2,628 research outputs found
Interpreting the shifty first person inclusive pronoun in Marathi
In some languages, indexicals (e.g. I, you, today) can shift in attitude reporting clauses to be interpreted with respect to the attitude context rather than the utterance context (Schlenker 1999; Anand & Nevins 2004; Anand 2006; Deal 2020, i.a.). This paper demonstrates that Marathi is a language with shiftable indexicals, but one which exhibits non-canonical properties. First, Marathi indexical shift enables the first person inclusive pronoun, rather than the first person singular pronoun, to refer to the attitude holder. Second, the shifted reading of the first person inclusive pronoun is available in mental attitude reports but not typical speech reports, in apparent violation of Deal’s (2020) and Sundaresan’s (2021) implicational hierarchies of indexical shift licensors. I propose a shifty operator-based analysis (Anand & Nevins 2004; Anand 2006) of this unusual pattern, which has implications for the semantics of mental attitude ascription
Copper Electrodeposition from Deep Eutectic Solvents —Voltammetric Studies Providing Insights into the Role of Substrate: Platinum vs Glassy Carbon
We report on the effect of the substrate on electrochemical deposition of Cu from deep eutectic solvent ethaline. We investigated the polarization behavior during electrodeposition of Cu on Pt and glassy carbon (GC) from both Cu2+ and Cu+ containing ethaline using cyclic voltammetry (CV). Formation of bulk Cu deposits on both substrates underwent nucleation and growth processes; however, the nucleation was considerably sluggish on GC compared to Pt. While experiments in Cu+ solutions indicated that coalescence of Cu islands on Pt is a slow process and that its surface may not be fully covered by Cu, such determination of Cu coverage could not be made on GC. Cu dissolution is also slower from GC than from Pt. It was observed that CV of Cu deposition on GC is influenced by the surface preparation method. Since ethaline has high chloride concentration, a parallel study in aqueous 3 M NaCl solution was conducted in order to examine the influence of the chloride medium on the electrodeposition process. This revealed that electrodeposition in both media occurred in the same manner but with different charge and mass transfer rates caused by the differences in viscosity and chloride concentrations of the two solutions
Electrical behaviour, characteristics and properties of anodic aluminium oxide films coloured by nickel electrodeposition
Porous anodic films on 1050 aluminium substrate were coloured by AC electrodeposition of nickel. Several experiments were performed at different deposition voltages and nickel concentrations in the electrolyte in order to correlate the applied electrical power to the electrical behaviour, as well as the characteristics and properties of the coatings. The content of nickel inside the coatings reached 1.67 g/m2, depending on the experimental conditions. According to the applied AC voltage in comparison with the threshold voltage Ut, the coating either acted only as a capacitor when U\Ut and, when U[Ut, the behaviour during the anodic and cathodic parts of the power sine wave was different. In particular, due to the semi-conducting characteristics of the barrier layer, additional oxidation of the aluminium substrate occurred during the anodic part of the electrical signal, whilst metal deposition (and solvent reduction) occurred during the cathodic part; these mechanisms correspond to the blocked and pass directions of the barrier layer/electrolyte junction, respectively
Understanding the Role of Complexation in the Charge-Transfer Kinetics of the Cu2+ + e ↔ Cu1+ Redox Reaction in Ethaline Deep Eutectic Solvent
Deep eutectic solvent (DES) based electrolytes are gaining attention for electrochemical applications. As such, knowledge of the charge transfer kinetics in DES and its dependence on electrolyte composition and temperature is important. Using Cu2+ + e ↔ Cu1+ as a model system, we demonstrate that metal redox reactions in chloride-containing DES media suffer from sluggish charge transfer kinetics. The exchange current density, i0, displayed a peculiar inverse relationship with the bulk chloride concentration, [Cl−]b. The i0 decreased from 7.9 to 3.0 mA/cm2 when [Cl−]b increased from 2.8 to 4.6 M at 30°C. Such dependence is shown to originate from Cl− complexation with reactant and product species. Furthermore, i0 increased with an increase in Cun+ bulk concentration in the 50–200 mM range. Also, increase in temperature elevated i0. The charge transfer coefficient αc, however, remained constant (∼0.5) and was unaffected by Cun+ or Cl− concentrations or by temperature. To explain how charge transfer kinetics depend on the various system parameters, a model incorporating complexation phenomena was developed and its predictions were compared to experiments
