The roots of cooperative credit from a theoretical and historical perspective

Credit is indubitably one of the most important sectors in which the supply of goods and services by cooperatives has arisen. Given the importance of the role of cooperative banks in the development of other sectors and of the territories or communities in which they operate, and the economic and political power that they consequently confer on those who manage them, some of the inherent problems distinctive in general of not-for-profit organizations become critical. In particular: in the case of rapid growth beyond the original group and area, the possibility of maintaining the principles of reciprocity and participation; the role and motivations of the social entrepreneurs acting in the bank; the corporate social responsibility, which, in the case of a bank, is closely connected to how the community’s savings are employed and how investments are selected. As with other cooperative enterprises, credit can be supplied in a variety of forms with different purposes and with different positive and/or negative externalities. Evaluation of the respective advantages and disadvantages must bear in mind the different contexts in which individual banks operate, considering both theoretical aspects (potentialities) and historical ones (past and present modes of operation). These inherent problems are discussed in the first part of the work from a theoretical point of view; while in the second part the first applications and the debate that accompanied them are analysed, given their importance in determining the features of subsequent experiences. In particular, we shall show that they stem from two different interpretations of solidarity and reciprocity: the first one, theorized and, to a certain extent, realized in the Raiffeisen model, is mainly ethical in nature; the second one, typical of the Schulze Delitzsch model, is more closely tied to individual interests tempered by social responsibility.

E-NEWTRIENTS: BIOELECTROCHEMICAL SYSTEMS AT THE SERVICE OF AGRICULTURAL SCIENCES

It is estimated that demand for food will continue to increase, as a result of population growth, but at the same time, food production will increasingly face huge constraints, such as water scarcity, soil desertification and the increase of fertilizers prices. Wastewater derived from food production chains should be treated in a sustainable way, to minimize environmental contamination, while maximizing the recovery of valuable fractions, such as plant nutrients. Bioelectrochemical systems (BES) have been proposed as solutions to treat different kinds of wastewaters and recover nutrients through bio-electrochemical reactions. In my project, new types of BES are studied, fabricated with biocompatible and biogenic materials starting from vegetable scraps, which could be applied as mean of organic matter and nutrients recovery from organic-rich wastewater streams coming from important agro-food chains, such as farming and agro-industrial productions. This novel type of BES was named ‘microbial recycling cells’ (MRCs). Biochar produced from controlled pyrolysis of plant materials is electro-conductive and can be used as base to fabricate MRCs, which can be used for this scope. Other materials like earthenware were also used in MRCs architectures, as electrolytic conductors and structural frames. After being enriched of nutrients from wastewaters, biochar-based MRCs can be fully recycled to produce soil improvers and renewable fertilizers. In soil applications, the electrochemical properties of biochar influence soil biogeochemical reactions, with important implications in plant nutrition and the environmental implications of soil-plant systems (e.g. carbon sequestration, CH4 emissions, etc.). The PhD project was hold in 3 different work packages: WP1) Selection of MRC architectures and optimization of e-biochar properties, WP2) Study of the microbial electrochemical processes driving nutrients deposition, WP3) Study of the properties of nutrients-enriched biochar derived from MRC after their life-cycle, as soil improvers of agricultural soil fertility, with both amending and fertilizing properties

Livestock and climate change: impact of livestock on climate and mitigation strategies

Introduction: According to the United Nations (UN, 2017), the world population increased by approximately 1 billion inhabitants during the last 12 years, reaching nearly 7.6 billion in 2017. Although this growth is slower than 10 years ago (1.24% vs. 1.10% per year), with an average increase of 83 million people annually, global population will reach about 8.6 billion in 2030 and 9.8 billion in 2050. Population growth, urbanization, and income rise in developing countries are the main driver of the increased demand for livestock products (UN, 2017). The livestock sector requires a significant amount of natural resources and is responsible for about 14.5% of total anthropogenic greenhouse gas emissions (7.1 Gigatonnes of carbon dioxide equivalents for the year 2005; Gerber et al., 2013). Mitigation strategies aimed at reducing emissions of this sector are needed to limit the environmental burden from food production while ensuring a sufficient supply of food for a growing world population. The objectives of this manuscript are to 1) discuss the main greenhouse gas emissions sources from the livestock sector and 2) summarize the best mitigation strategies

