Evaluation of Long Term Performance of Continuously Running Atomic Fountains

An ensemble of rubidium atomic fountain clocks has been put into operation at the U.S. Naval Observatory (USNO). These fountains are used as continuous clocks in the manner of commercial cesium beams and hydrogen masers for the purpose of improved timing applications. Four fountains have been in operation for more than two years and are included in the ensemble used to generate the USNO master clock. Individual fountain performance is characterized by a white-frequency noise level below $2\times 10^{-13}$ and fractional-frequency stability routinely reaching the low $10^{-16}$s. The highest performing pair of fountains exhibits stability consistent with each fountain integrating as white frequency noise, with Allan deviation surpassing $6\times 10^{-17}$ at $10^7$~s, and with no relative drift between the fountains at the level of $7.5 \times 10^{-19}$/day. As an ensemble, the fountains generate a timescale with white-frequency noise level of $1\times 10^{-13}$ and long-term frequency stability consistent with zero drift relative to the world's primary standards at $1 \times 10^{-18}$/day. The rubidium fountains are reported to the BIPM as continuously running clocks, as opposed to secondary standards, the only cold-atom clocks so reported. Here we further characterize the performance of the individual fountains and the ensemble during the first two years in an operational environment, presenting the first look at long-term continuous behavior of fountain clocks

Quadrupole collectivity in neutron-deficient Sn nuclei: \nuc{104}{Sn} and the role of proton excitations

We report on the experimental study of quadrupole collectivity in the neutron-deficient nucleus \nuc{104}{Sn} using intermediate-energy Coulomb excitation. The $B(E2; 0^+_1 \rightarrow 2^+_1)$ value for the excitation of the first $2^+$ state in \nuc{104}{Sn} has been measured to be $0.180(37)~e^2$b$^2$ relative to the well-known $B(E2)$ value of \nuc{102}{Cd}. This result disagrees by more than one sigma with a recently published measurement \cite{Gua13}. Our result indicates that the most modern many-body calculations remain unable to describe the enhanced collectivity below mid-shell in Sn approaching $N=Z=50$. We attribute the enhanced collectivity to proton particle-hole configurations beyond the necessarily limited shell-model spaces and suggest the asymmetry of the $B(E2)$-value trend around mid-shell to originate from enhanced proton excitations across $Z=50$ as $N=Z$ is approached.Comment: Accepted for publication as rapid communication in Physical Review

Children's construction task performance and spatial ability: controlling task complexity and predicting mathematics performance.

This paper presents a methodology to control construction task complexity and examined the relationships between construction performance and spatial and mathematical abilities in children. The study included three groups of children (N = 96); ages 7-8, 10-11, and 13-14 years. Each group constructed seven pre-specified objects. The study replicated and extended previous findings that indicated that the extent of component symmetry and variety, and the number of components for each object and available for selection, significantly predicted construction task difficulty. Results showed that this methodology is a valid and reliable technique for assessing and predicting construction play task difficulty. Furthermore, construction play performance predicted mathematical attainment independently of spatial ability

A global map to aid the identification and screening of critical habitat for marine industries

Marine industries face a number of risks that necessitate careful analysis prior to making decisions on the siting of operations and facilities. An important emerging regulatory framework on environmental sustainability for business operations is the International Finance Corporation’s Performance Standard 6 (IFC PS6). Within PS6, identification of biodiversity significance is articulated through the concept of “Critical Habitat”, a definition developed by the IFC and detailed through criteria aligned with those that support internationally accepted biodiversity designations. No publicly available tools have been developed in either the marine or terrestrial realm to assess the likelihood of sites or operations being located within PS6-defined Critical Habitat. This paper presents a starting point towards filling this gap in the form of a preliminary global map that classifies more than 13 million km2 of marine and coastal areas of importance for biodiversity (protected areas, Key Biodiversity Areas [KBA], sea turtle nesting sites, cold- and warm-water corals, seamounts, seagrass beds, mangroves, saltmarshes, hydrothermal vents and cold seeps) based on their overlap with Critical Habitat criteria, as defined by IFC. In total, 5798×103 km2 (1.6%) of the analysis area (global ocean plus coastal land strip) were classed as Likely Critical Habitat, and 7526×103 km2 (2.1%) as Potential Critical Habitat; the remainder (96.3%) were Unclassified. The latter was primarily due to the paucity of biodiversity data in marine areas beyond national jurisdiction and/or in deep waters, and the comparatively fewer protected areas and KBAs in these regions. Globally, protected areas constituted 65.9% of the combined Likely and Potential Critical Habitat extent, and KBAs 29.3%, not accounting for the overlap between these two features. Relative Critical Habitat extent in Exclusive Economic Zones varied dramatically between countries. This work is likely to be of particular use for industries operating in the marine and coastal realms as an early screening aid prior to in situ Critical Habitat assessment; to financial institutions making investment decisions; and to those wishing to implement good practice policies relevant to biodiversity management. Supplementary material (available online) includes other global datasets considered, documentation and justification of biodiversity feature classification, detail of IFC PS6 criteria/scenarios, and coverage calculations

Contrasting Effects of Al Substitution on Microbial Reduction of Fe(III) (Hydr)oxides

Aluminum, one of the most abundant elements in soils and sediments, is commonly found co-precipitated with Fe in natural Fe(III) (hydr)oxides; yet, little is known about how Al substitution impacts bacterial Fe(III) reduction. Accordingly, we investigated the reduction of Al substituted (0–13 mol% Al) goethite, lepidocrocite, and ferrihydrite by the model dissimilatory Fe(III)-reducing bacterium (DIRB), Shewanella putrefaciens CN32. Here we reveal that the impact of Al on microbial reduction varies with Fe(III) (hydr)oxide type. No significant difference in Fe(III) reduction was observed for either goethite or lepidocrocite as a function of Al substitution. In contrast, Fe(III) reduction rates significantly decreased with increasing Al substitution of ferrihydrite, with reduction rates of 13% Al-ferrihydrite more than 50% lower than pure ferrihydrite. Although Al substitution changed the minerals’ surface area, particle size, structural disorder, and abiotic dissolution rates, we did not observe a direct correlation between any of these physiochemical properties and the trends in bacterial Fe(III) reduction. Based on projected Al-dependent Fe(III) reduction rates, reduction rates of ferrihydrite fall below those of lepidocrocite and goethite at substitution levels equal to or greater than 18 mol% Al. Given the prevalence of Al substitution in natural Fe(III) (hydr)oxides, our results bring into question the conventional assumptions about Fe (hydr)oxide bioavailability and suggest a more prominent role of natural lepidocrocite and goethite phases in impacting DIRB activity in soils and sediments.Engineering and Applied Science

Retarded long-range potentials for the alkali-metal atoms and a perfectly conducting wall

The retarded long-range potentials for hydrogen and alkali-metal atoms in their ground states and a perfectly conducting wall are calculated. The potentials are given over a wide range of atom-wall distances and the validity of the approximations used is established.Comment: RevTeX, epsf, 11 pages, 2 fig