Normal background concentrations of contaminants in the soils of England : available data and data exploration

This draft report describes the completed Work Package 1 and 2 tasks of the Defra commissioned Science and Research Project SP1008 - Establishing data on normal/background levels of soil contamination in England. Work Package 1 (WP1) has investigated the available soil data sets that can be used to determine the Normal Background Concentrations (NBCs) for contaminants in soils from England. A database of available data set information has been created investigating the sample coverage, the sampling strategy and methods, the laboratory procedures, and the robustness, format and availability of the data. Key data sets are the British Geological Survey’s G-BASE topsoils for urban and rural areas and the National Soil Inventory (XRFS reanalysed) data which, although at a reduced sampling density compared to G-BASE, has complete coverage for both England and Wales. Supplementary minor data sets are also included in the Project’s extensive bibliographic database. There are also large data sets available that specifically target a particular land use or activity, i.e. not systematically collected, e.g. the BGS Mineral Reconnaissance Programme (MRP) soils. Such data will not be used to estimate NBCs as they will cause a substantial bias in the determinations. This data and information gathering phase will underpin subsequent work packages of this project. Work Package 1 has also addressed some key questions such as, “what are the priority contaminants?” and “what is meant by a normal background concentration?

Normal background concentrations (NBCs) of contaminants in English soils : final project report

The British Geological Survey (BGS) has been commissioned by the Department for Environment, Food and Rural Affairs (Defra) to give guidance on what are normal levels of contaminants in English soils in support of the Part 2A Contaminated Land Statutory Guidance. This has initially been done by studying the distribution of four contaminants – arsenic, lead, benzo[a]pyrene (BaP) and asbestos – in topsoils from England. This work was extended to a further four contaminants (cadmium, copper, nickel and mercury) which enabled methodologies developed to be tested on a larger range of contaminants. The first phase of the Project gathered data sets that were: nationally extensive; systematically collected so a broad range of land uses were represented; and collected and analysed to demonstrably and acceptable levels of quality. Information on the soil contaminant concentrations in urban areas was of particular importance as the normal background is considered to be a combination of both natural and diffuse anthropogenic contributions to the soil. Issues of soil quality are most important in areas where these affect most people, namely, the urban environment. The two principal data sets used in this work are the BGS Geochemical Baseline Survey of the Environment (G-BASE) rural and urban topsoils (37,269 samples) and the English NSI (National Soil Inventory) topsoils (4,864 samples) reanalysed at the BGS laboratories by X-ray fluorescence spectrometry (XRFS) so both data sets were highly compatible. These two data sets provide results for most inorganic element contaminants, though results explored for mercury and BaP are drawn from a variety of different and much less extensive data sets

Social networks : the future for health care delivery

With the rapid growth of online social networking for health, health care systems are experiencing an inescapable increase in complexity. This is not necessarily a drawback; self-organising, adaptive networks could become central to future health care delivery. This paper considers whether social networks composed of patients and their social circles can compete with, or complement, professional networks in assembling health-related information of value for improving health and health care. Using the framework of analysis of a two-sided network – patients and providers – with multiple platforms for interaction, we argue that the structure and dynamics of such a network has implications for future health care. Patients are using social networking to access and contribute health information. Among those living with chronic illness and disability and engaging with social networks, there is considerable expertise in assessing, combining and exploiting information. Social networking is providing a new landscape for patients to assemble health information, relatively free from the constraints of traditional health care. However, health information from social networks currently complements traditional sources rather than substituting for them. Networking among health care provider organisations is enabling greater exploitation of health information for health care planning. The platforms of interaction are also changing. Patient-doctor encounters are now more permeable to influence from social networks and professional networks. Diffuse and temporary platforms of interaction enable discourse between patients and professionals, and include platforms controlled by patients. We argue that social networking has the potential to change patterns of health inequalities and access to health care, alter the stability of health care provision and lead to a reformulation of the role of health professionals. Further research is needed to understand how network structure combined with its dynamics will affect the flow of information and potentially the allocation of health care resources

Remote sensing for shipwreck location. Or, all your problems solved.

