115 research outputs found

    Polydisperse fluid mixtures of adhesive colloidal particles

    Full text link
    We investigate polydispersity effects on the average structure factor of colloidal suspensions of neutral particles with surface adhesion. A sticky hard sphere model alternative to Baxter's one is considered. The choice of factorizable stickiness parameters in the potential allows a simple analytic solution, within the ``mean spherical approximation'', for any number of components and arbitrary stickiness distribution. Two particular cases are discussed: i) all particles have different sizes but equal stickiness (Model I), and ii) each particle has a stickiness proportional to its size (Model II). The interplay between attraction and polydispersity yields a markedly different behaviour for the two Models in regimes of strong coupling (i.e. strong adhesive forces and low temperature) and large polydispersity. These results are then exploited to reanalyze experimental scattering data on sterically stabilized silica particles.Comment: 9 pages, 2 figures (included), Physica A (2001) to appea

    Density Functional for Anisotropic Fluids

    Full text link
    We propose a density functional for anisotropic fluids of hard body particles. It interpolates between the well-established geometrically based Rosenfeld functional for hard spheres and the Onsager functional for elongated rods. We test the new approach by calculating the location of the the nematic-isotropic transition in systems of hard spherocylinders and hard ellipsoids. The results are compared with existing simulation data. Our functional predicts the location of the transition much more accurately than the Onsager functional, and almost as good as the theory by Parsons and Lee. We argue that it might be suited to study inhomogeneous systems.Comment: To appear in J. Physics: Condensed Matte

    Non-verbal information in spontaneous speech -- towards a new framework of analysis

    Full text link
    Non-verbal signals in speech are encoded by prosody and carry information that ranges from conversation action to attitude and emotion. Despite its importance, the principles that govern prosodic structure are not yet adequately understood. This paper offers an analytical schema and a technological proof-of-concept for the categorization of prosodic signals and their association with meaning. The schema interprets surface-representations of multi-layered prosodic events. As a first step towards implementation, we present a classification process that disentangles prosodic phenomena of three orders. It relies on fine-tuning a pre-trained speech recognition model, enabling the simultaneous multi-class/multi-label detection. It generalizes over a large variety of spontaneous data, performing on a par with, or superior to, human annotation. In addition to a standardized formalization of prosody, disentangling prosodic patterns can direct a theory of communication and speech organization. A welcome by-product is an interpretation of prosody that will enhance speech- and language-related technologies

    Exploring Princeton¿s Scheduling Conundrum

    No full text
    Every semester, students complain that all the courses they want to take are at the same time. But how much of this is actually problematic, and how much of this is just perception ¿ toast always falling butter-side down, so to speak? Moreover, even if there is a problem, could the University feasibly fix it? My thesis aims to answer both of these questions by algorithmically scheduling university courses based on student preferences. It explores how poorly the current schedule performs, and also how efficient various scheduling attempts are given the size of the University and the number of students. I find that Princeton¿s schedules, as they stand now, do not necessarily satisfy student preferences, and offer a number of solutions to improve them. These algorithms lead to more efficient scheduling, and more satisfied students, which would improve the Princeton academic environment

    Clustering phenomena in adhesive hard sphere fluids. Theory of freezing

    Full text link

    On the reactivity of singlet oxygen in aqueous micellar systems

    Full text link
    corecore