Processing of nano-micro copper materials for the production of conductive circuits

Copper inks potentially provide a cost-effective alternative to silver for printed electronic circuits. In glass-based applications such as PV or smart glass, they can provide a means of conductivity enhancement or additional functionality. Three inks consisting of a mixture of nano and micro copper particles were systematically studied to examine the relationship between sintering temperature, sintering time and gaseous environment on the electrical qualities of the sintered printed films deposited on FTO coated glass. There is a definite interaction between the particulate nature of the ink, the sintering conditions, and the conductive properties of the film. Films containing only nano-particles provide the most conductive films with optimum sintering conditions of temperature of 225 °C for 60 minutes. The inclusion of micro particles increased the ideal sintering temperature but lowered the sintering time. An ink containing an equal mixture of nano and micro particles exhibited the lowest performance. This could be attributed to partial oxidation of the nano-particles along the conductive path, which occurs as a result of the presence of the micro particles. Other samples were photonically sintered using a PulseForge 1200 laboratory photonic sintering unit where the number of pulses, pulse power, pulse frequency and the intra pulse gap could be varied. An initial optimization study identified an operational range of photonic energy profile. The best possible line conductivity obtained using these optimum conditions was around a 1/3 of that obtained by conventional thermal sintering. This relative conductivity of photonically sintered features further deviated from conventionally sintered features as the film thickness increased and as the line width reduced. Laser / NIR techniques were found ineffective to sinter the copper ink used in this study. The possibility to manually blend copper and silver paste ink was investigated and an optimum blend of 25% silver and 75% copper could be used which had maintained conductivity, cost, and adhesion benefits

Developing capacity sharing strategy for vehicular networks with integrated use of licensed and unlicensed spectrum

A widely deployed cellular network, supported by direct connections, can offer a promising solution that supports new services with strict requirements on access availability, reliability, and end-to-end (E2E) latency. The communications between vehicles can be made using different radio interfaces: One for cellular communication (i.e., cellular communication over the cellular network based on uplink (UL)/downlink (DL) connections) and the other for direct communication (i.e., D2D-based direct communications between vehicles which allows vehicular users (V-UEs) to communicate directly with others). Common cellular systems with licensed spectrum backed by direct communication using unlicensed spectrum can ensure high quality of service requirements for new intelligent transportation systems (ITS) services, increase network capacity and reduce overall delays. However, selecting a convenient radio interface and allocating radio resources to users according to the quality of service (QoS) requirements becomes a challenge. In this regard, let’s introduce a new radio resource allocation strategy to determine when it’s appropriate to establish the communication between the vehicles over a cellular network using licensed spectrum resources or D2D-based direct connections over unlicensed spectrum sharing with Wi-Fi. The proposed strategy aims at meeting the quality of service requirements of users, including reducing the possibility of exceeding the maximum delay restrictions and enhancing network capacity utilization in order to avoid service interruption. The proposed solution is evaluated by highlighting different conditions for the considered scenario, and it is demonstrated that the proposed strategy improves network performance in terms of transmitted data rate, packet success rate, latency, and resource usag

Thermal sintering of printable copper for enhanced conductivity of FTO coated glass substrates

Copper inks potentially provide a cost effective replacement to silver for printed electronic circuits. In glass based applications such as PV or smart glass, it can provide a means of conductivity enhancement or additional functionality. Three inks consisting of a mixture of nano and micro copper particles were systematically studied to examine the relationship between sintering temperature, sintering time and gaseous environment on the electrical qualities of the sintered printed films deposited on FTO coated glass. There is a definite interaction between the particulate nature of the ink, the sintering conditions and the conductive properties of the film. Films containing only nano-particles provide the most conductive films with optimum sintering conditions of temperatures of 225 °C for 60 min. The inclusion of micro particles increased the ideal sintering temperature but lowered the sintering time. An ink containing an equal mixture of nano and micro particles exhibited the lowest performance and this could be attributed to partial oxidation of the nano-particles along the conductive path, which occurs as a result of the presence of the micro particles

Time-Fractional Optimal Control of Initial Value Problems on Time Scales

We investigate Optimal Control Problems (OCP) for fractional systems involving fractional-time derivatives on time scales. The fractional-time derivatives and integrals are considered, on time scales, in the Riemann--Liouville sense. By using the Banach fixed point theorem, sufficient conditions for existence and uniqueness of solution to initial value problems described by fractional order differential equations on time scales are known. Here we consider a fractional OCP with a performance index given as a delta-integral function of both state and control variables, with time evolving on an arbitrarily given time scale. Interpreting the Euler--Lagrange first order optimality condition with an adjoint problem, defined by means of right Riemann--Liouville fractional delta derivatives, we obtain an optimality system for the considered fractional OCP. For that, we first prove new fractional integration by parts formulas on time scales.Comment: This is a preprint of a paper accepted for publication as a book chapter with Springer International Publishing AG. Submitted 23/Jan/2019; revised 27-March-2019; accepted 12-April-2019. arXiv admin note: substantial text overlap with arXiv:1508.0075

Synthesis of LiCo1-XNiXO2 nanomaterial by hydrothermal method as cathode for lithium ion battery

