Yang-Lee zeros and the helix-coil transition in a continuum model of polyalanine

We calculate the Yang-Lee zeros for characteristic temperatures of the helix-coil transition in a continuum model of polyalanine. The distribution of these zeros differs from predictions of the Zimm-Bragg theory and supports recent claims that polyalanine exhibits a true phase transition. New estimates for critical exponents are presented and the relation of our results to the Lee-Yang theorem is discussed.Comment: 15 pages and 5 figure

Structural and optical properties of Zn0.9 Mn0.1 O/ZnO core-shell nanowires designed by pulsed laser deposition

Partilhar documento na coleção da comunidade Laboratório Associado I3NCore-shell ZnO/ZnMnO nanowires on a-Al2O3 and GaN (buffer layer)/Si (111) substrates were fabricated by pulsed laser deposition using a Au catalyst. Two ZnO targets with a Mn content of 10% were sintered at 1150 and 550 °C in order to achieve the domination in them of paramagnetic MnO2 and ferromagnetic Mn2O3 phases, respectively. Cluster mechanism of laser ablation as a source of possible incorporation of secondary phases to the wire shell is discussed. Raman spectroscopy under excitation by an Ar+ laser revealed a broad peak related to the Mn-induced disorder and a redshift in the A1-LO phonon. Resonant Raman measurements revealed an increase in the multiphonon scattering caused by disorder in ZnO upon doping by Mn. Besides the UV emission, a vibronic green emission band assisted by a ∼ 71 meV LO phonon is also observed in the photoluminescence spectra. Core-shell structures with smooth shells show a high exciton to green band intensity ratio ( ∼ 10) even at room temperature. © 2009 American Institute of PhysicsSANDiE Network of Excellence of the EUFCT-PTDC/FIS/72843/200

Structural transitions in biomolecules - a numerical comparison of two approaches for the study of phase transitions in small systems

We compare two recently proposed methods for the characterization of phase transitions in small systems. The usefulness of these techniques is evaluated for the case of structural transition in alanine-based peptides.Comment: Accepted for publication in Int. J. Mol. Sci., to appear in a special issue devoted to R.S. Berr

Helix Formation and Folding in an Artificial Peptide

We study the relation between $\alpha$-helix formation and folding for a simple artificial peptide, Ala$_{10}$-Gly$_5$-Ala$_{10}$. Our data rely on multicanonical Monte Carlo simulations where the interactions among all atoms are taken into account. The free-energy landscape of the peptide is evaluated for various temperatures. Our data indicate that folding of this peptide is a two-step process: in a first step two $\alpha$-helices are formed which afterwards re-arrange themselves into a U-like structure.Comment: 15 pages, with 9 eps figure

DC magnetic field generation in unmagnetized shear flows

The generation of DC magnetic fields in unmagnetized plasmas with velocity shear is predicted for non relativistic and relativistic scenarios either due to thermal effects or due to the onset of the Kelvin-Helmholtz instability (KHI). A kinetic model describes the growth and the saturation of the DC field. The predictions of the theory are confirmed by multidimensional particle-in-cell simulations, demonstrating the formation of long lived magnetic fields ($t \sim 100s \omega_{pi}^{-1}$) along the full longitudinal extent of the shear layer, with transverse width on the electron length scale ($\sqrt{\gamma_0}c/\omega_{pe}$), reaching magnitudes $eB_{\mathrm{DC}}/m_ec\omega_{pe}\sim \beta_0\sqrt{\gamma_0}$

A low-mass stellar companion of the planet host star HD75289

We report on the detection of a new low-mass stellar companion of HD75289, a G0V star that harbors one known radial-velocity planet (Udry et al. 2000). Comparing an image of 2MASS with an image we obtained with SofI at the ESO 3.58m NTT three years later, we detected a co-moving companion located 21.465+-0.023arcsecs (621+-10AU at 29pc) east of HD75289. A second SofI image taken 10 months later confirmed the common proper motion of HD75289B with its host star. The infrared spectrum and colors of the companion are consistent with an M2 to M5 main-sequence star at the distance of HD75289. No further (sub)stellar companion down to H = 19mag could be detected. With the SofI detection limit we can rule out additional stellar companions beyond 140AU and substellar companions with masses m > 0.050Msun from 400AU up to 2000AU.Comment: accepted in A&