Detection of antibodies directed to the N-terminal region of GAD is dependent on assay format and contributes to differences in the specificity of GAD autoantibody assays for type 1 diabetes
Autoantibodies to glutamate decarboxylase (GADA) are sensitive markers of islet autoimmunity and type 1 diabetes. They form the basis of robust prediction models and are widely used for recruitment of subjects at high risk of type 1 diabetes to prevention trials. However GADA are also found in many individuals at low risk of diabetes progression. To identify the sources of diabetes irrelevant GADA reactivity therefore, we analyzed data from the 2009 and 2010 Diabetes Autoantibody Standardization Program GADA workshop and found that binding of healthy control sera varied according to assay type. Characterization of control sera found positive by radiobinding assay, but negative by ELISA showed that many of these sera reacted to epitopes in the N-terminal region of the molecule. This finding prompted development of an N-terminally truncated GAD65 radiolabel, (35)S-GAD65(96-585), which improved the performance of most GADA radiobinding assays (RBAs) participating in an Islet Autoantibody Standardization Program GADA substudy. These detailed workshop comparisons have identified a source of disease-irrelevant signals in GADA RBAs and suggest that N-terminally truncated GAD labels will enable more specific measurement of GADA in type 1 diabetes
An Efficient Authenticating Short Encrypted Messages Using IND-CPA Algorithms
In today's age of information and technology , many applications can exchange network of information and communication. In Banking , educational, economical area can also exchange the information over the internet. The exchange of information is too risky to work from internet. So many hackers are try to stolen information from the internet. So there is must require data security and integrity over the internet.There are many authentication Technics are in information technology fields. Like HMAC , UMAC, etc.but all this authentication schemes are time consuming and less secure .so we propose more secure and less time consuming authentication codes that are more useful than any other message authentication code in the our literature survey .
DOI: 10.17762/ijritcc2321-8169.15073
Sup3r: A Semi-Supervised Algorithm for increasing Sparsity, Stability, and Separability in Hierarchy Of Time-Surfaces architectures
The Hierarchy Of Time-Surfaces (HOTS) algorithm, a neuromorphic approach for
feature extraction from event data, presents promising capabilities but faces
challenges in accuracy and compatibility with neuromorphic hardware. In this
paper, we introduce Sup3r, a Semi-Supervised algorithm aimed at addressing
these challenges. Sup3r enhances sparsity, stability, and separability in the
HOTS networks. It enables end-to-end online training of HOTS networks replacing
external classifiers, by leveraging semi-supervised learning. Sup3r learns
class-informative patterns, mitigates confounding features, and reduces the
number of processed events. Moreover, Sup3r facilitates continual and
incremental learning, allowing adaptation to data distribution shifts and
learning new tasks without forgetting. Preliminary results on N-MNIST
demonstrate that Sup3r achieves comparable accuracy to similarly sized
Artificial Neural Networks trained with back-propagation. This work showcases
the potential of Sup3r to advance the capabilities of HOTS networks, offering a
promising avenue for neuromorphic algorithms in real-world applications
Avoiding Pitfalls in the Determination of Reliable Electrochemical Kinetics Parameters for the Cu2+ → Cu1+ Reduction Reaction in Deep Eutectic Solvents
Deep eutectic solvents (DES), on account of their low-cost, non-flammability and electrochemical stability, are attracting attention for their potential use in applications such as electrodeposition and energy storage. In these applications, knowledge of the transport and electrochemical kinetics properties of DES is critically important. To date, attempts to measure the kinetics parameters of the Cu2+ +e Cu1+ reaction in ethaline DES have yielded a cathodic charge transfer coefficient (α) in the range of 0.2–0.3 suggesting an unexpected asymmetric polarization behavior. In the present work, we pursued a comprehensive study of the kinetics and transport properties of the aforementioned reaction. Using steady-state and transient polarization measurements on RDE and microelectrodes combined with diffusion-reaction modeling, we demonstrate that the Cu2+/Cu1+ transition exhibits a charge transfer coefficient in the range of 0.49–0.54 and an exchange current density in the range 1.72–1.88 mA/cm2. Recommendations are provided for avoiding pitfalls in kinetics analysis of highly resistive DES electrolytes. These recommendations include the application of accurate IRΩ correction and the use of electrode configurations where the secondary current distribution is relatively uniform
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