Scintillation counter with MRS APD light readout

START, a high-efficiency and low-noise scintillation detector for ionizing particles, was developed for the purpose of creating a high-granular system for triggering cosmic muons. Scintillation light in START is detected by MRS APDs (Avalanche Photo-Diodes with Metal-Resistance-Semiconductor structure), operated in the Geiger mode, which have 1 mm^2 sensitive areas. START is assembled from a 15 x 15 x 1 cm^3 scintillating plastic plate, two MRS APDs and two pieces of wavelength-shifting optical fiber stacked in circular coils inside the plastic. The front-end electronic card is mounted directly on the detector. Tests with START have confirmed its operational consistency, over 99% efficiency of MIP registration and good homogeneity. START demonstrates a low intrinsic noise of about 10^{-2} Hz. If these detectors are to be mass-produced, the cost of a mosaic array of STARTs is estimated at a moderate level of 2-3 kUSD/m^2.Comment: 6 pages, 5 figure

Softening of Cu-O bond stretching phonon in tetragonal HgBa2_2CuO4+δ_{4+\delta}

Phonons in nearly optimally doped HgBa$_2$CuO$_{4+\delta}$ were studied by inelastic X-ray scattering. The dispersion of the low energy modes is well described by a shell model, while the Cu-O bond stretching mode at high energy shows strong softening towards the zone boundary, which deviates strongly from the model. This seems to be common in the hole-doped high-$T_\mathrm{c}$ superconducting cuprates, and, based on this work, not related to a lattice distortion specific to each material.Comment: 5 pages, 4 figures, accepted for publication in Phys. Rev. Let

Ab-initio study of structure and dynamics properties of crystalline ice

We investigated the structural and dynamical properties of a tetrahedrally coordinated crystalline ice from first principles based on density functional theory within the generalized gradient approximation with the projected augmented wave method. First, we report the structural behaviour of ice at finite temperatures based on the analysis of radial distribution functions obtained by molecular dynamics simulations. The results show how the ordering of the hydrogen bonding breaks down in the tetrahedral network of ice with entropy increase in agreement with the neutron diffraction data. We also calculated the phonon spectra of ice in a 3x1x1 supercell by using the direct method. So far, due to the direct method used in this calculation, the phonon spectra is obtained without taking into account the effect of polarization arising from dipole-dipole interactions of water molecules which is expected to yield the splitting of longitudinal and transverse optic modes at the Gamma-point. The calculated longitudinal acoustic velocities from the initial slopes of the acoustic mode is in a reasonable agreement with the neutron scatering data. The analysis of the vibrational density of states shows the existence of a boson peak at low energy of translational region a characteristic common to amorphous systems.Comment: International symposium on structure and dynamics of heterogeneous system SDHS'0

Light response of pure CsI calorimeter crystals painted with wavelength-shifting lacquer

We have measured scintillation properties of pure CsI crystals used in the shower calorimeter built for a precise determination of the pi+ -> pi0 e+ nu decay rate at the Paul Scherrer Institute (PSI). All 240 individual crystals painted with a special wavelength-shifting solution were examined in a custom-build detection apparatus (RASTA=radioactive source tomography apparatus) that uses a 137Cs radioactive gamma source, cosmic muons and a light emitting diode as complementary probes of the scintillator light response. We have extracted the total light output, axial light collection nonuniformities and timing responses of the individual CsI crystals. These results predict improved performance of the 3 pi sr PIBETA calorimeter due to the painted lateral surfaces of 240 CsI crystals. The wavelength-shifting paint treatment did not affect appreciably the total light output and timing resolution of our crystal sample. The predicted energy resolution for positrons and photons in the energy range of 10-100 MeV was nevertheless improved due to the more favorable axial light collection probability variation. We have compared simulated calorimeter ADC spectra due to 70 MeV positrons and photons with a Monte Carlo calculation of an ideal detector light response.Comment: Elsevier LaTeX, 35 pages in e-print format, 15 Postscript Figures and 4 Tables, also available at http://pibeta.phys.virginia.edu/~pibeta/subprojects/csipro/tomo/rasta.p

Lattice dynamics and electron-phonon coupling in transition metal diborides

The phonon density-of-states of transition metal diborides TMB2 with TM = Ti, V, Ta, Nb and Y has been measured using the technique of inelastic neutron scattering. The experimental data are compared with ab initio density functional calculations whereby an excellent agreement is registered. The calculations thus can be used to obtain electron-phonon spectral functions within the isotropic limit. A comparison to similar data for MgB2 and AlB2 which were subject of prior publications as well as parameters important for the superconducting properties are part of the discussion.Comment: 4 pages, 3 figure

