The activation of hydrogen by excited mercury atoms

That mercury atoms excited by absorption of the line 2537Å are able to activate various kinds of atoms by collisions of the second kind has been shown in several different ways. Using pressure measurements to follow the reaction, Cario and Franck (1) showed that hydrogen, in the presence of excited mercury vapor, can be activated and made to reduce copper oxide or tungsten oxide, while Dickinson (2) repeated the experiment using gaseous oxygen instead of solid oxide. Employing spectroscopic methods of detection, Cario (3) activated thallium vapor by collisions with excited mercury atoms and observed the radiation of the green thallium line 5351 Å and indeed all the thallium lines which would theoretically be expected

Financial Health of U.S. Farm Businesses in 1984 - A Region, Type and Size Analysis

Exact date of working paper unknown.Liquidity, solvency, and profitability indicators are used to develop a multi-dimensional ordinal measure of farm business financial health. Weighted ordinal logistic regression is employed to examine farm business financial health relative to region, type and size of farm. Findings suggest the "farm crisis" in 1984 was more severe from a farm business perspective than previously reported

Forcing and response in simulated 20th and 21st century surface energy and precipitation trends

A simple methodology is applied to a transient integration of the Met Office Hadley Centre Global Environmental Model version1 (UKMO-HadGEM1) fully coupled atmosphere-ocean general circulation model in order to separate forcing from climate response in simulated 20th century and future global mean surface energy and precipitation trends. Forcings include any fast responses that are caused by the forcing agent and that are independent of global temperature change. Results reveal that surface radiative forcing is dominated by shortwave forcing over the 20th and 21st centuries, which is strongly negative. However, when fast responses of surface turbulent heat fluxes are separated from climate feedbacks, and included in the forcing, net surface forcing becomes positive. The nonradiative forcings are the result of rapid surface and tropospheric adjustments and impact 20th century, as well as future, evaporation and precipitation trends. A comparison of energy balance changes in eight different climate models finds that all models exhibit a positive surface energy imbalance by the late 20th century. However, there is considerable disagreement in how this imbalance is partitioned between the longwave, shortwave, latent heat and sensible heat fluxes. In particular, all models show reductions in shortwave radiation absorbed at the surface by the late 20th century compared to the pre-industrial control state, but the spread of this reduction leads to differences in the sign of their latent heat flux changes and thus in the sign of their hydrological responses

Organometallic mediated radical polymerization

Controlled radical polymerization has become increasingly important over the past decade and a half, allowing for the facile synthesis of specific macromolecular architectures with excellent control over the chemical and physical properties. This article presents an organized and detailed review of one particular CRP technique, organometallic mediated radical polymerization (OMRP), focusing on the individual catalysts developed, their efficacy and monomer scope. Rhodium, cobalt, molybdenum, osmium, iron, palladium, titanium, chromium and vanadium mediated radical polymerizations are presented alongside organo-main group mediated reactions. A separate section reviews the types of copolymers which have been synthesized using OMRP techniques. An attempt is made to unify the many disparate names which have previously been used for OMRP by virtue of the common mechanistic aspects displayed by the different catalyst systems. A mechanistic discussion highlights the similarities and differences between these systems and examines the interplay between reversible termination and degenerative transfer OMRP and competing 1-electron redox processes

Multi-satellite observed responses of precipitation and its extremes to interannual climate variability