Electroactive Biochar for Large-Scale Environmental Applications of Microbial Electrochemistry

Large-scale environmental applications of microbial electrochemical technologies (MET), such as wastewater treatment, bioremediation, or soil improvement, would be more feasible if bioelectrodes could be fabricated with simpler materials. Biochar with potentially improved electroactive properties (e-biochar) can be an ideal candidate for this scope, being at the same time widely available, biocompatible, and fully recyclable at its end-of-life as a soil amendment. Here we review the application of biochar to MET, to set benchmarks aimed at tuning the electroactive properties of such materials from the point of view of MET. The precursor biomass, thermochemical process conditions, and pre-, in situ-, and/or post-treatments should tailor optimized combinations of electrical conductivity, capacitance, superficial redox-active and electroactive functional groups, porosity distribution, and capacity to host electroactive microbial communities. We also discuss methods to rigorously characterize e-biochar properties and the most relevant multidisciplinary research challenges toward its application in large-scale MET.This work has been financed by the Italian Ministry of University and Research (MIUR), within the SIR2014 Grant, project RBSI14JKU3. Dr. R. Berenguer also thanks the Spanish Ministerio de Economía y Competitividad and FEDER funds (RYC-2017-23618 and CTM2015-71520-C2-1-R) for financial support. Ricardo Louro and Catarina Paquete thank Fundação para a Ciência e a Tecnologia (FCT) Portugal [PTDC/BBBBQB/4178/2014 and PTDC/BIA-BQM/30176/2017], by Project LISBOA-01-0145-FEDER-007660 (Microbiologia Molecular, Estrutural e Celular) funded by FEDER funds through COMPETE2020 - Programa Operacional Competitividade e Internacionalização (POCI), and by ITQB research unit GREEN-it “Bioresources for sustainability” (UID/Multi/04551/2013). This work has also received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 810856. This investigation has also received funding from the European Union’s Horizon 2020 research and innovation programme under the grant agreement No. 642190 (Project “iMETLAND”; http://www.imetland.eu)

Removal of Hepatitis B virus surface HBsAg and core HBcAg antigens using microbial fuel cells producing electricity from human urine

© 2019, The Author(s). Microbial electrochemical technology is emerging as an alternative way of treating waste and converting this directly to electricity. Intensive research on these systems is ongoing but it currently lacks the evaluation of possible environmental transmission of enteric viruses originating from the waste stream. In this study, for the first time we investigated this aspect by assessing the removal efficiency of hepatitis B core and surface antigens in cascades of continuous flow microbial fuel cells. The log-reduction (LR) of surface antigen (HBsAg) reached a maximum value of 1.86 ± 0.20 (98.6% reduction), which was similar to the open circuit control and degraded regardless of the recorded current. Core antigen (HBcAg) was much more resistant to treatment and the maximal LR was equal to 0.229 ± 0.028 (41.0% reduction). The highest LR rate observed for HBsAg was 4.66 ± 0.19 h−1 and for HBcAg 0.10 ± 0.01 h−1. Regression analysis revealed correlation between hydraulic retention time, power and redox potential on inactivation efficiency, also indicating electroactive behaviour of biofilm in open circuit control through the snorkel-effect. The results indicate that microbial electrochemical technologies may be successfully applied to reduce the risk of environmental transmission of hepatitis B virus but also open up the possibility of testing other viruses for wider implementation

