Local structure of percolating gels at very low volume fractions

The formation of colloidal gels is strongly dependent on the volume fraction of the system and the strength of the interactions between the colloids. Here we explore very dilute solutions by the means of numerical simulations, and show that, in the absence of hydrodynamic interactions and for sufficiently strong interactions, percolating colloidal gels can be realised at very low values of the volume fraction. Characterising the structure of the network of the arrested material we find that, when reducing the volume fraction, the gels are dominated by low-energy local structures, analogous to the isolated clusters of the interaction potential. Changing the strength of the interaction allows us to tune the compactness of the gel as characterised by the fractal dimension, with low interaction strength favouring more chain-like structures

Recasting a model atomistic glassformer as a system of icosahedra

We consider a binary Lennard-Jones glassformer whose super-Arrhenius dynamics are correlated with the formation of icosahedral structures. Upon cooling these icosahedra organize into mesoclusters. We recast this glassformer as an effective system of icosahedra which we describe with a population dynamics model. This model we parameterize with data from the temperature regime accessible to molecular dynamics simulations. We then use the model to determine the population of icosahedra in mesoclusters at arbitrary temperature. Using simulation data to incorporate dynamics into the model we predict relaxation behavior at temperatures inaccessible to conventional approaches. Our model predicts super-Arrhenius dynamics whose relaxation time remains finite for non-zero temperature.Comment: 10 pages, 9 figure

Structure in sheared supercooled liquids:Dynamical rearrangements of an effective system of icosahedra

We consider a binary Lennard-Jones glassformer whose super-Arrhenius dynamics are correlated with the formation of particles organized into icosahedra under simple steady state shear. We recast this glassformer as an effective system of icosahedra [Pinney et al. J. Chem. Phys. 143 244507 (2015)]. From the observed population of icosahedra in each steady state, we obtain an effective temperature which is linearly dependent on the shear rate in the range considered. Upon shear banding, the system separates into a region of high shear rate and a region of low shear rate. The effective temperatures obtained in each case show that the low shear regions correspond to a significantly lower temperature than the high shear regions. Taking a weighted average of the effective temperature of these regions (weight determined by region size) yields an estimate of the effective temperature which compares well with an effective temperature based on the global mesocluster population of the whole system.Comment: accepted by J. Chehm. Phy

Path-dependent initialization of a single quantum dot exciton spin in a nanophotonic waveguide

We demonstrate a scheme for in-plane initialization of a single exciton spin in an InGaAs quantum dot (QD) coupled to a GaAs nanobeam waveguide. The chiral coupling of the QD and the optical mode of the nanobeam enables spin initialization fidelity approaching unity in magnetic field B=1 T and >0.9 without the field. We further show that this in-plane excitation scheme is independent of the incident excitation laser polarization and depends solely on the excitation direction. This scheme provides a robust in-plane spin excitation basis for a photon-mediated spin network for quantum information applications

On-chip electrically controlled routing of photons from a single quantum dot

Electrical control of on-chip routing of photons emitted by a single InAs/GaAs self-assembled quantum dot (SAQD) is demonstrated in a photonic crystal cavity-waveguide system. The SAQD is located inside an H1 cavity, which is coupled to two photonic crystal waveguides. The SAQD emission wavelength is electrically tunable by the quantum-confined Stark effect. When the SAQD emission is brought into resonance with one of two H1 cavity modes, it is preferentially routed to the waveguide to which that mode is selectively coupled. This proof of concept provides the basis for scalable, low-power, high-speed operation of single-photon routers for use in integrated quantum photonic circuits

Non-equilibrium sedimentation of colloids on the particle scale

We investigate sedimentation of model hard sphere-like colloidal dispersions confined in horizontal capillaries using laser scanning confocal microscopy, dynamical density functional theory, and Brownian dynamics computer simulations. For homogenized initial states we obtain quantitative agreement of the results from the respective approaches for the time evolution of the one-body density distribution and the osmotic pressure on the walls. We demonstrate that single particle information can be obtained experimentally in systems that were initialized further out-of-equilibrium such that complex lateral patterns form.Comment: to be published in Phys. Rev. Let