The compounds of LiCoO2 (LCO) and LiCo1-xNixO2 (LCNO), with (x=0,0.25,0.5,0.75,1) were synthesized as cathode active material for lithium–ion batteries using hydrothermal technique in this study. Structure and morphology characterization were conducted for all prepared samples. The crystalline results indicate that both LCO and LCNO possess a rhombohedral structure, while the morphology results show irregular shapes. Electrochemical tests were carried out for LiCoO2 and LiCo0.25 Ni0.75O2 samples only. From the electrochemical measurements, the LiCo0.25 Ni0.75O2 demonstrate higher charge and discharge capacities compared to the LiCoO2 electrode, findings which are consistent with the electrochemical impedance spectroscopy (EIS) results. The X-ray diffraction (XRD) results of both the prepared Lithium Cobalt Oxide (LCO) and Lithium Cobalt Nickel Oxide (LCNO) samples reveal characteristic peaks at specific angles (2θ) indicating crystallographic planes. For LCO, peaks were observed at 18.96°, 37.40°, 38.35°, 39.07°, 45.29°, 49.45°, and 59.62° corresponding to crystallographic planes (003), (101), (006), (012), (104), (015), and (107) respectively. These peaks confirm the formation of a rhombohedral LiCoO2 nanostructure with space group (R-3m no.166), consistent with standard data (JCPDS 00-016-0427). The EDX spectra of the synthesized Lithium Cobalt Oxide (LCO) and Lithium Cobalt Nickel Oxide (LCNO) were analyzed. The results showed the presence of oxygen (O), cobalt (Co), and nickel (Ni) elements. However, the peak corresponding to lithium (Li) was not visible due to its low activation energy. Finally, the synthesis and characterization of LiCoO2 (LCO) and LiCo1-xNixO2 (LCNO) compounds were conducted, with electrochemical tests indicating superior performance of LiCo0.25 Ni0.75O2 over LiCoO

Assessing the Dynamic Performance of Thermochemical Storage Materials

Thermochemical storage provides a volumetric and cost-efficient means of collecting energy from solar/waste heat in order to utilize it for space heating in another location. Equally important to the storage density, the dynamic thermal response dictates the power available which is critical to meet the varied demands of a practical space heating application. Using a laboratory scale reactor (127 cm3), an experimental study with salt in matrix (SIM) materials found that the reactor power response is primarily governed by the flow rate of moist air through the reactor and that creating salt with a higher salt fraction had minimal impact on the thermal response. The flowrate dictates the power profile of the reactor with an optimum value which balances moisture reactant delivery and reaction rate on the SIM. A mixed particle size produced the highest power (22 W) and peak thermal uplift (32 °C). A narrow particle range reduced the peak power and peak temperature as a result of lower packing densities of the SIM in the reactor. The scaled maximum power density which could be achieved is >150 kW/m3, but achieving this would require optimization of the solid–moist air interaction

Optimisation of CaCl2 impregnated expanded graphite and alginate matrices – Targeted salt loading

The incorporation of salt hydrates in thermochemical energy storage is often limited by poor kinetics and mechanical instability during charge and discharge cycles. This study explores the influence of salt loading on the energy storage capacity and charge/discharge performance of salt-impregnated expanded graphite and alginate composites. By controlling the salt bath concentration during composite synthesis, the quantity of salt within the bead can be regulated. Four composites have been synthesised with salt wt% values ranging from 63.7 to 77.2 %, resulting in salt volumetric densities form 0.22–0.52 g/cm3 and energy densities between 1052 and 1281 kJ/kg. The study found that increasing salt bath concentration above 60 % significantly decreases the porosity within the composite. This reduces moisture transfer kinetics and also fails to accommodate for salt expansion and deliquescence. Consequently, composites at near-maximum salt capacity displayed diminished discharge performance and charge efficiency. Conversely, samples below the saturation threshold exhibited greater heat output and charge efficiency, contained overhydration, and maintained structural integrity. These findings highlight the importance of carefully balancing energy storage capacity with improved reaction kinetics and stability to achieve an optimal storage solution in solar thermal systems or waste heat recovery

Experimental Study on Ultimate Strength of Steel Tube Column Filled with Reactive Powder Concrete

Composite concrete Filled Tubular Steel (CFT) members, which have excellent deformability due to the well-known confined and constrained interaction between steel tube and concrete, have largely been utilized as bridge piers or columns in high-rise buildings, resulting in increased strength and decreased column size. This study examined the experimental performance of steel tube columns filled with reactive powder concrete (RPC) under axial compression. Three sets of columns were used in the experiment, each with variations in shape (square, rectangular, and circular), length-to-diameter ratio, and compressive strength of the RPC. The first set consisted of five columns, while the second and third sets each had seven columns with three different lengths (750 mm, 600 mm, and 450 mm) and two different compressive strengths (54 and 92 MPa). A new numerical model was developed to calculate the ultimate failure load of the columns by considering factors such as the yield strength of steel, the compressive strength of concrete, the column shape, and the ratio of concrete to steel. This model was validated by comparing the results obtained from the experiments to those predicted by the model, as well as by designing equations from various codes. The results showed that the proposed numerical model accurately predicted the ultimate failure load for columns filled with different types of concrete, especially for RPC, while maintaining conservatism compared to the ACI, AISC, and EN codes equations. Doi: 10.28991/CEJ-2023-09-06-04 Full Text: PD