998 research outputs found

    Leading logarithm calculation of the e^+ e^- -> e^+ \nu_e \bar{u} d cross section

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    We analytically evaluate in the leading logarithm approximation the differential cross section for e^+ e^- -> e^+ \nu_e \bar{u} d. We compare our order \alpha^4 \alpha_s^0 leading-log result to the order \alpha^4 \alpha_s^0 exact result obtained from the GRC4F Monte Carlo program. Finally we use the Gluck, Reya, Schienbien distribution of partons in a virtual photon, which incorporates both evolution and nonperturbative strong interaction contributions, to obtain better estimates of the differential cross section.Comment: 10 pages including 9 figure

    Lower bounds on the dilation of plane spanners

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    (I) We exhibit a set of 23 points in the plane that has dilation at least 1.43081.4308, improving the previously best lower bound of 1.41611.4161 for the worst-case dilation of plane spanners. (II) For every integer n13n\geq13, there exists an nn-element point set SS such that the degree 3 dilation of SS denoted by δ0(S,3) equals 1+3=2.7321\delta_0(S,3) \text{ equals } 1+\sqrt{3}=2.7321\ldots in the domain of plane geometric spanners. In the same domain, we show that for every integer n6n\geq6, there exists a an nn-element point set SS such that the degree 4 dilation of SS denoted by δ0(S,4) equals 1+(55)/2=2.1755\delta_0(S,4) \text{ equals } 1 + \sqrt{(5-\sqrt{5})/2}=2.1755\ldots The previous best lower bound of 1.41611.4161 holds for any degree. (III) For every integer n6n\geq6 , there exists an nn-element point set SS such that the stretch factor of the greedy triangulation of SS is at least 2.02682.0268.Comment: Revised definitions in the introduction; 23 pages, 15 figures; 2 table

    Prospects of pulsed amperometric detection in flow-based analytical systems: a review

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    Electrochemical (EC) detection techniques in flow-based analytical systems such as flow injection analysis (FIA), capillary electrophoresis (CE), and liquid chromatography (LC) have attracted continuous interest over the last three decades, leading to significant advances in EC detection of a wide range of analytes in the liquid phase. In this context, the unique advantages of pulsed amperometric detection (PAD) in terms of high sensitivity and selectivity, and electrode cleaning through the application of pulsed potential for noble metal electrodes (e.g. Au, Pt), have established PAD as an important detection technique for a variety of electrochemically active compounds. PAD is especially valuable for analytes not detectable by ultraviolet (UV) photometric detection, such as organic aliphatic compounds and carbohydrates, especially when used with miniaturised capillary and chip-based separation methods. These applications have been accomplished through advances in PAD potential waveform design, as well as through the incorporation of nanomaterials (NMs) employed as microelectrodes in PAD. PAD allows on-line pulsed potential cleaning and coupling with capillary or standard separation techniques. The NMs are largely employed in microelectrodes to speed up mass and electron transfer between electrode surfaces and to perform as reactants in EC analysis. These advances in PAD have improved the sensitive and selective EC detection of analytes, especially in biological samples with complex sample matrices, and detection of electro-inactive compounds such as aliphatic organic compounds (i.e., formic acid, acetic acid, maleic acids, and β-cyclodextrin complexes). This review addresses the fundamentals of PAD, the role of pulsed sequences in AD, the utilization of different EC detectors for PAD, technological advancements in PAD waveforms, utilisation of microelectrodes in PAD techniques, advances in the use of NMs in PAD, the applications of PAD, and prospects for EC detection, with emphasis on PAD in flow-based systems

    Multivariate analysis of the effects of age, particle size and landfill depth on heavy metals pollution content of closed and active landfill precursors

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    The file attached to this record is the author's final peer reviewed version. The Publisher's final version can be found by following the DOI link.Multivariate analysis of a heavy metal pollution survey of closed and active landfill precursors was carried out in order to compare environmental risk levels in relation to age, particle size and depth of the precursors. Landfill precursors (77) were collected and analyzed for 15 USEPA toxic heavy metals using ICP-MS. Heavy metals concentrations in closed landfill precursors were significantly higher than those in the active landfill for 11 of 15 heavy metals investigated (closed landfill order: Fe > Al > Mn > Cu > Pb > Ba> Co > Cr > Ni > Cd > As > Se > Ti). Cluster analysis and correlation studies indicated the distribution of the metals was more influenced by landfill precursor size than by depth of the sample. Principal component analysis (PCA) showed that 10 of 15 of heavy metals of both landfill precursors were from similar anthropogenic sources. Heavy metals pollution indices (Igeo > 5, EF > 40 and CF > 7) of both active and closed landfill precursors exceeded limits in the order of Zn > Cd > Pb > Cu > Ag, indicating a major potential health risk influenced by age and particle size of precursor. Zn, Cd, Cu and Pb of both landfill precursors exceeded the USEPA set standard for assessment of human health risk for each of the metals (1×10 -4 to 1× 10-3). This study highlights the need for the integration of a clean-up process for precursors from both types of landfill to reduce possible environmental pollution during a reuse process

    Conversion of solid waste to activated carbon to improve landfill sustainability

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    The file attached to this record is the author's final peer reviewed version. The Publisher's final version can be found by following the DOI link.Landfills’ heterogeneous composites waste were evaluated as precursors for generation of activated carbon (AC). A single step chemical activation process was applied involving irradiation with microwave energy and impregnation with KOH. The average percentage yield of AC from active landfill precursor was higher than that from closed landfill for all depths sampled. Increase in impregnation ratio and irradiation power decreased the average percentage yield for both landfill precursors (Active: 38.1 to 33.1%) (Closed 42.1: to 33.3%). The optimum pH range for adsorption of methylene blue was pH 6-7, while adsorption increased with increase in temperature over the range 30 to 50oC. Carbonyl and hydroxyl groups were the major functional groups on the surface of AC. The properties of the AC are potentially suitable for the removal of cationic dyes and pollutants. AC generated from the landfill composite were comparable to that from some other biomass being managed through AC generation. This is the first report to demonstrate the possible reuse of landfill composite as AC. The reuse option of landfill composite could provide a means of sustainable management of landfilled municipal waste
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