Porous LSCF/Dense 3YSZ Interface Fracture Toughness Measured by Single Cantilever Beam Wedge Test

Sandwich specimens were prepared by firing a thin inter-layer of porous La0.6Sr0.4Co0.2Fe0.8O3-d (LSCF) to bond a thin tetragonal yttria-stabilised zirconia (YSZ) beam to a thick YSZ substrate. Fracture of the joint was evaluated by introducing a wedge between the two YSZ adherands so that the stored energy in the thin YSZ cantilever beam drives a stable crack in the adhesive bond and allows the critical energy release rate for crack extension (fracture toughness) to be measured. The crack path in most specimens showed a mixture of adhesive failure (at the YSZ-LSCF interface) and cohesive failure (within the LSCF). It was found that the extent of adhesive fracture increased with firing temperature and decreased with LSCF layer thickness. The adhesive failures were mainly at the interface between the LSCF and the thin YSZ beam and FEM modelling revealed that this is due to asymmetric stresses in the LSCF. Within the firing temperature range of 1000-1150C, the bonding fracture toughness appears to have a strong dependence on firing temperature. However, the intrinsic adhesive fracture toughness of the LSCF/YSZ interface was estimated to be 11 Jm2 and was not firing temperature dependent within the temperature range investigated.Comment: 13 figures, 1 table, journal paper publishe

The Economics of a Centralized Judiciary: Uniformity, Forum Shopping and the Federal Circuit

In 1982, the US Congress established the Court of Appeals for the Federal Circuit (CAFC) as the sole appellate court for patent cases. Ostensibly, this court was created to eliminate inconsistencies in the application and interpretation of patent law across federal courts, and thereby mitigate the incentives of patentees and alleged infringers to "forum shop" for a preferred venue. We perform the first econometric study of the extent of non-uniformity and forum shopping in the pre-CAFC era and of the CAFC's impact on these phenomena. We find that in patentee-plaintiff cases the pre-CAFC era was indeed characterized by significant non-uniformity in patent validity rates across circuits and by forum shopping on the basis of validity rates. We find weak evidence that the CAFC has increased uniformity of validity rates and strong evidence that forum shopping on the basis of validity rates ceased several years prior to the CAFC's establishment. In patentee-defendant cases, we find that validity rates are lower on average, but do not find either significant non-uniformity of validity rates across circuits or significant forum shopping.

LDEF data: Comparisons with existing models

The relationship between the observed cratering impact damage on the Long Duration Exposure Facility (LDEF) versus the existing models for both the natural environment of micrometeoroids and the man-made debris was investigated. Experimental data was provided by several LDEF Principal Investigators, Meteoroid and Debris Special Investigation Group (M&D SIG) members, and by the Kennedy Space Center Analysis Team (KSC A-Team) members. These data were collected from various aluminum materials around the LDEF satellite. A PC (personal computer) computer program, SPENV, was written which incorporates the existing models of the Low Earth Orbit (LEO) environment. This program calculates the expected number of impacts per unit area as functions of altitude, orbital inclination, time in orbit, and direction of the spacecraft surface relative to the velocity vector, for both micrometeoroids and man-made debris. Since both particle models are couched in terms of impact fluxes versus impactor particle size, and much of the LDEF data is in the form of crater production rates, scaling laws have been used to relate the two. Also many hydrodynamic impact computer simulations were conducted, using CTH, of various impact events, that identified certain modes of response, including simple metallic target cratering, perforations and delamination effects of coatings

Damage areas on selected LDEF aluminum surfaces

With the U.S. about to embark on a new space age, the effects of the space environment on a spacecraft during its mission lifetime become more relevant. Included among these potential effects are degradation and erosion due to micrometeoroid and debris impacts, atomic oxygen and ultraviolet light exposure as well as material alteration from thermal cycling, and electron and proton exposure. This paper focuses on the effects caused by micrometeoroid and debris impacts on several LDEF aluminum plates from four different bay locations: C-12, C-10, C-01, and E-09. Each plate was coated with either a white, black, or gray thermal paint. Since the plates were located at different orientations on the satellite, their responses to the hypervelocity impacts varied. Crater morphologies range from a series of craters, spall zones, domes, spaces, and rings to simple craters with little or no spall zones. In addition, each of these crater morphologies is associated with varying damage areas, which appear to be related to their respective bay locations and thus exposure angles. More than 5% of the exposed surface area examined was damaged by impact cratering and its coincident effects (i.e., spallation, delamination and blow-off). Thus, results from this analysis may be significant for mission and spacecraft planners and designers

Evolución morfodinámica de un enclave montañoso recién deglaciado: El caso del Corral del Veleta (Sierra Nevada), ¿Consecuencia del cambio climático?

RESUMEN: El Corral del Veleta (Sierra Nevada. España) cobija en su seno y bajo manto detrítico hielo glaciar fósil y permafrost alpino, restos, como mínimo, de la Pequeña Edad del Hielo (siglos XV/XIX). En la actualidad, estas masas heladas se encuentran en proceso de degradación. Los análisis y controles que desde 2001 se vienen llevando a cabo en un glaciar rocoso incipiente instalado en el tercio oriental del Corral del Veleta muestran procesos continuados de subsidencia de su manto detrítico, apoyado sobre las masas heladas referidas. La merma del manto nival durante el verano, las aguas de fusión y el grado de penetración de la onda de radiación externa en el suelo, son parámetros clave que explican este mecanismo de subsidencia, que podría estar relacionado con variaciones climáticas que vienen detectándose desde hace décadas

Peak Oxygen Uptake in Chronic Fatigue Syndrome/Myalgic Encephalomyelitis::A Meta-Analysis

To evaluate the magnitude of the difference in VO2peak between patients with Chronic Fatigue Syndrome/ Myalgic Encephalomyelitis (CFS/ME) and apparently healthy controls, 7 databases (Cochrane, PubMed, PsycINFO, Web of Knowledge, Embase, Scopus, Medline) were searched for articles published up to March 2018. Search terms included “chronic fatigue syndrom*”AND (“peak” OR “maxim*” OR “max”) AND (“oxygen uptake” OR “oxygen consumption” OR “VO2peak” or “VO2max”. Eligibility criteria were adults>18 y with clinically diagnosed CFS/ME, with VO2peak measured in a maximal test and compared against an apparently healthy control group. The methodological quality of included studies was assessed using a modified Systematic Appraisal of Quality for Observational Research critical appraisal framework. A random effects meta-analysis was conducted on 32 cross-sectional studies (effects). Pooled mean VO2peak was 5.2 (95% CI: 3.8–6.6) ml.kg−1min−1 lower in CFS/ME patients vs. healthy controls. Between-study variability (Tau) was 3.4 (1.5–4.5) ml.kg−1min−1 indicating substantial heterogeneity. The 95% prediction interval was −1.9 to 12.2 ml.kg−1min−1. The probability that the effect in a future study would be>the minimum clinically important difference of 1.1 ml.kg−1min−1 (in favour of controls) was 0.88 – likely to be clinically relevant. Synthesis of the available evidence indicates that CFS/ME patients have a substantially reduced VO2peak compared to controls