Monolithic integration of a quantum emitter with a compact on-chip beam-splitter

A fundamental component of an integrated quantum optical circuit is an on-chip beam-splitter operating at the single-photon level. Here, we demonstrate the monolithic integration of an on-demand quantum emitter in the form of a single self-assembled InGaAs quantum dot (QD) with a compact (>10 μm), air clad, free standing directional coupler acting as a beam-splitter for anti-bunched light. The device was tested by using single photons emitted by a QD embedded in one of the input arms of the device. We verified the single-photon nature of the QD signal by performing Hanbury Brown-Twiss measurements and demonstrated single-photon beam splitting by cross-correlating the signal from the separate output ports of the directional coupler

Sibling discourses of future planning for individuals with learning disabilities: An exploration of taboo

Background: Given the enhanced life expectancy of individuals with learning disabilities, siblings are increasingly adopting caregiving responsibilities when parents are no longer able. Therefore, future care planning in families is significantly important; however, previous research highlights challenges with this process. To date, research has primarily focused on future planning from parents’ perspectives. This study explores how siblings talk about the future care planning process within the family context, attending specifically to taboo discourses. Materials and Methods: Twelve siblings of individuals with learning disabilities were interviewed about planning the future care of their brother and/or sister. The data were subsequently subject to discourse analysis. Results: Siblings were reluctant to engage in explicit future planning discussions, which drew on several taboo topics including death, conflict and obligation. Consequently, siblings employed multiple discursive strategies to evade, manage and negotiate troublesome talk. Conclusions: In addition to parents, siblings also pose a barrier to future planning. Avoidance of discussion may shield them from criticism and vulnerability, whilst also protecting familial relationships. Professionals need to recognise the challenges these conversations raise for siblings. They should endeavour to involve siblings, in order to facilitate open dialogue and collaborative future planning

On-chip resonantly-driven quantum emitter with enhanced coherence

Advances in nanotechnology provide techniques for the realisation of integrated quantum-optical circuits for on-chip quantum information processing(QIP). The indistinguishable single photons, required for such devices can be generated by parametric down-conversion, or from quantum emitters such as colour centres and quantum dots(QDs). Among these, semiconductor QDs offer distinctive capabilities including on-demand operation, coherent control, frequency tuning and compatibility with semiconductor nanotechnology. Moreover, the coherence of QD photons can be significantly enhanced in resonance fluorescence(RF) approaching at its best the coherence of the excitation laser. However, the implementation of QD RF in scalable on-chip geometries remains challenging due to the need to suppress stray laser photons. Here we report on-chip QD RF coupled into a single-mode waveguide with negligible resonant laser background and show that the coherence is enhanced compared to off-resonant excitation. The results pave the way to a novel class of integrated quantum-optical devices for on-chip QIP with embedded resonantly-driven quantum emitters

Backward Cherenkov radiation emitted by polariton solitons in a microcavity wire

Exciton-polaritons in semiconductor microcavities form a highly nonlinear platform to study a variety of effects interfacing optical, condensed matter, quantum and statistical physics. We show that the complex polariton patterns generated by picosecond pulses in microcavity wire waveguides can be understood as the Cherenkov radiation emitted by bright polariton solitons, which is enabled by the unique microcavity polariton dispersion, which has momentum intervals with positive and negative group velocities. Unlike in optical fibres and semiconductor waveguides, we observe that the microcavity wire Cherenkov radiation is predominantly emitted with negative group velocity and therefore propagates backwards relative to the propagation direction of the emitting soliton. We have developed a theory of the microcavity wire polariton solitons and of their Cherenkov radiation and conducted a series of experiments, where we have measured polariton-soliton pulse compression, pulse breaking and emission of the backward Cherenkov radiation