Oxidation Behavior of a Pd_(43)Cu_(27)Ni_(10)P_(20) Bulk Metallic Glass and Foam in Dry Air

The oxidation behavior of both Pd_(43)Cu_(27)Ni_(10)P_(20) bulk metallic glass (Pd4-BMG) and its amorphous foam containing 45 pct porosity (Pd4-AF) was investigated over the temperature range of 343 K (70 °C) to 623 K (350 °C) in dry air. The results showed that virtually no oxidation occurred in the Pd4-BMG at T < 523 K (250 °C), revealing the alloy’s favorable oxidation resistance in this temperature range. In addition, the oxidation kinetics at T ≥ 523 K (250 °C) followed a parabolic-rate law, and the parabolic-rate constants (k_p values) generally increased with temperature. It was found that the oxidation k_p values of the Pd4-AF are slightly lower than those of the Pd4-BMG, indicating that the porous structure contributes to improving the overall oxidation resistance. The scale formed on the alloys was composed exclusively of CuO at T ≥ 548 K (275 °C), whose thickness gradually increased with increasing temperature. In addition, the amorphous structure remained unchanged at T ≤ 548 K (275 °C), while a triplex-phase structure developed after the oxidation at higher temperatures, consisting of Pd_2Ni_2P, Cu_3P, and Pd_3P

Total and Nonresidual Concentrations of Selected Elements in Two Soil Series on the Island of Hawaii

Thirty Aridisol soil samples of the Kawaihae soil series on the dry, leeward, northwestern side of the island of Hawaii and 13 Histosol samples of the Papai series on the wet, windward, eastern side of the island were subjected to (1) complete dissolution by a mixture ofHN03, HCl, and HF to determine total concentrations of Co, Cr, Cu, Fe, Mn, Ni, and Zn and (2) extraction of these metals by shaking 10 g soil: 100 mL 0.5M HCl solutions for 16hr to determine nonresidual concentrations. Analyses were performed mainly by flame and electrothermal atomic absorption spectrophotometry. Loss on ignition (LOI) and soil pH were also determined. Total metal concentrations, quantity extracted, LOI, and soil pH were analyzed statistically. Compared to the Histosol, the Aridisol samples typically contain more Co, Cr, Fe, and Mn, less Cu, similar concentrations of Ni and Zn, and have less LOI and higher pH. The Aridisol exhibits a high degree of correlation between total Cr and Ni, while a strong negative correlation occurs between Cu, Mn, Co, and Fe individually with LOI in the Histosol. The mean concentrations of these metals in both soils are significantly greater than those which occur in soils of the conterminous United States. The effectiveness of extraction by the acid solution, as measured by the percentage of metal extracted, is approximately Mn > Co > Cu > Cr > Fe > Zn - Ni for the Aridisol and Cu - Zn > Co - Mn > Fe - Ni > Cr for the Histosol; the difference is attributed to weathering under different climatic conditions. The latter soils exhibit a higher degree of correlation for percentages of metals extracted among the various metals and with LOI

Interplay of Peltier and Seebeck effects in nanoscale nonlocal spin valves

We have experimentally studied the role of thermoelectric effects in nanoscale nonlocal spin valve devices. A finite element thermoelectric model is developed to calculate the generated Seebeck voltages due to Peltier and Joule heating in the devices. By measuring the first, second and third harmonic voltage response non locally, the model is experimentally examined. The results indicate that the combination of Peltier and Seebeck effects contributes significantly to the nonlocal baseline resistance. Moreover, we found that the second and third harmonic response signals can be attributed to Joule heating and temperature dependencies of both Seebeck coefficient and resistivity.Comment: 4 pages, 4 figure

Submerged in the mainstream? A case study of an immigrant learner in a New Zealand primary classroom

Immigrant children from diverse language backgrounds face not only linguistic challenges when enrolled in mainstream English-medium classrooms, but also difficulties adjusting to an unfamiliar learning community. The culture of primary school classrooms in New Zealand typically reflects conventions across three dimensions: interactional, instructional task performance and cognitive-academic development. All three dimensions are underpinned by the culturally specific discourse conventions involved in language socialisation. New learners may be helped by classmates or their teacher to understand and successfully use these conventions, but left on their own they may sink rather than swim. This is a case study of one Taiwanese 11-year old boy, 'John', who entered a New Zealand primary classroom midway through the school year. John's basic conversational ability was sound, but he did not possess the interactive classroom skills needed to operate in the new culture of learning. Selected from a wider study of the classroom, transcript data from audio-recorded excerpts of John's interactions over several months with his teacher and classmates are interpreted from perspectives derived from sociocultural and language socialisation theories. The article concludes with a brief consideration of the extent to which John constructed, or was constrained from constructing meaningful learning experiences, and suggestions for further research and reflection

GRB 070201: A possible Soft Gamma Ray Repeater in M31

The gamma-ray burst (GRB) 070201 was a bright short-duration hard-spectrum GRB detected by the Inter-Planetary Network (IPN). Its error quadrilateral, which has an area of 0.124 sq. deg, intersects some prominent spiral arms of the nearby M31 (Andromeda) galaxy. Given the properties of this GRB, along with the fact that LIGO data argues against a compact binary merger origin in M31, this GRB is an excellent candidate for an extragalactic Soft Gamma-ray Repeater (SGR) giant flare, with energy of 1.4x10^45 erg. Analysis of ROTSE-IIIb visible light observations of M31, taken 10.6 hours after the burst and covering 42% of the GRB error region, did not reveal any optical transient down to a limiting magnitude of 17.1. We inspected archival and proprietary XMM-Newton X-ray observations of the intersection of the GRB error quadrilateral and M31, obtained about four weeks prior to the outburst, in order to look for periodic variable X-ray sources. No SGR or Anomalous X-ray Pulsar (AXP) candidates (periods in range 1 to 20 s) were detected. We discuss the possibility of detecting extragalactic SGRs/AXPs by identifying their periodic X-ray light curves. Our simulations suggest that the probability of detecting the periodic X-ray signal of one of the known Galactic SGRs/AXPs, if placed in M31, is about 10% (50%), using 50 ks (2 Ms) XMM-Newton exposures.Comment: 7 pages, submitted to ApJ (Fig. 2 resolution reduced

Irradiation of Materials with Short, Intense Ion pulses at NDCX-II

We present an overview of the performance of the Neutralized Drift Compression Experiment-II (NDCX-II) accelerator at Berkeley Lab, and report on recent target experiments on beam driven melting and transmission ion energy loss measurements with nanosecond and millimeter-scale ion beam pulses and thin tin foils. Bunches with around 10^11 ions, 1-mm radius, and 2-30 ns FWHM duration have been created with corresponding fluences in the range of 0.1 to 0.7 J/cm^2. To achieve these short pulse durations and mm-scale focal spot radii, the 1.1 MeV He+ ion beam is neutralized in a drift compression section, which removes the space charge defocusing effect during final compression and focusing. The beam space charge and drift compression techniques resemble necessary beam conditions and manipulations in heavy ion inertial fusion accelerators. Quantitative comparison of detailed particle-in-cell simulations with the experiment play an important role in optimizing accelerator performance.Comment: 15 pages, 7 figures. revised manuscript submitted to Laser and Particle Beam