Bulk, surface and corner free energy series for the chromatic polynomial on the square and triangular lattices

We present an efficient algorithm for computing the partition function of the q-colouring problem (chromatic polynomial) on regular two-dimensional lattice strips. Our construction involves writing the transfer matrix as a product of sparse matrices, each of dimension ~ 3^m, where m is the number of lattice spacings across the strip. As a specific application, we obtain the large-q series of the bulk, surface and corner free energies of the chromatic polynomial. This extends the existing series for the square lattice by 32 terms, to order q^{-79}. On the triangular lattice, we verify Baxter's analytical expression for the bulk free energy (to order q^{-40}), and we are able to conjecture exact product formulae for the surface and corner free energies.Comment: 17 pages. Version 2: added 4 further term to the serie

The application of the global isomorphism to the surface tension of the liquid-vapor interface of the Lennard-Jones fluids

In this communication we show that the surface tension of the real fluids of the Lennard-Jones type can be obtained from the surface tension of the lattice gas (Ising model) on the basis of the global isomorphism approach developed earlier for the bulk properties.Comment: 8 pages, 6 figure

Study of the Potts Model on the Honeycomb and Triangular Lattices: Low-Temperature Series and Partition Function Zeros

We present and analyze low-temperature series and complex-temperature partition function zeros for the $q$-state Potts model with $q=4$ on the honeycomb lattice and $q=3,4$ on the triangular lattice. A discussion is given as to how the locations of the singularities obtained from the series analysis correlate with the complex-temperature phase boundary. Extending our earlier work, we include a similar discussion for the Potts model with $q=3$ on the honeycomb lattice and with $q=3,4$ on the kagom\'e lattice.Comment: 33 pages, Latex, 9 encapsulated postscript figures, J. Phys. A, in pres

Statistical mechanical aspects of joint source-channel coding

An MN-Gallager Code over Galois fields, $q$, based on the Dynamical Block Posterior probabilities (DBP) for messages with a given set of autocorrelations is presented with the following main results: (a) for a binary symmetric channel the threshold, $f_c$, is extrapolated for infinite messages using the scaling relation for the median convergence time, $t_{med} \propto 1/(f_c-f)$; (b) a degradation in the threshold is observed as the correlations are enhanced; (c) for a given set of autocorrelations the performance is enhanced as $q$ is increased; (d) the efficiency of the DBP joint source-channel coding is slightly better than the standard gzip compression method; (e) for a given entropy, the performance of the DBP algorithm is a function of the decay of the correlation function over large distances.Comment: 6 page

The matrix product representations for all valence bond states

We introduce a simple representation for irreducible spherical tensor operators of the rotation group of arbitrary integer or half integer rank and use these tensor operators to construct matrix product states corresponding to all the variety of valence-bond states proposed in the Affleck-Kennedy-Lieb-Tasaki (AKLT) construction. These include the fully dimerized states of arbitrary spins, with uniform or alternating patterns of spins, which are ground states of Hamiltonians with nearest and next-nearest neighbor interactions, and the partially dimerized or AKLT/VBS (Valence Bond Solid) states, which are constructed from them by projection. The latter states are translation-invariant ground states of Hamiltonians with nearest-neighbor interactions.Comment: 24 pages, references added, the version which appears in the journa

Experimental and Theoretical Evidence for Nitrogen-Fluorine Halogen Bonding in Silver-Initiated Radical Fluorinations

We report experimental and computational evidence for nitrogen–fluorine halogen bonding in Ag­(I)-initiated radical C–H fluorinations. Simple pyridines form [N–F–N]+ halogen bonds with Selectfluor to facilitate single-electron reduction by catalytic Ag­(I). Pyridine electronics affect the extent of halogen bonding, leading to significant differences in selectivity between mono- and difluorinated products. Electronic structure calculations show that halogen bonding to various pyridines alters the single-electron reduction potential of Selectfluor, which is consistent with experimental electrochemical analysis. Multinuclear correlation NMR also provides spectroscopic evidence for pyridine halogen bonding to Selectfluor under ambient conditions

Grand canonical and canonical solution of self-avoiding walks with up to three monomers per site on the Bethe lattice

We solve a model of polymers represented by self-avoiding walks on a lattice which may visit the same site up to three times in the grand-canonical formalism on the Bethe lattice. This may be a model for the collapse transition of polymers where only interactions between monomers at the same site are considered. The phase diagram of the model is very rich, displaying coexistence and critical surfaces, critical, critical endpoint and tricritical lines, as well as a multicritical point. From the grand-canonical results, we present an argument to obtain the properties of the model in the canonical ensemble, and compare our results with simulations in the literature. We do actually find extended and collapsed phases, but the transition between them, composed by a line of critical endpoints and a line of tricritical points, separated by the multicritical point, is always continuous. This result is at variance with the simulations for the model, which suggest that part of the line should be a discontinuous transition. Finally, we discuss the connection of the present model with the standard model for the collapse of polymers (self-avoiding self-attracting walks), where the transition between the extended and collapsed phases is a tricritical point.Comment: 34 pages, including 10 figure

Directed percolation near a wall

Series expansion methods are used to study directed bond percolation clusters on the square lattice whose lateral growth is restricted by a wall parallel to the growth direction. The percolation threshold $p_c$ is found to be the same as that for the bulk. However the values of the critical exponents for the percolation probability and mean cluster size are quite different from those for the bulk and are estimated by $\beta_1 = 0.7338 \pm 0.0001$ and $\gamma_1 = 1.8207 \pm 0.0004$ respectively. On the other hand the exponent $\Delta_1=\beta_1 +\gamma_1$ characterising the scale of the cluster size distribution is found to be unchanged by the presence of the wall. The parallel connectedness length, which is the scale for the cluster length distribution, has an exponent which we estimate to be $\nu_{1\parallel} = 1.7337 \pm 0.0004$ and is also unchanged. The exponent $\tau_1$ of the mean cluster length is related to $\beta_1$ and $\nu_{1\parallel}$ by the scaling relation $\nu_{1\parallel} = \beta_1 + \tau_1$ and using the above estimates yields $\tau_1 = 1$ to within the accuracy of our results. We conjecture that this value of $\tau_1$ is exact and further support for the conjecture is provided by the direct series expansion estimate $\tau_1= 1.0002 \pm 0.0003$.Comment: 12pages LaTeX, ioplppt.sty, to appear in J. Phys.

Non-Abelian Bosonization and Haldane's Conjecture

We study the long wavelength limit of a spin S Heisenberg antiferromagnetic chain. The fermionic Lagrangian obtained corresponds to a perturbed level 2S SU(2) Wess-Zumino-Witten model. This effective theory is then mapped into a compact U(1) boson interacting with Z_{2S} parafermions. The analysis of this effective theory allows us to show that when S is an integer there is a mass gap to all excitations, whereas this gap vanishes in the half-odd-integer spin case. This gives a field theory treatment of the so-called Haldane's conjecture for arbitrary values of the spin S.Comment: 9 pages REVTeX, no figure

Proceedings of the 3rd International Conference on Manufacturng Research ICMR2005: Advances in Manufacturing Technology and Management

The International Conference on Manufacturing Research (ICMR) is an annual event, normally held in the early part of September. For many years, it was an UK National Conference that had successfully brought academics and industrialists together to share their knowledge and experiences. Now the conference has developed as a major international event with a growing number of international delegates participating to exchange their research findings with UK researchers and practitioners. The next conference (ICMR2005) will be held at Cranfield University, a distinctive postgraduate university focusing on engineering, management and applied science