Room temperature self-assembly of mixed nanoparticles into complex material systems and devices

The ability to manufacture nanomaterials with complex and structured composition using otherwise incompatible materials increasingly underpins the next generation of technologies. This is translating into growing efforts integrating a wider range of materials onto key technology platforms1 - in photonics, one such platform is silica, a passive, low loss and robust medium crucial for efficient optical transport2. Active functionalisation, either through added gain or nonlinearity, is mostly possible through the integration of active materials3, 4. The high temperatures used in manufacturing of silica waveguides, unfortunately, make it impossible to presently integrate many organic and inorganic species critical to achieving this extended functionality. Here, we demonstrate the fabrication of novel waveguides and devices made up of complex silica based materials using the self-assembly of nanoparticles. In particular, the room temperature fabrication of silica microwires integrated with organic dyes (Rhodamine B) and single photon emitting nanodiamonds is presented.Comment: Key words: nanotechnology, nanoparticles, self-assembly, quantum science, singel photon emitters, telecommunications, sensing, new materials, integration of incompatible materials, silica, glass, breakthrough scienc

Development of sports turf systems suitable for Irish conditions.

End of Project ReportThe principal objective of the study was to establish scientific data in relation to the nutritional requirements and best management practice for golf greens constructed to the United States Golf Association (USGA) 1973 specification under Irish conditions. The game of golf is one of the biggest sports industries in the world. Income from golf tourism in Ireland has increased from £73 million in 1994 to £180 million in 1998. Good quality turfgrass is required to underpin the promotion of golf tourism. Traditionally, golf greens on Irish golf courses were constructed from local materials and vary from green to green within a given golf course and also between different golf courses. In recent years there is a perception that the quality of putting surfaces is superior on greens constructed to the USGA specification. In addition, greens constructed to this specification are similar one to the other and location to location. The principal features of the USGA 1973 specification could be summarised as follows: (1) A network of drainage pipes installed in the underground soil covered with a carpet of peat gravel; (2) A blinding layer of specifically graded sand placed on the peat gravel; (3) A root zone mixture of graded sand (80%) and graded peat moss (20%) by volume. The particle size of the component layers must comply to the exact specification in terms of size, diameter and shape. As sands contain no nutrients, the management of greens constructed mainly of sand is more exacting than the traditional soil constructed greens. The results from this project confirmed this assumption. Three major objectives were researched in this project: (a) the effect of micro nutrients, when applied or omitted, on the quality and growth of grass on a green surface; (b) the encroachment of Poa annua (annual meadow grass) onto the green; and (c) the comparison of two nitrogen top dressing programmes on sand greens. The detailed results are given in the text and in the conclusions of this report.European Union Structural Funds (EAGGF

The distribution of dark and luminous matter in the unique galaxy cluster merger Abell 2146

Abell 2146 ($z$ = 0.232) consists of two galaxy clusters undergoing a major merger. The system was discovered in previous work, where two large shock fronts were detected using the $\textit{Chandra X-ray Observatory}$, consistent with a merger close to the plane of the sky, caught soon after first core passage. A weak gravitational lensing analysis of the total gravitating mass in the system, using the distorted shapes of distant galaxies seen with Advanced Camera for Surveys - Wide Field Channel on $\textit{Hubble Space Telescope}$, is presented. The highest peak in the reconstruction of the projected mass is centred on the brightest cluster galaxy (BCG) in Abell 2146-A. The mass associated with Abell 2146-B is more extended. Bootstrapped noise mass reconstructions show the mass peak in Abell 2146-A to be consistently centred on the BCG. Previous work showed that BCG-A appears to lag behind an X-ray cool core; although the peak of the mass reconstruction is centred on the BCG, it is also consistent with the X-ray peak given the resolution of the weak lensing mass map. The best-fitting mass model with two components centred on the BCGs yields $M_{200}$ = 1.1$^{+0.3}_{-0.4}$ × 10$^{15}$ and 3$^{+1}_{-2}$ × 10$^{14}$ M$_\odot$ for Abell 2146-A and Abell 2146-B, respectively, assuming a mass concentration parameter of $c$ = 3.5 for each cluster. From the weak lensing analysis, Abell 2146-A is the primary halo component, and the origin of the apparent discrepancy with the X-ray analysis where Abell 2146-B is the primary halo is being assessed using simulations of the merger

Predicting Graph Categories from Structural Properties

Complex networks are often categorized according to the underlying phenomena that they represent such as molecular interactions, re-tweets, and brain activity. In this work, we investigate the problem of predicting the category (domain) of arbitrary networks. This includes complex networks from different domains as well as synthetically generated graphs from five different network models. A classification accuracy of 96.6% is achieved using a random forest classifier with both real and synthetic networks. This work makes two important findings. First, our results indicate that complex networks from various domains have distinct structural properties that allow us to predict with high accuracy the category of a new previously unseen network. Second, synthetic graphs are trivial to classify as the classification model can predict with near-certainty the network model used to generate it. Overall, the results demonstrate that networks drawn from different domains (and network models) are trivial to distinguish using only a handful of simple structural properties

X-ray bright active galactic nuclei in massive galaxy clusters III: New insights into the triggering mechanisms of cluster AGN

