The potential of artificial aging for modelling of natural aging processes of ballpoint ink

Artificial aging has been used to reproduce natural aging processes in an accelerated pace. Questioned documents were exposed to light or high temperature in a well-defined manner in order to simulate an increased age. This may be used to study the aging processes or to date documents by reproducing their aging curve. Ink was studied especially because it is deposited on the paper when a document, such as a contract, is produced. Once on the paper, aging processes start through degradation of dyes, solvents drying and resins polymerisation. Modelling of dye's and solvent's aging was attempted. These processes, however, follow complex pathways, influenced by many factors which can be classified as three major groups: ink composition, paper type and storage conditions. The influence of these factors is such that different aging states can be obtained for an identical point in time. Storage conditions in particular are difficult to simulate, as they are dependent on environmental conditions (e.g. intensity and dose of light, temperature, air flow, humidity) and cannot be controlled in the natural aging of questioned documents. The problem therefore lies more in the variety of different conditions a questioned document might be exposed to during its natural aging, rather than in the simulation of such conditions in the laboratory. Nevertheless, a precise modelling of natural aging curves based on artificial aging curves is obtained when performed on the same paper and ink. A standard model for aging processes of ink on paper is therefore presented that is based on a fit of aging curves to a power law of solvent concentrations as a function of time. A mathematical transformation of artificial aging curves into modelled natural aging curves results in excellent overlap with data from real natural aging processes

A simplex of bound entangled multipartite qubit states

We construct a simplex for multipartite qubit states of even number n of qubits, which has the same geometry concerning separability, mixedness, kind of entanglement, amount of entanglement and nonlocality as the bipartite qubit states. We derive the entanglement of the class of states which can be described by only three real parameters with the help of a multipartite measure for all discrete systems. We prove that the bounds on this measure are optimal for the whole class of states and that it reveals that the states possess only n-partite entanglement and not e.g. bipartite entanglement. We then show that this n-partite entanglement can be increased by stochastic local operations and classical communication to the purest maximal entangled states. However, pure n-partite entanglement cannot be distilled, consequently all entangled states in the simplex are n-partite bound entangled. We study also Bell inequalities and find the same geometry as for bipartite qubits. Moreover, we show how the (hidden) nonlocality for all n-partite bound entangled states can be revealed.Comment: 11 pages, 4 figures; 2nd version changed considerably and a detailed derivation of the multipartite measure is include

Lorentz invariance of entanglement classes in multipartite systems

We analyze multipartite entanglement in systems of spin-1/2 particles from a relativistic perspective. General conditions which have to be met for any classification of multipartite entanglement to be Lorentz invariant are derived, which contributes to a physical understanding of entanglement classification. We show that quantum information in a relativistic setting requires the partition of the Hilbert space into particles to be taken seriously. Furthermore, we study exemplary cases and show how the spin and momentum entanglement transforms relativistically in a multipartite setting.Comment: v2: 5 pages, 4 figures, minor changes to main body, journal references update

Discovery of the VHE gamma-ray source HESS J1641-463

A new TeV source, HESS J1641-463, has been serendipitously discovered in the Galactic plane by the High Energy Stereoscopic System (H.E.S.S.) at a significance level of 8.6 standard deviations. The observations of HESS J1641-463 were performed between 2004 and 2011 and the source has a moderate flux level of 1.7% of the Crab Nebula flux at E > 1 TeV. HESS J1641-463 has a rather hard photon index of 1.99 +- 0.13_stat +- 0.20_sys. HESS J1641-463 is positionally coincident with the radio supernova remnant SNR G338.5+0.1, but no clear X-ray counterpart has been found in archival Chandra observations of the region. Different possible VHE production scenarios will be discussed in this contribution.Comment: 5 pages, 5 figures, 2012 Fermi Symposium proceedings - eConf C12102

How nucleation and luminosity shape faint dwarf galaxies

We study the intrinsic shapes of a sample of over 400 quiescent galaxies in the cores of the Virgo and Fornax clusters with luminosities $10^{6} \leq L_{g}/L_{\odot} \leq 10^{8}$. Similar to satellites of the Local Group and Centaurus A, these faint, low surface brightness cluster galaxies are best described as a family of thick ($C/A > 0.5$), oblate-triaxial spheroids. However, the large sample size allows us to show that the flattening of their stellar distributions depends both on luminosity and on the presence of a nuclear star cluster. Nucleated satellites are thicker at all luminosities compared to their non-nucleated counterparts, and fainter galaxies are systematically thicker as well, regardless of nucleation. Once nucleation is accounted for, we find no evidence that the environment the satellites live in plays a relevant role in setting their three-dimensional structure. We interpret both the presence of stellar nuclei and the associated thicker shapes as the result of preferential early and rapid formation, effectively making these faint nucleated galaxies the first generation of cluster satellites.Comment: Accepted for publication in MNRAS Letter

Chemical Characterization and Source Apportionment of Household Fine Particulate Matter in Rural, Peri-urban, and Urban West Africa

