Adsorption du pentachlorophenol sur divers matériaux : Influence de co-adsorbats organiques (Substances humiques et lindane)

Nous avons réalisé, pour de faibles concentrations, l'étude de l'adsoprtion d'un pesticide le pentachlorophénol, sur plusieurs matériaux adsorbants : le charbon actif, la kaolinite et la bentone. Les résultats montrent que l'adsorption du pentachlorophénol sur la kaolinite reste négligeable tandis que la bentone SD-3 (argile traitée) permet d'obtenir des résultats intéressants avec toutefois une capacité maximale d'adsorption 10 à 100 fois plus faible que celle du charbon actif. Le charbon actif reste le meilleur matériau adsorbant pour le pentachlorophénol. La solubilité de ce composé étant très variable en fonction du pH du milieu on constate que l'adsorption du pentachlorophénol-pentachlorophénate (5 mg.l-1) diminue pour des valeurs de pH supérieures au pKa du couple acide-base que nous avons déterminé expérimentalement, égal à 5,9 ± 0,1. L'adsorption du pentachlorophénol n'est pas affectée par la présence d'acides humiques (obtenus à partir de substances commerciales) utilisés comme coadsorbats (10 mg.l-1) alors que les acides fulviques (20 mg.l-1) extraits de sols semblent provoquer une promotion de l'adsorption. On observe d'autre part que le pentachlorophénol n'affecte pas l'adsorption des acides humiques mais augmente légèrement celle des acides fulviques. Ces remarques suggèrent la possible formation d'un complexe acides fulviques-pentachlorophénol. Lorsqu'on utilise le lindane, pesticide hydrophobe comme coadsorbat (165 mg.l-1), on observe encore d'une façon systématique pour tous les nombreux essais une légère promotion de l'adsorption.Adsorption studies for the removal of the pesticide pentachlorophenol found in a number of water supplies (BELAMIE and GIROUD, 1986) were carried out using various materials including kaolinite, bentone SD-3 and powdered activated carbon (WEBER and GOULD, 1966; WEBER and JODELHAH, 1985). It was found that adsorption on kaolinite was negligible, whereas bentone SD-3 presented and adsorption efficiency from 10 to 100-fold less than equivalent quantities of powdered activated carbon (LOTSE et al., 1968; SHAROM et al., 1980). The effect of the pH on the removal of pentachlorophenol by activated carbon was studied. The removal efficiency of pentachlorophenol by activated carbon is better in acidic media. A clear dependence of adsorption on the pH appeared to be the result of a marked variation of the pesticide solubility as a function of the pH (fig. 3). Adsorption of pentachlorophenol/phenate (5mg.l-1) diminishes markedly at pH values above the pKa of this weak acid (that we found equal to 5,9 ± 0,1) when the pentachlorophenol exists almost entirely in ionic form in aqueous solution, and is enhanced at low pH when the percentage of molecular species (whose concentration can be determined from pKa value) becomes significant (WARD and GETZEN, 1970). These remarks and the adsorptive capacities (163 mg.g-1= 0,6 mmol.g-1 at pH = 5,2 and 79 mg.g-1 0,3 mmol.g-1 at pH =12,7), suggest a П-П interaction between pentachlorophenol and activated carbon which seems to be confirmed by the results with bentone SD-3 (tables 1 to 4), and the values of the electrokinetic potential of these materials. This study emphasizes the effect of organic coadsorbates (e.g., dissolved humic substances and the pesticide lindane) on the adsorption capacity of activated carbon for pentachlorophenol. Two different natural organic matters were studied as coadsorbates : purified humic acids from a commercial source (at 10 mg.l-1) and fulvic acids extracted from a top soil horizon (et 20 mg.l-1) (SCHNITZER and SKINNER, 1963; THURMAN and MALCOLM, 1981). Pentachlorophenol adsorption was not affected by humic acids, whereas an increase of adsorption seemed to be observed in the presence of fulvic acids (fig. 6). Pentachlorophenol does not affect the adsorption of humic acids, but improves slightly the removal of fulvic acids. This suggests an association between the two kinds of organic compounds (WERSNAW et al., 1969; KHAN, 1972; OGNER and SCHNITZER, 1970), the resulting « complex », fulvic acids/pentachlorophenol, being more adsorbed than the compounds themselves. The coadsorbate lindane (0,65 mg.l-1) which is easily adsorbed by activated carton (GOMELLA and BELLE, 1975...) seemed also to Improve slightly the removal efficiency of pentachlorophenol by activated carton (fig. 7)

Influence de l'origine et de la nature des substances humiques sur l'adsorption de l'atrazine sur charbon actif en poudre