The Mediterranean Forecasting System – Part 1: Evolution and performance

The Mediterranean Forecasting System produces operational analyses and reanalyses and 10 d forecasts for many essential ocean variables (EOVs), from currents, temperature, salinity, and sea level to wind waves and pelagic biogeochemistry. The products are available at a horizontal resolution of 1/24∘ (approximately 4 km) and with 141 unevenly spaced vertical levels. The core of the Mediterranean Forecasting System is constituted by the physical (PHY), the biogeochemical (BIO), and the wave (WAV) components, consisting of both numerical models and data assimilation modules. The three components together constitute the so-called Mediterranean Monitoring and Forecasting Center (Med-MFC) of the Copernicus Marine Service. Daily 10 d forecasts and analyses are produced by the PHY, BIO, and WAV operational systems, while reanalyses are produced every ∼ 3 years for the past 30 years and are extended (yearly). The modelling systems, their coupling strategy, and their evolutions are illustrated in detail. For the first time, the quality of the products is documented in terms of skill metrics evaluated over a common 3-year period (2018–2020), giving the first complete assessment of uncertainties for all the Mediterranean environmental variable analyses.</p

Testing novel multicomposite materials for electromethanogenesis

Electromethanogenesis is an innovative technology that uses a microbial electrochemical system to produce methane from CO2, in a power-to-gas (BEP2G) concept. The results of experimental tests of new and cost-effective carbonaceous materials for electrode are presented here. The study aims at optimizing electromethanogenesis processes at laboratory level in mesothermic condition. As part of the experiments, hydrogenotrophic microorganisms (Family Metanobacteriaceae of Archaea domains) were selected from a mixed consortium taken from a biogas digestate and inoculated in double-chamber bioelectrochemical systems. The maximum amount of methane produced was 0.3 - 0.8 mol/m2g (normalized to the cathode area) with carbon cloth electrodes. Aiming at improving the methane productivity, innovative materials for the electrodes were now studied, creating porous high-surface composites, and studying nitrogen carbons doped with Cu and hydroxyapatite (Multicomposite Cu@/HAP/C), as chemical catalysts for CO2 reduction (CO2RR). The description of the procedure for the Multicomposite Cu@/HAP/C production is reported in detail.</jats:p

EXPERIMENTAL ASSESSMENT OF THE DYNAMIC BEHAVIOR OF POLYOLEFIN THERMOPLASTIC HOT MELT ADHESIVE

In the last decades, the use of adhesives has rapidly increased in many industrial fields. Adhesive joints are often preferred to traditional fasteners due to the many advantages that they offer. For instance, adhesive joints show a better stress distribution compared to the traditional fasteners and high mechanical properties under different loading conditions. Furthermore, they are usually preferred for joining components made of different materials. A wide variety of adhesives is currently available: thermoset adhesives are generally employed for structural joints but recently there has been a significant increment in the use of thermoplastic adhesives, in particular of the hot-melt adhesives (HMAs). HMAs permit to bond a large number of materials, including metal and plastics (e.g., polypropylene, PP), which can be hardly bonded with traditional adhesives. Furthermore, HMAs are characterized by a short open time and, therefore, permit for a quick and easy assembly process since they can be easily spread on the adherend surfaces by means of a hot-melt gun and they offer the opportunity of an ease disassembling process for repair and recycle. For all these reasons, HMAs are employed in many industrial applications and are currently used also for bonding polypropylene and polyolefin piping systems. In the present paper, the dynamic response of single lap joints (SLJ) obtained by bonding together with a polyolefin HMA two polypropylene substrates was experimentally assessed. Quasi-static tests and dynamic tests were carried out to investigate the strain rate effect: dynamic tests were carried out with a modified instrumented impact pendulum. Relevant changes in the joint performance have been put in evidence. Failure modes were finally analysed and compared. A change in the failure mode is experimentally found: in quasi-static tests SLJ failed due to a cohesive failure of the adhesive, whereas in dynamic tests the SLJ failed due to an interfacial failure, with a low energy absorption