Sensing of single nuclear spins in random thermal motion with proximate nitrogen-vacancy centers

Nitrogen-vacancy (NV) centers in diamond have emerged as valuable tools for sensing and polarizing spins. Motivated by potential applications in chemistry, biology, and medicine, we show that NV-based sensors are capable of detecting single spin targets even if they undergo diffusive motion in an ambient thermal environment. Focusing on experimentally relevant diffusion regimes, we derive an effective model for the NV-target interaction, where parameters entering the model are obtained from numerical simulations of the target motion. The practicality of our approach is demonstrated by analyzing two realistic experimental scenarios: (i) time-resolved sensing of a fluorine nuclear spin bound to an N-heterocyclic carbene-ruthenium (NHC-Ru) catalyst that is immobilized on the diamond surface and (ii) detection of an electron spin label by an NV center in a nanodiamond, both attached to a vibrating chemokine receptor in thermal motion. We find in particular that the detachment of a fluorine target from the NHC-Ru carrier molecule can be monitored with a time resolution of a few seconds.Comment: 14 pages, 8 figures, supplemental materia

Cosmic Topology of Polyhedral Double-Action Manifolds

A special class of non-trivial topologies of the spherical space S^3 is investigated with respect to their cosmic microwave background (CMB) anisotropies. The observed correlations of the anisotropies on the CMB sky possess on large separation angles surprising low amplitudes which might be naturally be explained by models of the Universe having a multiconnected spatial space. We analysed in CQG 29(2012)215005 the CMB properties of prism double-action manifolds that are generated by a binary dihedral group D^*_p and a cyclic group Z_n up to a group order of 180. Here we extend the CMB analysis to polyhedral double-action manifolds which are generated by the three binary polyhedral groups (T^*, O^*, I^*) and a cyclic group Z_n up to a group order of 1000. There are 20 such polyhedral double-action manifolds. Some of them turn out to have even lower CMB correlations on large angles than the Poincare dodecahedron

How well-proportioned are lens and prism spaces?

The CMB anisotropies in spherical 3-spaces with a non-trivial topology are analysed with a focus on lens and prism shaped fundamental cells. The conjecture is tested that well proportioned spaces lead to a suppression of large-scale anisotropies according to the observed cosmic microwave background (CMB). The focus is put on lens spaces L(p,q) which are supposed to be oddly proportioned. However, there are inhomogeneous lens spaces whose shape of the Voronoi domain depends on the position of the observer within the manifold. Such manifolds possess no fixed measure of well-proportioned and allow a predestined test of the well-proportioned conjecture. Topologies having the same Voronoi domain are shown to possess distinct CMB statistics which thus provide a counter-example to the well-proportioned conjecture. The CMB properties are analysed in terms of cyclic subgroups Z_p, and new point of view for the superior behaviour of the Poincar\'e dodecahedron is found

Spectral Statistics in the Quantized Cardioid Billiard

The spectral statistics in the strongly chaotic cardioid billiard are studied. The analysis is based on the first 11000 quantal energy levels for odd and even symmetry respectively. It is found that the level-spacing distribution is in good agreement with the GOE distribution of random-matrix theory. In case of the number variance and rigidity we observe agreement with the random-matrix model for short-range correlations only, whereas for long-range correlations both statistics saturate in agreement with semiclassical expectations. Furthermore the conjecture that for classically chaotic systems the normalized mode fluctuations have a universal Gaussian distribution with unit variance is tested and found to be in very good agreement for both symmetry classes. By means of the Gutzwiller trace formula the trace of the cosine-modulated heat kernel is studied. Since the billiard boundary is focusing there are conjugate points giving rise to zeros at the locations of the periodic orbits instead of exclusively Gaussian peaks.Comment: 20 pages, uu-encoded ps.Z-fil

Level spacings and periodic orbits

Starting from a semiclassical quantization condition based on the trace formula, we derive a periodic-orbit formula for the distribution of spacings of eigenvalues with k intermediate levels. Numerical tests verify the validity of this representation for the nearest-neighbor level spacing (k=0). In a second part, we present an asymptotic evaluation for large spacings, where consistency with random matrix theory is achieved for large k. We also discuss the relation with the method of Bogomolny and Keating [Phys. Rev. Lett. 77 (1996) 1472] for two-point correlations.Comment: 4 pages, 2 figures; major revisions in the second part, range of validity of asymptotic evaluation clarifie

Cosmic microwave anisotropies in an inhomogeneous compact flat universe

The anisotropies of the cosmic microwave background (CMB) are computed for the half-turn space E_2 which represents a compact flat model of the Universe, i.e. one with finite volume. This model is inhomogeneous in the sense that the statistical properties of the CMB depend on the position of the observer within the fundamental cell. It is shown that the half-turn space describes the observed CMB anisotropies on large scales better than the concordance model with infinite volume. For most observer positions it matches the temperature correlation function even slightly better than the well studied 3-torus topology

