Refined Simulations of the Reaction Front for Diffusion-Limited Two-Species Annihilation in One Dimension

Extensive simulations are performed of the diffusion-limited reaction A$+$B$\to 0$ in one dimension, with initially separated reagents. The reaction rate profile, and the probability distributions of the separation and midpoint of the nearest-neighbour pair of A and B particles, are all shown to exhibit dynamic scaling, independently of the presence of fluctuations in the initial state and of an exclusion principle in the model. The data is consistent with all lengthscales behaving as $t^{1/4}$ as $t\to\infty$. Evidence of multiscaling, found by other authors, is discussed in the light of these findings.Comment: Resubmitted as TeX rather than Postscript file. RevTeX version 3.0, 10 pages with 16 Encapsulated Postscript figures (need epsf). University of Geneva preprint UGVA/DPT 1994/10-85

Coupling Lattice Boltzmann and Molecular Dynamics models for dense fluids

We propose a hybrid model, coupling Lattice Boltzmann and Molecular Dynamics models, for the simulation of dense fluids. Time and length scales are decoupled by using an iterative Schwarz domain decomposition algorithm. The MD and LB formulations communicate via the exchange of velocities and velocity gradients at the interface. We validate the present LB-MD model in simulations of flows of liquid argon past and through a carbon nanotube. Comparisons with existing hybrid algorithms and with reference MD solutions demonstrate the validity of the present approach.Comment: 14 pages, 5 figure

Synchronous and Asynchronous Recursive Random Scale-Free Nets

We investigate the differences between scale-free recursive nets constructed by a synchronous, deterministic updating rule (e.g., Apollonian nets), versus an asynchronous, random sequential updating rule (e.g., random Apollonian nets). We show that the dramatic discrepancies observed recently for the degree exponent in these two cases result from a biased choice of the units to be updated sequentially in the asynchronous version

Opportunity for development or necessary nuisance? The case for viewing working with interpreters as a bonus in therapeutic work

This paper explores the central role a language interpreter can play in the process of the therapeutic relationship. Although others have described the changes to the therapeutic dyad that the presence of a third party (an interpreter) brings, little attention has been paid to the advantages and additional opportunities of this altered therapeutic situation. This paper details these gains and further argues that clinicians who are willing to gain experience of working with interpreters will find that benefits accrue at the micro and macro levels: at the micro level, through enhancement of their work with individual non English speaking clients, and at the macro level through learning about different cultural perspectives, idioms of distress and the role of language in the therapeutic endeavour. This is in addition to developing skills to fulfil legal and professional requirements relating to equity of service provision. Some ideas are offered to explain the negative slant than runs throughout the literature in this area and tends to colour the overall discussion of therapeutic work with interpreters and, before the final section, makes some specific suggestions which may help maximise the gains possible in such work while reducing difficulties

The lattice Boltzmann advection-diffusion model revisited

Advection-diffusion processes can be simulated by the Lattice Boltzmann method. Two formulations have been proposed in the literature. We show that they are not fully correct (only first order accurate). A new formulation is proposed, which is shown to produce better results, both from the point of view of the Chapman-Enskog expansion or when comparing simulations with an exact time-dependent solution of the advection-diffusion equatio

Pore-scale mass and reactant transport in multiphase porous media flows

Reactive processes associated with multiphase flows play a significant role in mass transport in unsaturated porous media. For example, the effect of reactions on the solid matrix can affect the formation and stability of fingering instabilities associated with the invasion of a buoyant non-wetting fluid. In this study, we focus on the formation and stability of capillary channels of a buoyant non-wetting fluid (developed because of capillary instabilities) and their impact on the transport and distribution of a reactant in the porous medium. We use a combination of pore-scale numerical calculations based on a multiphase reactive lattice Boltzmann model (LBM) and scaling laws to quantify (i)the effect of dissolution on the preservation of capillary instabilities, (ii)the penetration depth of reaction beyond the dissolution/melting front, and (iii)the temporal and spatial distribution of dissolution/melting under different conditions (concentration of reactant in the non-wetting fluid, injection rate). Our results show that, even for tortuous non-wetting fluid channels, simple scaling laws assuming an axisymmetrical annular flow can explain (i)the exponential decay of reactant along capillary channels, (ii)the dependence of the penetration depth of reactant on a local Péclet number (using the non-wetting fluid velocity in the channel) and more qualitatively (iii)the importance of the melting/reaction efficiency on the stability of non-wetting fluid channels. Our numerical method allows us to study the feedbacks between the immiscible multiphase fluid flow and a dynamically evolving porous matrix (dissolution or melting) which is an essential component of reactive transport in porous medi

Localization-delocalization transition of a reaction-diffusion front near a semipermeable wall

The A+B --> C reaction-diffusion process is studied in a system where the reagents are separated by a semipermeable wall. We use reaction-diffusion equations to describe the process and to derive a scaling description for the long-time behavior of the reaction front. Furthermore, we show that a critical localization-delocalization transition takes place as a control parameter which depends on the initial densities and on the diffusion constants is varied. The transition is between a reaction front of finite width that is localized at the wall and a front which is detached and moves away from the wall. At the critical point, the reaction front remains at the wall but its width diverges with time [as t^(1/6) in mean-field approximation].Comment: 7 pages, PS fil