We present the results of a new analysis of the X-ray selected Active Galactic Nuclei (AGN) population in the vicinity of 135 of the most massive galaxy clusters in the redshift range of 0.2 < z < 0.9 observed with Chandra. With a sample of more than 11,000 X-ray point sources, we are able to measure, for the first time, evidence for evolution in the cluster AGN population beyond the expected evolution of field AGN. Our analysis shows that overall number density of cluster AGN scales with the cluster mass as $\sim M_{500}^{-1.2}$. There is no evidence for the overall number density of cluster member X-ray AGN depending on the cluster redshift in a manner different than field AGN, nor there is any evidence that the spatial distribution of cluster AGN (given in units of the cluster overdensity radius r_500) strongly depends on the cluster mass or redshift. The $M^{-1.2 \pm 0.7}$ scaling relation we measure is consistent with theoretical predictions of the galaxy merger rate in clusters, which is expected to scale with the cluster velocity dispersion, $\sigma$, as $\sim \sigma^{-3}$ or $\sim M^{-1}$. This consistency suggests that AGN in clusters may be predominantly triggered by galaxy mergers, a result that is further corroborated by visual inspection of Hubble images for 23 spectroscopically confirmed cluster member AGN in our sample. A merger-driven scenario for the triggering of X-ray AGN is not strongly favored by studies of field galaxies, however, suggesting that different mechanisms may be primarily responsible for the triggering of cluster and field X-ray AGN.Comment: 21 Pages, 8 figures, 5 tables. Submitted to MNRAS. Comments are welcome, and please request Steven Ehlert for higher resolution figure

Probing the extreme realm of AGN feedback in the massive galaxy cluster, RX J1532.9+3021

We present a detailed Chandra, XMM-Newton, VLA and HST analysis of one of the strongest cool core clusters known, RX J1532.9+3021 (z=0.3613). Using new, deep 90 ks Chandra observations, we confirm the presence of a western X-ray cavity or bubble, and report on a newly discovered eastern X-ray cavity. The total mechanical power associated with these AGN-driven outflows is (22+/-9)*10^44 erg/s, and is sufficient to offset the cooling, indicating that AGN feedback still provides a viable solution to the cooling flow problem even in the strongest cool core clusters. Based on the distribution of the optical filaments, as well as a jet-like structure seen in the 325 MHz VLA radio map, we suggest that the cluster harbours older outflows along the north to south direction. The jet of the central AGN is therefore either precessing or sloshing-induced motions have caused the outflows to change directions. There are also hints of an X-ray depression to the north aligned with the 325 MHz jet-like structure, which might represent the highest redshift ghost cavity discovered to date. We further find evidence of a cold front (r=65kpc) that coincides with the outermost edge of the western X-ray cavity and the edge of the radio mini-halo. The common location of the cold front with the edge of the radio mini-halo supports the idea that the latter originates from electrons being reaccelerated due to sloshing induced turbulence. Alternatively, its coexistence with the edge of the X-ray cavity may be due to cool gas being dragged out by the outburst. We confirm that the central AGN is highly sub-Eddington and conclude that a >10^10M_Sun or a rapidly spinning black hole is favoured to explain both the radiative-inefficiency of the AGN and the powerful X-ray cavities.Comment: Accepted for publication to ApJ (minor corrections), 16 pages, 16 figures, 5 tables. Full resolution at http://www.stanford.edu/~juliehl/M1532

Student perception of workplace-based assessment.

Workplace-based assessment (WPBA) is key to medical education, providing a framework through which the trainee can be assessed and receive feedback in the clinical setting. WPBA was introduced in 2008-2009 to students in year 4 at University College London Medical School (UCLMS). Students raised concerns about the lack of standardisation in grading. As a result, white-space areas were introduced on WPBA forms. The aim of this was to permit assessors to expand their feedback, thereby enhancing its developmental potential. The aim of the project was to assess student perception of WPBA at UCLMS, and to determine whether re-designing the form had altered this perception

Cooling in the X-ray halo of the rotating, massive early-type galaxy NGC 7049

The relative importance of the physical processes shaping the thermodynamics of the hot gas permeating rotating, massive early-type galaxies is expected to be different from that in non-rotating systems. Here, we report the results of the analysis of XMM-Newton data for the massive, lenticular galaxy NGC 7049. The galaxy harbours a dusty disc of cool gas and is surrounded by an extended hot X-ray emitting gaseous atmosphere with unusually high central entropy. The hot gas in the plane of rotation of the cool dusty disc has a multi-temperature structure, consistent with ongoing cooling. We conclude that the rotational support of the hot gas is likely capable of altering the multiphase condensation regardless of the $t_{\rm cool}/t_{\rm ff}$ ratio, which is here relatively high, $\sim 40$. However, the measured ratio of cooling time and eddy turnover time around unity ($C$-ratio $\approx 1$) implies significant condensation, and at the same time, the constrained ratio of rotational velocity and the velocity dispersion (turbulent Taylor number) ${\rm Ta_t} > 1$ indicates that the condensing gas should follow non-radial orbits forming a disc instead of filaments. This is in agreement with hydrodynamical simulations of massive rotating galaxies predicting a similarly extended multiphase disc.Comment: 11 pages, 12 figures, accepted for publication in MNRA