A measure on the set of compact Friedmann-Lemaitre-Robertson-Walker models

Compact, flat Friedmann-Lemaitre-Robertson-Walker (FLRW) models have recently regained interest as a good fit to the observed cosmic microwave background temperature fluctuations. However, it is generally thought that a globally, exactly-flat FLRW model is theoretically improbable. Here, in order to obtain a probability space on the set F of compact, comoving, 3-spatial sections of FLRW models, a physically motivated hypothesis is proposed, using the density parameter Omega as a derived rather than fundamental parameter. We assume that the processes that select the 3-manifold also select a global mass-energy and a Hubble parameter. The inferred range in Omega consists of a single real value for any 3-manifold. Thus, the obvious measure over F is the discrete measure. Hence, if the global mass-energy and Hubble parameter are a function of 3-manifold choice among compact FLRW models, then probability spaces parametrised by Omega do not, in general, give a zero probability of a flat model. Alternatively, parametrisation by the injectivity radius r_inj ("size") suggests the Lebesgue measure. In this case, the probability space over the injectivity radius implies that flat models occur almost surely (a.s.), in the sense of probability theory, and non-flat models a.s. do not occur.Comment: 19 pages, 4 figures; v2: minor language improvements; v3: generalisation: m, H functions of

Hot pixel contamination in the CMB correlation function?

Recently, it was suggested that the map-making procedure, which is applied to the time-ordered CMB data by the WMAP team, might be flawed by hot pixels. This could lead to a bias in the pixels having an angular distance of about 141 degrees from hot pixels due to the differential measuring process of the satellite WMAP. Here, the bias is confirmed, and the temperature two-point correlation function C(theta) is reevaluated by excluding the affected pixels. It is shown that the most significant effect occurs in C(theta) at the largest angles near theta = 180 degrees. Furthermore, the corrected correlation function C(theta) is applied to the cubic topology of the Universe, and it is found that such a multi-connected universe matches the temperature correlation better than the LCDM concordance model, provided the cubic length scale is close to L=4 measured in units of the Hubble length

Supernovae observations and cosmic topology

Two fundamental questions regarding our description of the Universe concern the geometry and topology of its 3-dimensional space. While geometry is a local characteristic that gives the intrinsic curvature, topology is a global feature that characterizes the shape and size of the 3-space. The geometry constrains, but does not dictate the the spatial topology. We show that, besides determining the spatial geometry, the knowledge of the spatial topology allows to place tight constraints on the density parameters associated with dark matter ($\Omega_m$) and dark energy ($\Omega_{\Lambda}$). By using the Poincar\'e dodecahedral space as the observable spatial topology, we reanalyze the current type Ia supenovae (SNe Ia) constraints on the density parametric space $\Omega_{m} - \Omega_{\Lambda}$. From this SNe Ia plus cosmic topology analysis, we found best fit values for the density parameters, which are in agreement with a number of independent cosmological observations.Comment: 5 pages, 2 figures. Minor changes and a ref. added. To appear in A&A (2006

The optimal phase of the generalised Poincare dodecahedral space hypothesis implied by the spatial cross-correlation function of the WMAP sky maps

Several studies have proposed that the shape of the Universe may be a Poincare dodecahedral space (PDS) rather than an infinite, simply connected, flat space. Both models assume a close to flat FLRW metric of about 30% matter density. We study two predictions of the PDS model. (i) For the correct model, the spatial two-point cross-correlation function, \ximc, of temperature fluctuations in the covering space, where the two points in any pair are on different copies of the surface of last scattering (SLS), should be of a similar order of magnitude to the auto-correlation function, \xisc, on a single copy of the SLS. (ii) The optimal orientation and identified circle radius for a "generalised" PDS model of arbitrary twist $\phi$, found by maximising \ximc relative to \xisc in the WMAP maps, should yield $\phi \in \{\pm 36\deg\}$. We optimise the cross-correlation at scales < 4.0 h^-1 Gpc using a Markov chain Monte Carlo (MCMC) method over orientation, circle size and $\phi$. Both predictions were satisfied: (i) an optimal "generalised" PDS solution was found, with a strong cross-correlation between points which would be distant and only weakly correlated according to the simply connected hypothesis, for two different foreground-reduced versions of the WMAP 3-year all-sky map, both with and without the kp2 Galaxy mask: the face centres are $(l,b)_{i=1,6}\approx (184d, 62d), (305d, 44d), (46d, 49d), (117d, 20d), (176d, -4d), (240d, 13d) to within ~2d, and their antipodes; (ii) this solution has twist \phi= (+39 \pm 2.5)d, in agreement with the PDS model. The chance of this occurring in the simply connected model, assuming a uniform distribution$\phi \in [0,2\pi]$, is about 6-9%.Comment: 20 pages, 22 figures, accepted in Astronomy & Astrophysics, software available at http://adjani.astro.umk.pl/GPLdownload/dodec/ and MCMCs at http://adjani.astro.umk.pl/GPLdownload/MCM