Calculation of mean and fluctuating properties of the incompressible turbulent boundary layer

Mathematical model for calculation of mean and fluctuating properties of incompressible turbulent boundary layer

Free radical 5-exo-dig cyclization as the key step in the synthesis of bis-butyrolactone natural products: experimental and theoretical studies

Radical cyclization reactions were performed by 5-exo-dig mode to yield cis-fused bicyclic systems, leading to the synthesis of bis-butyrolactone class of natural products. The study was aimed at understanding the impact of alkyl side chains of furanoside ring systems in L-ara configuration on the radical cyclization. It was amply demonstrated by experimental studies that the increase in the length of the alkyl side chain has an effect on the cyclization: while efficient cyclization reactions could be realized with methyl and ethyl side chains, the yields were significantly reduced in the case of n-pentyl side chain. Theoretical studies using DFT and (RO)MP2 methods were carried out to analyze the influence of the substitution pattern on the cyclization barriers

Turbulence In the Outer Regions of Protoplanetary Disks. II. Strong Accretion Driven by a Vertical Magnetic Field

We carry out a series of local, vertically stratified shearing box simulations of protoplanetary disks that include ambipolar diffusion and a net vertical magnetic field. The ambipolar diffusion profiles we employ correspond to 30AU and 100AU in a minimum mass solar nebula (MMSN) disk model, which consists of a far-UV-ionized surface layer and low-ionization disk interior. These simulations serve as a follow up to Simon et al. (2013), in which we found that without a net vertical field, the turbulent stresses that result from the magnetorotational instability (MRI) are too weak to account for observed accretion rates. The simulations in this work show a very strong dependence of the accretion stresses on the strength of the background vertical field; as the field strength increases, the stress amplitude increases. For gas to magnetic pressure ratios of 1e4 and 1e5, we find accretion rates between 1e-8 and 1e-7 solar masses per year. These accretion rates agree with observational constraints, suggesting a vertical magnetic field strength between 60 and 200 microgauss at 30AU and 10 and 30 microgauss at 100AU in a MMSN disk. Furthermore, the stress has a non-negligible component due to a magnetic wind. For sufficiently strong vertical field strengths, MRI turbulence is quenched, and the flow becomes largely laminar, with accretion proceeding through large scale correlations in the radial and toroidal field components as well as through the magnetic wind. In all simulations, the presence of a low ionization region near the disk mid-plane, which we call the ambipolar damping zone, results in reduced stresses there.Comment: accepted to ApJ after very minor revision

Free-stream noise and transition measurements on a cone in a Mach 3.5 pilot low-disturbance tunnel

A small scale Mach 3.5 wind tunnel incorporating certain novel design features and intended for boundary-layer-transition research has been tested. The free stream noise intensities and spectral distributions were determined throughout the test section for several values of unit Reynolds number and for nozzle boundary layer bleed on and off. The boundary layer transition location on a slender cone and the response of this to changes in the noise environment were determined. Root mean square free stream noise levels ranged from less than one tenth up to values approaching those for conventional nozzles, with the lowest values prevailing at upstream locations within the nozzle. For low noise conditions, cone transition Reynolds numbers were in the range of those for free flight; whereas for high noise conditions, they were in the range of those in conventional tunnels

Constraints on the Space Density of Methane Dwarfs and the Substellar Mass Function from a Deep Near-Infrared Survey

We report preliminary results of a deep near-infrared search for methane-absorbing brown dwarfs; almost five years after the discovery of Gl 229b, there are only a few confirmed examples of this type of object. New J band, wide-field images, combined with pre-existing R band observations, allow efficient identification of candidates by their extreme (R-J) colours. Follow-up measurements with custom filters can then confirm objects with methane absorption. To date, we have surveyed a total of 11.4 square degrees to J~20.5 and R~25. Follow-up CH_4 filter observations of promising candidates in 1/4 of these fields have turned up no methane absorbing brown dwarfs. With 90% confidence, this implies that the space density of objects similar to Gl 229b is less than 0.012 per cubic parsec. These calculations account for the vertical structure of the Galaxy, which can be important for sensitive measurements. Combining published theoretical atmospheric models with our observations sets an upper limit of alpha <= 0.8 for the exponent of the initial mass function power law in this domain.Comment: 11 pages + 2 figures To be published in Astrophysical Journal Letter

