sr2+ is associated with Q2 phosphate units