High frequency longitudinal and transverse dynamics in water

High-resolution, inelastic x-ray scattering measurements of the dynamic structure factor S(Q,\omega) of liquid water have been performed for wave vectors Q between 4 and 30 nm^-1 in distinctly different thermodynamic conditions (T= 263 - 420 K ; at, or close to, ambient pressure and at P = 2 kbar). In agreement with previous inelastic x-ray and neutron studies, the presence of two inelastic contributions (one dispersing with Q and the other almost non-dispersive) is confirmed. The study of their temperature- and Q-dependence provides strong support for a dynamics of liquid water controlled by the structural relaxation process. A viscoelastic analysis of the Q-dispersing mode, associated with the longitudinal dynamics, reveals that the sound velocity undergoes the complete transition from the adiabatic sound velocity (c_0) (viscous limit) to the infinite frequency sound velocity (c_\infinity) (elastic limit). On decreasing Q, as the transition regime is approached from the elastic side, we observe a decrease of the intensity of the second, weakly dispersing feature, which completely disappears when the viscous regime is reached. These findings unambiguously identify the second excitation to be a signature of the transverse dynamics with a longitudinal symmetry component, which becomes visible in the S(Q,\omega) as soon as the purely viscous regime is left.Comment: 28 pages, 12 figure

Isotope effects and possible pairing mechanism in optimally doped cuprate superconductors

We have studied the oxygen-isotope effects on T_{c} and in-plane penetration depth \lambda_{ab}(0) in an optimally doped 3-layer cuprate Bi_{1.6}Pb_{0.4}Sr_{2}Ca_{2}Cu_{3}O_{10+y} (T_{c} \sim 107 K). We find a small oxygen-isotope effect on T_{c} (\alpha_{O} = 0.019), and a substantial effect on \lambda_{ab} (0) (\Delta \lambda_{ab} (0)/\lambda_{ab} (0) = 2.5\pm0.5%). The present results along with the previously observed isotope effects in single-layer and double-layer cuprates indicate that the isotope exponent \alpha_{O} in optimally doped cuprates is small while the isotope effect on the in-plane effective supercarrier mass is substantial and nearly independent of the number of the CuO_{2} layers. A plausible pairing mechanism is proposed to explain the isotope effects, high-T_{c} superconductivity and tunneling spectra in a consistent way.Comment: 5 pages, 4 figure

LiBC by polarized Raman spectroscopy: Evidence for lower crystal symmetry ?

The paper presents polarized Raman scattering study on a few-micron-size crystallite of LiBC with natural faces. The experiment on as grown sample has revealed a four lattice modes with frequencies at 1276 cm^-1, 830 cm^-1, 546 cm^-1 and 170 cm^-1, respectively. The number of observed Raman lines and their selection rules are incompatible with the assumed D6h symmetry. The modes at 1276 cm^-1 and 170 cm^-1 correspond to the expected Raman active modes. In contrast with the superconducting compound MgB2, the B-C bond stretching mode (at 1276 cm^-1) has rather small damping. The two "forbidden" modes (at 830 cm^-1 and 546 cm^-1) disappeared after subsequent thermal treatment.Comment: 4 pages, LaTeX, complementary experimental resul

Far-infrared vibrational properties of high-pressure-high-temperature C60 polymers and the C60 dimer

We report high-resolution far-infrared transmission measurements of the 2 + 2 cycloaddition C-60 dimer and two-dimensional rhombohedral and one-dimensional orthorhombic high-pressure high-temperature C60 polymers. In the spectral region investigated(20-650 cm(-1)), we see no low-energy interball modes, but symmetry breaking of the linked C-60 balls is evident in the complex spectrum of intramolecular modes. Experimental features suggest large splittings or frequency shifts of some IhC60-derived modes that are activated by symmetry reduction, implying that the balls are strongly distorted in these structures. We have calculated the vibrations of all three systems by first-principles quantum molecular dynamics and use them to assign the predominant IhC60 symmetries of observed modes. Pur calculations show unprecedentedly large downshifts of T-1u(2)-derived modes and extremely large splittings of other modes, both of which are consistent with the experimental spectra. For the rhombohedral and orthorhombic polymers, the T-1u(2)-derived mode that is polarized along the bonding direction is calculated to downshift below any T-1u(1)-derived modes. We also identify a previously unassigned feature near 610 cm(-1) in all three systems as a widely split or shifted mode derived from various silent IhC60 vibrations, confirming a strong perturbation model for these linked fullerene structures