Computer program for compressible laminar or turbulent nonsimilar boundary layers

Description of computer program for solving two dimensional and axisymmetric forms of compressible boundary layer equations for continuity, mean momentum, and mean total enthalp

A Second Order Godunov Method for Multidimensional Relativistic Magnetohydrodynamics

We describe a new Godunov algorithm for relativistic magnetohydrodynamics (RMHD) that combines a simple, unsplit second order accurate integrator with the constrained transport (CT) method for enforcing the solenoidal constraint on the magnetic field. A variety of approximate Riemann solvers are implemented to compute the fluxes of the conserved variables. The methods are tested with a comprehensive suite of multidimensional problems. These tests have helped us develop a hierarchy of correction steps that are applied when the integration algorithm predicts unphysical states due to errors in the fluxes, or errors in the inversion between conserved and primitive variables. Although used exceedingly rarely, these corrections dramatically improve the stability of the algorithm. We present preliminary results from the application of these algorithms to two problems in RMHD: the propagation of supersonic magnetized jets, and the amplification of magnetic field by turbulence driven by the relativistic Kelvin-Helmholtz instability (KHI). Both of these applications reveal important differences between the results computed with Riemann solvers that adopt different approximations for the fluxes. For example, we show that use of Riemann solvers which include both contact and rotational discontinuities can increase the strength of the magnetic field within the cocoon by a factor of ten in simulations of RMHD jets, and can increase the spectral resolution of three-dimensional RMHD turbulence driven by the KHI by a factor of 2. This increase in accuracy far outweighs the associated increase in computational cost. Our RMHD scheme is publicly available as part of the Athena code.Comment: 75 pages, 28 figures, accepted for publication in ApJS. Version with high resolution figures available from http://jila.colorado.edu/~krb3u/Athena_SR/rmhd_method_paper.pd

Improved Si:As BIBIB (Back-Illuminated Blocked-Impurity-Band) hybrid arrays

Results of a program to increase the short wavelength (less than 10 microns) detective quantum efficiency, eta/beta, of Si:As Impurity Band Conduction arrays are presented. The arrays are epitaxially grown Back-Illuminated Blocked (BIB) Impurity-Band (BIBIB) 10x50 detectors bonded to switched-FET multiplexers. It is shown that the 4.7 microns detective quantum efficiency increases proportionately with the thickness of the infrared active layer. A BIB array with a thick active layer, designed for low dark current, exhibits eta/beta = 7 to 9 percent at 4.7 microns for applied bias voltages between 3 and 5 V. The product of quantum efficiency and photoelectric gain, etaG, increases from 0.3 to 2.5 as the voltage increases from 3 to 5 V. Over this voltage range, the dark current increases from 8 to 120 e(-)s(-1) at a device temperature of 4.2 K and is under 70 e(-)s(-1) for all voltages at 2 K. Because of device gain, the effective dark current (equivalent photon rate) is less than 3 e(-)s(-1) under all operating conditions. The effective read noise (equivalent photon noise) is found to be less than 12 electrons under all operating conditions and for integration times between 0.05 and 100 seconds

A short-term longitudinal study of correlates and sequelae of attachment security in autism

In this short-term longitudinal study, thirty preschool-aged children with autism were first observed in Ainsworth’s Strange Situation procedure and, separately, interacting with the primary caregiver in the home. One year later, each child completed both a developmental assessment and an observational assessment of empathic responding. Behaviors typical for children with autism were distinguished from behaviors suggestive of relationally based attachment disorganization. Forty five percent of the children were classified as securely attached. The secure group demonstrated language skills superior to those of the insecurely attached group, concurrently and during the follow-up. Compared to parents of children who were insecurely attached, parents of securely attached children were rated as more sensitive. Compared to both organized insecure and disorganized children, secure children were rated as more responsive to an examiner’s apparent distress during the follow-up relative to their ratings at intake, whereas empathy ratings of children with insecure classifications did not increase. Importantly, attachment security was associated with empathy above and beyond the contribution of children’s language level. These results indicate that the sequelae of attachment security in autism may be similar to those documented for typically developing children.This work was supported by the Eunice Kennedy Shriver National Institute of Child Health and Human Development and the National Institute on Deafness and Other Communication Disorders, as part of the Collaborative Programs of Excellence in Autism: [Program Project Grant Number HD-DCD35470] and Wellcome Trust: [Grant Number WT103343MA]