Les essais d'adsorption sur charbon actif en poudre, de sept acides humiques (H) ou fulviques (F) et pour trois pH (5,6 ; 7,0 ; 8,8) marquent que ces acides ont un comportement différent suivant leur origine.Lorsque le pH de la suspension de charbon est basique, l'adsorption des différentes fractions humiques diminue, ce qui est en relation avec l'augmentation de leur solubilité. Pour un même pH de la suspension, les acides humiques et fulviques d'origine aqueuse s'adsorbent mieux que ceux d'origine commerciale ou que ceux extraits de sol.La capacité maximale d'adsorption de l'atrazine sur charbon actif en poudre : 260 mg.g-1 (Langmuir), est plus fortement diminuée en présence d'acides fulviques que d'acides humiques d'une part, et plus inhibée (jusqu'à 40 %) par les acides fulviques extraits d'eau (F1, F2) que par ceux extraits de sol (F3) d'autre part.Par contre, les acides humiques provenant de substances commerciales (H4, H5) influencent moins l'adsorption de l'atrazine.L'ensemble des essais montre que l'origine et la nature des substances humiques joue un rôle prépondérant sur l'adsorption de l'atrazine sur charbon actif, le pH ayant une influence limitée.Enfin l'étude de l'influence de l'atrazine sur l'adsorption des substances humiques sur charbon actif en poudre indique également une différence de comportement entre les acides fulviques, pour lesquels on note peu de variation, et les acides humiques, pour lesquels on note à la fois une promotion de l'adsorption et une meilleure affinité d'adsorption sur le charbon actif en poudre en présence d'atrazine.Ce travail met en évidence l'importance du choix des substances humiques pour des essais d'évaluation des interactions substances humiques - pesticides lors de l'adsorption sur charbon actif en poudre.Though the subject was copiously and oldly studied, this work is bringing a new contribution to the study of the influence of the origin and the nature upon their properties and in particular with atrazine, the more used herbicide these fast years.In order to study this influence of the origin and nature of various humic substances upon the removal of atrazine by adsorption onto powdered activated carbon (PAC), humic substances were obtained from different sources :- Natural aquatic fulvic (F1) and humic (H1) acids isolated from Beaune Lake (Limoges, France).- Natural aquatic fulvic (F2) and humic (H2) acids extracted from hydroxyde sludges of the water treatment plant of La Bastide (Limoges, France).- Soil fulvic acids (F3) extracted from a canadian top soil horizon.- Commercial humic acids (Aldrich. H4 and Jansen H5) obtained from commercial sodium humates.The results of adsorption test of humic acids, fulvic acids and atrazine (alone or together) onto powdered activated carbon (PAC) at three different pH (5,6 ; 7,0 ; 8,8) were expressed by Freundlich's and Langmuir’s models and permitted us to note that :- According to the increasing of water solubility of humic substances with basic pH, their adsorption was better in acidic medium.- Natural aquatic humic substances (H1, H2, F1, F2) were more adsorbed onto PAC than humic substances tram soil (H3) or commercial origines (H4, H5).- Atrazine adsorption capacity was 260 mg.g-1 according to Langmuir's model.- Atrazine adsorption decreased with F1 for all pH ; the same result was also observed with the other natural aquatic humic substances.- Commercial humic acids didn’t importantly affect atrazine adsorption. These differences appeared to be derived from the nature and the origin of fulvic and humic acids. The rose of atrazine on the humic substances adsorption showed a difference between humic and fulvic acids whose adsorption was not influenced by atrazine even humic acids only presented an increasing of adsorption.All these results showed the importance of the selection of humic substances to evaluate the interaction SH-Pesticides during adsorption onto PAC and let us think to a competitive adsorption between fulvic acids and atrazine onto PAC

Study on geological and structural characterization around Mai Kenetal, Central Tigray in Northern Ethiopia

The present research is aims to study geological and structural characterization around Mai Kenetal, central Tigray, in northern Ethiopia. Topographic difference of the Mai Kenetal area helped in identifying the rock units in the north-western and south-eastern parts of the study area. So that metavolcanic, metavolcaniclastic formations are located in the north and northeast sides whereas slate and phyllite are situated in the south, central and eastern side. Also intrusive granite and dikes are recognized in the central part of the study area. The results shows that the basement rocks are prominently NE-SW trending and shows parallel to the regional lineaments of Mai Kenetal is syncline inliers structure. In study area, the dominant structures such as foliation, shear zone, fold, and fractures like fault, joints, and slickenside are appears. Structural data suggests that the study area has been experienced in three phases of deformation and it also indicated presence of hydrothermal alterations like chloritization, epidotization, sericitization. Based on the lithology study and the non-development of foliation or schistosity suggest that the study area is experienced in low grade metamorphic conditions

Lignin biosynthesis in wheat (Triticum aestivum L.): its response to waterlogging and association with hormonal levels

