507 research outputs found

    Coherent generation of symmetry-forbidden phonons by light-induced electron-phonon interactions in magnetite

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    Symmetry breaking across phase transitions often causes changes in selection rules and emergence of optical modes which can be detected via spectroscopic techniques or generated coherently in pump-probe experiments. In second-order or weakly first-order transitions, fluctuations of the order parameter are present above the ordering temperature, giving rise to intriguing precursor phenomena, such as critical opalescence. Here, we demonstrate that in magnetite (Fe3_3O4_4) light excitation couples to the critical fluctuations of the charge order and coherently generates structural modes of the ordered phase above the critical temperature of the Verwey transition. Our findings are obtained by detecting coherent oscillations of the optical constants through ultrafast broadband spectroscopy and analyzing their dependence on temperature. To unveil the coupling between the structural modes and the electronic excitations, at the origin of the Verwey transition, we combine our results from pump-probe experiments with spontaneous Raman scattering data and theoretical calculations of both the phonon dispersion curves and the optical constants. Our methodology represents an effective tool to study the real-time dynamics of critical fluctuations across phase transitions

    Attosecond streaking of photoelectron emission from disordered solids

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    Attosecond streaking of photoelectrons emitted by extreme ultraviolet light has begun to reveal how electrons behave during their transport within simple crystalline solids. Many sample types within nanoplasmonics, thin-film physics, and semiconductor physics, however, do not have a simple single crystal structure. The electron dynamics which underpin the optical response of plasmonic nanostructures and wide-bandgap semiconductors happen on an attosecond timescale. Measuring these dynamics using attosecond streaking will enable such systems to be specially tailored for applications in areas such as ultrafast opto-electronics. We show that streaking can be extended to this very general type of sample by presenting streaking measurements on an amorphous film of the wide-bandgap semiconductor tungsten trioxide, and on polycrystalline gold, a material that forms the basis of many nanoplasmonic devices. Our measurements reveal the near-field temporal structure at the sample surface, and photoelectron wavepacket temporal broadening consistent with a spread of electron transport times to the surface

    Philosophical, Legal, and Social Rationales for Appropriating the Tribal Estate, 1607 to1980

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    The old drama and the new: conceptions of the nature of the theatrical experience in the work of William Archer, G.B. Shaw, W.B. Yeats, E.G. Craig and H. Granville-Barker.

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    PhDTwo opposing philosophical outlooks can be discerned in the thought of the men discussed in this dissertation.. The humanist view, associated with Archer and Barker, sees life as centred solely on man; the religious thinkers, Yeats and Craig, are concerned with man's relationship with a power beyond himself. Shaw is unique in his advocacy of contradictory elements from both philosophies. The humanist thinkers are concerned in art with the communication of information about man; those of the religious party value an indescribable experience communicated by artistic symbols. These two kinds of communication can perhaps be seen in the English theatre of the nineteenth century; the theatre of the early part of the century made use of a traditional language of theatrical symbols, while the later theatres of Irving and the Bancrofts abandoned tradition in favour of new "realistic" portrayals of society and human psychology. Archer illustrates the humanist approach to art in his concern for the moral and psychological information conveyed by the play. In his humanist guise, Shaw emphasizes the need for drama to convey new social and philosophical ideas. For Barker, drama conveys, through the medium of the actor, a special kind of "subjective" truth. Each of the religious theorists seeks symbolic value in a different facet of the theatrical performance;, for Yeats, the religious communication is achieved by the traditional symbols of poetry; for Shaw, in his religious guise, the performer is the prime source of symbolic value; for Craig, purely visual symbols of natural process provide a glimpse of a world untainted by man's egotism. The theories are open to criticism. The humanist theories seem to deny the value of artistic form, while the religious theories seem to seek form without content. All the theories seem to show insufficient respect for the laws of audience psychology
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