Up on the Housetop

According to William Studwell in The Christmas Carol Reader, Up on the House Top was the second-oldest secular Christmas song, outdone only by Jingle Bells , which was written in 1857 (although the latter was originally intended as a Thanksgiving song). It is also considered the first Yuletide song to focus primarily on Santa Claus. In fact, according to Readers Digest Merry Christmas Song Book, Hanby was the first to offer up the idea that Santa and his sleigh land on the roof of homes. Benjamin Russell Hanby was born in 1833 near Rushville, Ohio, the son of a minister involved with the Underground Railroad. During his short life, he wrote some 80 songs before dying of tuberculosis in 1867. Other than Up on the House Top his best-known song is Darling Nelly Gray . Performance in December 2014 by the a cappella student group Ottertuned. Their version commemorates the 150th anniversary of Benjamin Hanby\u27s composition. Members include Tim Andrews,Sammie Becker, Lane Conley, Benjamin Graber, Kristin Gramza, Michael Grimm, Allison Hunter, Katie Jump, Alyx Lynham, Austin Miller, Victoria Morin, Koryn Naylor, Kaitlin Steinour and Adam Sullivan.https://digitalcommons.otterbein.edu/hanby_scores/1000/thumbnail.jp

Ole Shady - The Song of the Contraband

The song \u27Ole Shady\u27 or the Song of the Contraband, composed by Benjamin Russel Hanby, was published in 1861. It is 6 pages long and measures 10 by 13.5 (25.4 by 34.29 cm). Composer Benjamin Russel.https://digitalcommons.otterbein.edu/hanby_scores/1001/thumbnail.jp

We\u27ll All Meet Again in the Morning - The Revellers\u27 Chorus

The occurrence which prompted this song actually occurred recently in a city of California. Some nineteen abandoned inebriates had been for days and nights together carousing in a fireman\u27s club house until delirium tremens ensued. As soon as reason began to return, one of them stung, with feeling of deep self reproach, declared his intention never to drink another drop, and urged his comrads to join him. His proposition was heartily agreed to, and a league was formed which from that day to the present has rapidly increased in its membership ‘till it now numbers several thousand staunch confederates.https://digitalcommons.otterbein.edu/hanby_scores/1002/thumbnail.jp

Magnetron sputtered thin films and composites for automotive and aerospace electrical insulation

Ceramics are highly prised as insulating materials because of their high stability under demanding conditions (thermal, chemical and radiological). However, the use of ceramics as wire insulation is currently limited to powder packed and relatively thick low voltage coatings. This work follows the development of sputtered Al2O3 and Al2O3, SiO2 and Ta2O5 composite films as deposited onto copper. Copper disk studies will ultimately be translated onto Cu wire for a proof of concept study. Initial Al2O3 deposition utilised RF or DC sputtering but this found to have low deposition rate (up to 16 nmh 1) and to contain crystallite and metallic defects (up to 19.6 at. % Al0) respectively. These issues were addressed by introducing pulsed DC (PDC) deposition conditions, producing films with no crystalline or metallic defects (up to 146 nmh 1). The dielectric strength of PDC films measured by AFM time dependant dielectric breakdown was 310 ± 21 Vμm 1, higher than that of the DC deposited films which had a dielectric strength of between 165 ± 19 and 221 ± 20 Vμm 1. A dielectric strength of 310 Vμm 1 is suitable for applications with a voltage rating below 150 V and is also a good platform for the production of higher quality coatings. The mechanical properties of the films did suffer from a lower amount of blending at the interface, DC pull off strength was 25.8 ± 9.8 - 72.3 ± 5.6 MPa with the PDC pull off strength being 55.7 ± 2.9 MPa). Wires coated with such PDC Al2O3 showed promise with full circumference coating, however, short circuiting was apparent in the wires potentially caused by micro cracking induced either during or post deposition. The use of multilayer composites consisting of the aforementioned PDC Al2O3 and RF SiO2 or RF Ta2O5 resulted in significant gains with respect to the material’s electrical properties. The films deposited with 2 layers of each PDC Al2O3 and the RF addition performed best in terms of dielectric strengths of 513 ± 18 and 466 ± 86 Vμm 1 for Ta2O5 and SiO2 composites respectively. The success of the 2x2 layer configuration resulted from a compromise between the number of RF layers and their thickness. The mechanical properties did, however, suffer as a result of increased intrinsic stress caused by the use of multilayers of materials with varying expansion coefficients, reducing pull off adhesion strength to a maximum of 34.4 ± 4.4 MPa, where ideally the pull off adhesion would be above 80 MPa. Heat treatment of these coatings resulted in decreased adhesive properties, with a maximum pull off adhesion strength of 20.1 ± 0.9 MPa being apparent. Most of the electrical properties remained the same or were decreased by heat treatment, however the dielectric strength of the SiO2 composites improved by an average of 12 % resulting in a maximum dielectric strength of 517 ± 24 Vμm 1 due to a reduction in the defect density in the films. Conversely the electrical properties of Ta2O5 composites suffered greatly following heat treatment with a maximum dielectric strength of 358 ± 31 Vμm 1. This was theorised to result from Cu migration from the substrate and the potential for Ta2O5 to crystallise at temperatures close to 500 °C. Coating of Cu wires with PDC alumina was shown to be possible, with coatings of various interlayer and coating thickness. Characterisation showed that the wire coating rig enabled the whole circumference of the wire to be coated with alumina. Tensile testing resulted in transvers cracking followed by longitudinal cracking above an applied strain of 1.5 and 4.0 % respectively. Following heat treatment the copper substrate softened and resulted in delamination failures in the coatings during tensile testing. Electrical testing of the wires was inconsistent due micro cracking in the wire coatings. It has been shown that the use of mixed material composites sputtered by PDC and RF sputtering have potential as high dielectric strength insulating materials, improving upon the base Al2O3 believed to be a result of passivation of structural and compositional defects. Additionally, it has been shown that physical vapour deposition in conjunction with a modified sample holder can be utilised for coating of bare copper wire with the potential to act as isolative coatings