The consistency of precipitation variability estimated from the multiple satellite-based observing systems is assessed. There is generally good agreement between TRMM TMI, SSM/I, GPCP and AMSRE datasets for the inter-annual variability of precipitation since 1997 but the HOAPS dataset appears to overestimate the magnitude of variability. Over the tropical ocean the TRMM 3B42 dataset produces unrealistic variabilitys. Based upon deseasonalised GPCP data for the period 1998-2008, the sensitivity of global mean precipitation (P) to surface temperature (T) changes (dP/dT) is about 6%/K, although a smaller sensitivity of 3.6%/K is found using monthly GPCP data over the longer period 1989-2008. Over the tropical oceans dP/dT ranges from 10-30%/K depending upon time-period and dataset while over tropical land dP/dT is -8 to -11%/K for the 1998-2008 period. Analyzing the response of the tropical ocean precipitation intensity distribution to changes in T we find the wetter area P shows a strong positive response to T of around 20%/K. The response over the drier tropical regimes is less coherent and varies with datasets, but responses over the tropical land show significant negative relationships over an interannual time-scale. The spatial and temporal resolutions of the datasets strongly influence the precipitation responses over the tropical oceans and help explain some of the discrepancy between different datasets. Consistency between datasets is found to increase on averaging from daily to 5-day time-scales and considering a 1o (or coarser) spatial resolution. Defining the wet and dry tropical ocean regime by the 60th percentile of P intensity, the 5-day average, 1o TMI data exhibits a coherent drying of the dry regime at the rate of -20%/K and the wet regime becomes wetter at a similar rate with warming

ESDIS Standards Office (ESO): Requirements, Standards and Practices

The ESDIS Standards Office assists the ESDIS Project in formulating standards policy for NASA Earth Science Data Systems (ESDS), coordinates standards activities within ESDIS, and provides technical expertise and assistance with standards related tasks within the NASA Earth Science Data System Working Groups (ESDSWG). This poster summarizes information found on the earthdata.nasa.gov site that describes the ESO

GPS phase scintillation associated with optical auroral emissions:first statistical results from the geographic South Pole

Ionospheric irregularities affect the propagation of Global Navigation Satellite System (GNSS) signals, causing radio scintillation. Particle precipitation from the magnetosphere into the ionosphere, following solar activity, is an important production mechanism for ionospheric irregularities. Particle precipitation also causes the aurorae. However, the correlation of aurorae and GNSS scintillation events is not well established in literature. This study examines optical auroral events during 2010-2011 and reports spatial and temporal correlations with Global Positioning System (GPS) L1 phase fluctuations using instrumentation located at South Pole Station. An all-sky imager provides a measure of optical emission intensities ([OI] 557.7nm and 630.0nm) at auroral latitudes during the winter months. A collocated GPS antenna and scintillation receiver facilitates superimposition of auroral images and GPS signal measurements. Correlation statistics are produced by tracking emission intensities and GPS L1 sigma indices at E and F-region heights. This is the first time that multi-wavelength auroral images have been compared with scintillation measurements in this way. Correlation levels of up to 74% are observed during 2-3hour periods of discrete arc structuring. Analysis revealed that higher values of emission intensity corresponded with elevated levels of sigma. The study has yielded the first statistical evidence supporting the previously assumed relationship between the aurorae and GPS signal propagation. The probability of scintillation-induced GPS outages is of interest for commercial and safety-critical operations at high latitudes. Results in this paper indicate that image databases of optical auroral emissions could be used to assess the likelihood of multiple satellite scintillation activity

Are Nudges for Alternative Transit Persistent?

The benefits of converting single-person drivers to alternative transit options are well-established. One option to accomplish this is for employers to provide alternative commute incentive programs. However, the research on the implementation of such programs is lacking. To provide a test, this research analyzes data obtained from a field experiment on daily alternative transit commute choices for a seven-month period. Participants are divided into four treatment groups in a two-by-two design for the first three-month period: incentives with either loss or gain framing, and messaging nudges with either the private or public benefits of alternative transit commute choices. The participants then continue in the field experiment for the remaining four-month period with all groups receiving only gain framing incentives and messaging nudges are discontinued. The results from the two time periods are compared. Loss framing and private messaging have the most significant effect on participants’ decisions to revert back to single-person driving when nudges are discontinued, and thus nudges are not persistent. The incentive program did not provide enduring conversion to alternative transit options, but the results suggest employers who want to optimize their alternative transit incentive programs should utilize loss framing incentives and combine both private and public messaging into continuous nudges

Evaluation of alternative solvents in common amide coupling reactions : replacement of dichloromethane and N,N-dimethylformamide

A range of alternative solvents have been evaluated within amidation reactions employing common coupling reagents with a view to identifying suitable replacements for dichloromethane and N,N-dimethylformamid