Household air pollution in sub-Saharan Africa and other developing regions is an important cause of disease burden. Little is known about the chemical composition and sources of household air pollution in sub-Saharan Africa, and how they differ between rural and urban homes. We analyzed the chemical composition and sources of fine particles (PM2.5) in household cooking areas of multiple neighborhoods in Accra, Ghana, and in peri-urban (Banjul) and rural (Basse) areas in The Gambia. In Accra, biomass burning accounted for 39–62% of total PM2.5 mass in the cooking area in different neighborhoods; the absolute contributions were 10–45 μg/m3. Road dust and vehicle emissions comprised 12–33% of PM2.5 mass. Solid waste burning was also a significant contributor to household PM2.5 in a low-income neighborhood but not for those living in better-off areas. In Banjul and Basse, biomass burning was the single dominant source of cooking-area PM2.5, accounting for 74–87% of its total mass; the relative and absolute contributions of biomass smoke to PM2.5 mass were larger in households that used firewood than in those using charcoal, reaching as high as 463 μg/m3 in Basse homes that used firewood for cooking. Our findings demonstrate the need for policies that enhance access to cleaner fuels in both rural and urban areas, and for controlling traffic emissions in cities in sub-Saharan Africa

Oligomer formation during gas-phase ozonolysis of small alkenes and enol ethers: new evidence for the central role of the Criegee Intermediate as oligomer chain unit

An important fraction of secondary organic aerosol (SOA) formed by atmospheric oxidation of diverse volatile organic compounds (VOC) has recently been shown to consist of high-molecular weight oligomeric species. In our previous study (Sadezky et al., 2006), we reported the identification and characterization of oligomers as main constituents of SOA from gas-phase ozonolysis of small enol ethers. These oligomers contained repeated chain units of the same chemical composition as the main Criegee Intermediates (CI) formed during the ozonolysis reaction, which were CH<sub>2</sub>O<sub>2</sub> (mass 46) for alkyl vinyl ethers (AVE) and C<sub>2</sub>H<sub>4</sub>O<sub>2</sub> (mass 60) for ethyl propenyl ether (EPE). In the present work, we extend our previous study to another enol ether (ethyl butenyl ether EBE) and a variety of structurally related small alkenes (<i>trans</i>-3-hexene, <i>trans</i>-4-octene and 2,3-dimethyl-2-butene). <br><br> Experiments have been carried out in a 570 l spherical glass reactor at atmospheric conditions in the absence of seed aerosol. SOA formation was measured by a scanning mobility particle sizer (SMPS). SOA filter samples were collected and chemically characterized off-line by ESI(+)/TOF MS and ESI(+)/TOF MS/MS, and elemental compositions were determined by ESI(+)/FTICR MS and ESI(+)/FTICR MS/MS. The results for all investigated unsaturated compounds are in excellent agreement with the observations of our previous study. Analysis of the collected SOA filter samples reveal the presence of oligomeric compounds in the mass range 200 to 800 u as major constituents. The repeated chain units of these oligomers are shown to systematically have the same chemical composition as the respective main Criegee Intermediate (CI) formed during ozonolysis of the unsaturated compounds, which is C<sub>3</sub>H<sub>6</sub>O<sub>2</sub> (mass 74) for ethyl butenyl ether (EBE), <i>trans</i>-3-hexene, and 2,3-dimethyl-2-butene, and C<sub>4</sub>H<sub>8</sub>O<sub>2</sub> (mass 88) for extit{trans}-4-octene. Analogous fragmentation pathways among the oligomers formed by gas-phase ozonolysis of the different alkenes and enol ethers in our present and previous study, characterized by successive losses of the respective CI-like chain unit as a neutral fragment, indicate a similar principal structure. In this work, we confirm the basic structure of a linear oligoperoxide – [CH(R)-O-O]<sub>n</sub> – for all detected oligomers, with the repeated chain unit CH(R)OO corresponding to the respective major CI. The elemental compositions of parent ions, fragment ions and fragmented neutrals determined by accurate mass measurements with the FTICR technique allow us to assign a complete structure to the oligomer molecules. We suggest that the formation of the oligoperoxidic chain units occurs through a new gas-phase reaction mechanism observed for the first time in our present work, which involves the addition of stabilized CI to organic peroxy radicals. Furthermore, copolymerization of CI simultaneously formed in the gas phase from two different unsaturated compounds is shown to occur during the ozonolysis of a mixture of extit{trans}-3-hexene and ethyl vinyl ether (EVE), leading to formation of oligomers with mixed chain units C<sub>3</sub>H<sub>6</sub>O<sub>2</sub> (mass 74) and CH<sub>2</sub>O<sub>2</sub> (mass 46). We therefore suggest oligoperoxide formation by repeated peroxy radical-stabilized CI addition to be a general reaction pathway of small stabilized CI in the gas phase, which represents an alternative way to high-molecular products and thus contributes to SOA formation

Quarkonia production with the Hera-B experiment

Measurements of the dependence of the J/Psi production cross section on its kinematic variables as well as on the target atomic numbers for 920 GeV/c protons incident on different targets have been made with the Hera-B detector. The large collected di-lepton sample allows to study the production ratio of Psi(2S) to J/Psi and of Chic to J/Psi . We also report on measurements of the b-bbar and Upsilon production cross section.Comment: 9 pages, 11 figure

Baryonic Effect on chi_cJ Suppression in Au+Au Collisions at RHIC Energies

We predict that initially produced chi_cJ mesons at low transverse momentum in the central rapidity region are almost dissociated by nucleons and antinucleons in hadronic matter produced in central Au+Au collisions at RHIC energies sqrt {s_{NN}}= 130 and 200 GeV. In calculations the nucleon and antinucleon distributions in hadronic matter are results of evolution from their freeze-out distributions which well fit the experimental p_T spectra of proton and antiproton. Any measured chi_cJ mesons at low p_T are generated from deconfined matter and give an explicit proof of regeneration mechanism (recombination mechanism).Comment: 10 pages, 3 figures, Latex, a discussion added to the referenc