A routine site inspection of a proposed shipwreck salvage excavation revealed a technique with important ramifications for survey archaeology. Its potential may prove disastrous to the present job market for field archaeologists

Theoretical Study of Solvent Effects on the Electronic Coupling Element in Rigidly Linked Donor-Acceptor Systems

The recently developed generalized Mulliken-Hush approach for the calculation of the electronic coupling matrix element for electron-transfer processes is applied to two rigidly linked donor-bridge-acceptor systems having dimethoxyanthracene as the donor and a dicarbomethoxycyclobutene unit as the acceptor. The dependence of the electronic coupling matrix element as a function of bridge type is examined with and without solvent molecules present. For clamp-shaped bridge structures solvent can have a dramatic effect on the electronic coupling matrix element. The behavior with variation of solvent is in good agreement with that observed experimentally for these systems

A contribution to the conceptualisation of quality in impact assessment

Quality is much sought after in, and a basic foundation for, good impact assessment (IA). However, the term is rarely defined, has an uncertain relationship with IA effectiveness, and it means different things to different stakeholders, which can lead to debates over the legitimacy associated with an IA process. Thus, IA quality needs conceptualising to position research and practice within broader understandings. This paper contributes to this conceptualisation by identifying nine dimensions of quality through a process of literature review drawing on three fields of study in which quality and quality management have already been debated and conceptualised: education; health care; and business. This approach sidesteps the plural views on quality existing within the field of IA itself which might otherwise bias the identification of quality dimensions. We therefore propose that the dimensions of IA quality are: Efficiency; Optimacy; Conformance; Legitimacy; Equity; Capacity Maintenance; Transformative Capacity; and Quality Management. A literature review of IA research and practice confirms the relevance of the identified quality dimensions to IA. We identify, to an extent, the relationship between quality and effectiveness. Quality aligns with procedural and transactive effectiveness, partly aligns with normative effectiveness and is distinct from, but helps to deliver, substantive effectiveness

The Mersey Estuary : sediment geochemistry

This report describes a study of the geochemistry of the Mersey estuary carried out between April 2000 and December 2002. The study was the first in a new programme of surveys of the geochemistry of major British estuaries aimed at enhancing our knowledge and understanding of the distribution of contaminants in estuarine sediments. The report first summarises the physical setting, historical development, geology, hydrography and bathymetry of the Mersey estuary and its catchment. Details of the sampling and analytical programmes are then given followed by a discussion of the sedimentology and geochemistry. The chemistry of the water column and suspended particulate matter have not been studied, the chief concern being with the geochemistry of the surface and near-surface sediments of the Mersey estuary and an examination of their likely sources and present state of contamination

Call Me Caitlyn: Making and making over the 'authentic' transgender body in Anglo-American popular culture

A conception of transgender identity as an ‘authentic’ gendered core ‘trapped’ within a mismatched corporeality, and made tangible through corporeal transformations, has attained unprecedented legibility in contemporary Anglo-American media. Whilst pop-cultural articulations of this discourse have received some scholarly attention, the question of why this 'wrong body' paradigm has solidified as the normative explanation for gender transition within the popular media remains underexplored. This paper argues that this discourse has attained cultural pre-eminence through its convergence with a broader media and commercial zeitgeist, in which corporeal alteration and maintenance are perceived as means of accessing one’s ‘authentic’ self. I analyse the media representations of two transgender celebrities: Caitlyn Jenner and Nadia Almada, alongside the reality TV show TRANSform Me, exploring how these women’s gender transitions have been discursively aligned with a cultural imperative for all women, cisgender or trans, to display their authentic femininity through bodily work. This demonstrates how established tropes of authenticity-via-bodily transformation, have enabled transgender to become culturally legible through the wrong body trope. Problematically, I argue, this process has worked to demarcate ideals of ‘acceptable’ transgender subjectivity: self-sufficient, normatively feminine, and eager to embrace the possibilities for happiness and social integration provided by the commercial domain