An investigation of adhesive/adherend and fiber matrix interactions

Research during the report period focused on continued scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) of lap shear samples and flatwise tensile specimens and on the surface characterization of TiO2, Ti 6-4, and Ti powders with particular emphasis on their interaction with primer solutions of both polyphenylquinoxaline and LaRC-13 polyimide. The use of SEM and XPS in the analysis of Ti 6-4 adherend surfaces is described as well as differences in Ti 6-4 surface composition after different chemical pretreatments. Analysis of fractured surfaces is used to established the failure mode. The surface acidity of Ti 6-4 coupons can be established by reflectance visible spectroscopy using indicator dyes

Editorial: Language of Possibilities and Sense of the 1m/possible in Art Education

Schooling in the United States is increasingly defined by arthritic traditionalisms of standardized assessments and testing, school and teacher accountabilities, models of exacerbated efficiency and tracking, and even more strident state and federal calls for more of the same (Kanpol, 1997, p. ix). Mired in escalating restricted conventional practices that deny humanistic and democratic possibilities, many art educators are frequently unaware of what, in reality, is possible with/in art/ education. Moreover, our praxis continues to reflect dispositions and actions that are oftentimes bereft of the language of possibility or hope. Using the language of possibility, we transform our thinking from how it has been to how it could be. Those who achieve the impossible tend to focus their thoughts and energies on possibilities rather than limitations. Possibilities encompass the big picture, and provide hope for the future. To predict the future, we are obliged to actively create it. Even impossibilities give way to possibilities when we exhibit conduct, habits, or ways that lead to success. What we envision today with/in art/education, raising the quality of education, equity of opportunity in education, social responsibility, research, and possible initiatives, will give birth to worlds of possibilities

A fundamental approach to adhesion: Synthesis, surface analysis, thermodynamics and mechanics

Pretreated and primed Ti 6-4 surfaces were characterized by scanning electron microscopy/energy dispersive analysis of X-rays (SEM/EDAX) and electron spectroscopy for chemical analysis (ESCA). Fractured lap shear bonded Ti 6-4 specimens were also characterized by SEM/EDAX and ESCA. A number of surface techniques were used to characterize Ti02 powders

A fundamental approach to adhesion: Synthesis, surface analysis, thermodynamics and mechanics

Several techniques were used to study pretreated Ti 6-4 surfaces including scanning electron microscopy (SEM), electron spectroscopy of chemical analysis (ESCA), and, reflectance visible spectroscopy. Each pretreatment type gave a characteristic surface morphology as seen by SEM. Elemental analysis of the Ti 6-4 surfaces was done using ESCA. Trace residual contaminants from particular chemical pretreatments were identified readily. Results indicate that reflectance visible spectroscopy using indicator dyes placed on Ti 6-4 surfaces appears to be a feasible approach to establish surface acidity. Differences in surface acidity were observed using bromthymol blue on Ti 6-4 surfaces pretreated by two different methods

Continuity of symplectically adjoint maps and the algebraic structure of Hadamard vacuum representations for quantum fields on curved spacetime

We derive for a pair of operators on a symplectic space which are adjoints of each other with respect to the symplectic form (that is, they are sympletically adjoint) that, if they are bounded for some scalar product on the symplectic space dominating the symplectic form, then they are bounded with respect to a one-parametric family of scalar products canonically associated with the initially given one, among them being its ``purification''. As a typical example we consider a scalar field on a globally hyperbolic spacetime governed by the Klein-Gordon equation; the classical system is described by a symplectic space and the temporal evolution by symplectomorphisms (which are symplectically adjoint to their inverses). A natural scalar product is that inducing the classical energy norm, and an application of the above result yields that its ``purification'' induces on the one-particle space of the quantized system a topology which coincides with that given by the two-point functions of quasifree Hadamard states. These findings will be shown to lead to new results concerning the structure of the local (von Neumann) observable-algebras in representations of quasifree Hadamard states of the Klein-Gordon field in an arbitrary globally hyperbolic spacetime, such as local definiteness, local primarity and Haag-duality (and also split- and type III_1-properties). A brief review of this circle of notions, as well as of properties of Hadamard states, forms part of the article.Comment: 42 pages, LaTeX. The Def. 3.3 was incomplete and this has been corrected. Several misprints have been removed. All results and proofs remain unchange

"Massless" vector field in de Sitter Universe

In the present work the massless vector field in the de Sitter (dS) space has been quantized. "Massless" is used here by reference to conformal invariance and propagation on the dS light-cone whereas "massive" refers to those dS fields which contract at zero curvature unambiguously to massive fields in Minkowski space. Due to the gauge invariance of the massless vector field, its covariant quantization requires an indecomposable representation of the de Sitter group and an indefinite metric quantization. We will work with a specific gauge fixing which leads to the simplest one among all possible related Gupta-Bleuler structures. The field operator will be defined with the help of coordinate independent de Sitter waves (the modes) which are simple to manipulate and most adapted to group theoretical matters. The physical states characterized by the divergencelessness condition will for instance be easy to identify. The whole construction is based on analyticity requirements in the complexified pseudo-Riemanian manifold for the modes and the two-point function.Comment: 33 pages, 3 figure

Causality, particle localization and positivity of the energy

Positivity of the Hamiltonian alone is used to show that particles, if initially localized in a finite region, immediately develop infinite tails.Comment: To appear in: Irreversibility and Causality in Quantum Theory -- Semigroups and Rigged Hilbert Spaces, edited by A. Bohm, H.-D. Doebner and P. Kielanowski, Springer Lecture Notes in Physics, Vol. 504 (1998

Pade approximants and the anharmonic oscillator

The diagonal Padé approximants of the perturbation series for the eigenvalues of the anharmonic oscillator (a βκ^1 perturbation of p^2 + κ^2) converge to the eigenvalues

At what time does a quantum experiment have a result?

This paper provides a general method for defining a generalized quantum observable (or POVM) that supplies properly normalized conditional probabilities for the time of occurrence (i.e., of detection). This method treats the time of occurrence as a probabilistic variable whose value is to be determined by experiment and predicted by the Born rule. This avoids the problematic assumption that a question about the time at which an event occurs must be answered through instantaneous measurements of a projector by an observer, common to both Rovelli (1998) and Oppenheim et al. (2000). I also address the interpretation of experiments purporting to demonstrate the quantum Zeno effect, used by Oppenheim et al. (2000) to justify an inherent uncertainty for measurements of times.Comment: To appear in proceedings of 2015 ETH Zurich Workshop on Time in Physic

On Equivalence of Duffin-Kemmer-Petiau and Klein-Gordon Equations

A strict proof of equivalence between Duffin-Kemmer-Petiau (DKP) and Klein-Gordon (KG) theories is presented for physical S-matrix elements in the case of charged scalar particles interacting in minimal way with an external or quantized electromagnetic field. First, Hamiltonian canonical approach to DKP theory is developed in both component and matrix form. The theory is then quantized through the construction of the generating functional for Green functions (GF) and the physical matrix elements of S-matrix are proved to be relativistic invariants. The equivalence between both theories is then proved using the connection between GF and the elements of S-matrix, including the case of only many photons states, and for more general conditions - so called reduction formulas of Lehmann, Symanzik, Zimmermann.Comment: 23 pages, no figures, requires macro tcilate