Phylogenetic relationships of wheat C3H and CCoAOMT genes with the homologs from other species. Phylogenetic trees of C3H (A) and CCoAOMT (B) were generated based on nucleic acid sequence similarity of wheat genes with 15 C3H and 19 CCoAOMT genes, respectively, of other monocot and dicot species identified from the NCBI nucleotide database [39] using MEGA program [41], and the trees were inferred using Maximum Likelihood method based on the Tamura-nei model. The percentage of replicate trees in which the associated taxa clustered together in the bootstrap test of 500 replicates is shown next to the branches. ●, wheat candidate gene; ▲, genes from dicot species other than Arabidopsis; *, wheat sequence used for the analysis. (PDF 175 kb

Burden of podoconiosis in poor rural communities in Guliso woreda, western Ethiopia

Background. Podoconiosis is an environmental lymphoedema affecting people living and working barefoot on irritant red clay soil. Podoconiosis is relatively well described in southern Ethiopia, but remains neglected in other parts of the Ethiopian highlands. This study aimed to assess the burden of podoconiosis in rural communities in western Ethiopia. Methodology/Principal Findings. A cross-sectional study was conducted in Gulliso woreda (district), west Ethiopia. A household survey in the 26 rural kebeles (villages) of this district was conducted to identify podoconiosis patients and to measure disease prevalence. A more detailed study was done in six randomly selected kebeles to describe clinical features of the disease, patients’ experiences of foot hygiene, and shoe wearing practice. 1,935 cases of podoconiosis were registered, giving a prevalence of 2.8%. The prevalence was higher in those aged 15 – 64 years (5.2%) and in females than males (prevalence ratio 2.6:1). 90.3% of patients were in the 15 – 64 year age group. In the detailed study, 335 cases were interviewed and their feet assessed. The majority of patients were farmers, uneducated, and poor. Two-third of patients developed the disease before the age of thirty. Almost all patients (97.0%) had experienced adenolymphangitis (ALA - red, hot legs, swollen and painful groin) at least once during the previous year. Patients experienced an average of 5.5 ALA episodes annually, each of average 4.4 days, thus 24 working days were lost annually. The incidence of ALA in podoconiosis patients was higher than that reported for filariasis in other countries. Shoe wearing was limited mainly due to financial problems. Conclusions. We have documented high podoconiosis prevalence, frequent adenolymphangitis and high disease-related morbidity in west Ethiopia. Interventions must be developed to prevent, treat and control podoconiosis, one of the core neglected tropical diseases in Ethiopia

Individual correlates of podoconiosis in areas of varying endemicity: a case-control study

BACKGROUND Podoconiosis is a non-filarial form of elephantiasis resulting in lymphedema of the lower legs. Previous studies have suggested that podoconiosis arises from the interplay of individual and environmental factors. Here, our aim was to understand the individual-level correlates of podoconiosis by comparing 460 podoconiosis-affected individuals and 707 unaffected controls. METHODS/PRINCIPAL FINDINGS This was a case-control study carried out in six kebeles (the lowest governmental administrative unit) in northern Ethiopia. Each kebele was classified into one of three endemicity levels: 'low' (prevalence 5%). A total of 142 (30.7%) households had two or more cases of podoconiosis. Compared to controls, the majority of the cases, especially women, were less educated (OR = 1.7, 95% CI = 1.3 to 2.2), were unmarried (OR = 3.4, 95% CI = 2.6-4.6) and had lower income (t = -4.4, p<0.0001). On average, cases started wearing shoes ten years later than controls. Among cases, age of first wearing shoes was positively correlated with age of onset of podoconiosis (r = 0.6, t = 12.5, p<0.0001). Among all study participants average duration of shoe wearing was less than 30 years. Between both cases and controls, people in 'high' and 'medium' endemicity kebeles were less likely than people in 'low' endemicity areas to 'ever' have owned shoes (OR = 0.5, 95% CI = 0.4-0.7). CONCLUSIONS Late use of shoes, usually after the onset of podoconiosis, and inequalities in education, income and marriage were found among cases, particularly among females. There were clustering of cases within households, thus interventions against podoconiosis will benefit from household-targeted case tracing. Most importantly, we identified a secular increase in shoe-wearing over recent years, which may give opportunities to promote shoe-wearing without increasing stigma among those at high risk of podoconiosis

Tuberculin screening of some selected Fulani lactating cows in north-central Nigeria

The prevalence of mycobacterial infection among lactating Fulani cows was investigated in the Federal Capital Territory, Abuja and Kaduna State of Nigeria. Tuberculin testing using single comparative intradermal tuberculin test showed a 14.6 % positive, 4 % doubtful, and 81.4 % negative reactors. Mycobacterial infection was found to be present in the nomadic (constantly moving) and seminomadic (limited movement) management systems studied but management showed no significant effect on the prevalence of the disease. However, the prevalence was significantly higher in older age groups than the younger ones (P < 0.05).Peer reviewedSubmitted Versio