Magnetron sputtered thin films and composites for automotive and aerospace electrical insulation

Ceramics are highly prised as insulating materials because of their high stability under demanding conditions (thermal, chemical and radiological). However, the use of ceramics as wire insulation is currently limited to powder packed and relatively thick low voltage coatings. This work follows the development of sputtered Al2O3 and Al2O3, SiO2 and Ta2O5 composite films as deposited onto copper. Copper disk studies will ultimately be translated onto Cu wire for a proof of concept study. Initial Al2O3 deposition utilised RF or DC sputtering but this found to have low deposition rate (up to 16 nmh 1) and to contain crystallite and metallic defects (up to 19.6 at. % Al0) respectively. These issues were addressed by introducing pulsed DC (PDC) deposition conditions, producing films with no crystalline or metallic defects (up to 146 nmh 1). The dielectric strength of PDC films measured by AFM time dependant dielectric breakdown was 310 ± 21 Vμm 1, higher than that of the DC deposited films which had a dielectric strength of between 165 ± 19 and 221 ± 20 Vμm 1. A dielectric strength of 310 Vμm 1 is suitable for applications with a voltage rating below 150 V and is also a good platform for the production of higher quality coatings. The mechanical properties of the films did suffer from a lower amount of blending at the interface, DC pull off strength was 25.8 ± 9.8 - 72.3 ± 5.6 MPa with the PDC pull off strength being 55.7 ± 2.9 MPa). Wires coated with such PDC Al2O3 showed promise with full circumference coating, however, short circuiting was apparent in the wires potentially caused by micro cracking induced either during or post deposition. The use of multilayer composites consisting of the aforementioned PDC Al2O3 and RF SiO2 or RF Ta2O5 resulted in significant gains with respect to the material’s electrical properties. The films deposited with 2 layers of each PDC Al2O3 and the RF addition performed best in terms of dielectric strengths of 513 ± 18 and 466 ± 86 Vμm 1 for Ta2O5 and SiO2 composites respectively. The success of the 2x2 layer configuration resulted from a compromise between the number of RF layers and their thickness. The mechanical properties did, however, suffer as a result of increased intrinsic stress caused by the use of multilayers of materials with varying expansion coefficients, reducing pull off adhesion strength to a maximum of 34.4 ± 4.4 MPa, where ideally the pull off adhesion would be above 80 MPa. Heat treatment of these coatings resulted in decreased adhesive properties, with a maximum pull off adhesion strength of 20.1 ± 0.9 MPa being apparent. Most of the electrical properties remained the same or were decreased by heat treatment, however the dielectric strength of the SiO2 composites improved by an average of 12 % resulting in a maximum dielectric strength of 517 ± 24 Vμm 1 due to a reduction in the defect density in the films. Conversely the electrical properties of Ta2O5 composites suffered greatly following heat treatment with a maximum dielectric strength of 358 ± 31 Vμm 1. This was theorised to result from Cu migration from the substrate and the potential for Ta2O5 to crystallise at temperatures close to 500 °C. Coating of Cu wires with PDC alumina was shown to be possible, with coatings of various interlayer and coating thickness. Characterisation showed that the wire coating rig enabled the whole circumference of the wire to be coated with alumina. Tensile testing resulted in transvers cracking followed by longitudinal cracking above an applied strain of 1.5 and 4.0 % respectively. Following heat treatment the copper substrate softened and resulted in delamination failures in the coatings during tensile testing. Electrical testing of the wires was inconsistent due micro cracking in the wire coatings. It has been shown that the use of mixed material composites sputtered by PDC and RF sputtering have potential as high dielectric strength insulating materials, improving upon the base Al2O3 believed to be a result of passivation of structural and compositional defects. Additionally, it has been shown that physical vapour deposition in conjunction with a modified sample holder can be utilised for coating of bare copper wire with the potential to act as isolative coatings

Darling Nelly Gray

1. There\u27s low green valley on the low Kentucky shore, There I\u27ve whiled many happy hours away, A sitting and a singing by the little cottage door Where lived my darling Nelly Gray. CHORUS: Oh! my poor Nelly Gray, they have taken you away And I\u27ll never see my darling any more, I\u27m sitting by the river and I\u27m weeping all the day, For you\u27ve gone from the old Kentucky shore. 2. When the moon had climb\u27d the mountain and the stars were shining too, Then I\u27d take my darling Nelly Gray, And we\u27d float down the river in my little red canoe, While my banjo sweetly I would play. 3. I went to see her but she\u27s gone! the neighbors say, The white man bound her with his chain, They have taken her to Georgia for to wear her life away, As she toils in the cotton and the cane. 4. My canoe is underwater and my banjo is unstrung, I\u27m tired of living any more, My eyes shall look downward and my songs shall be unsung While I stay on the old Kentucky shore. 5. My eyes are getting blinded and I cannot see my way, Hark! there\u27s somebody knocking at the door Oh! I hear the angels calling and I see my Nelly Gray Farewell to the old Kentucky shore. CHORUS: Oh! my darling Nelly Gray, up in heaven there they say, That they\u27ll never take you from me any more, I\u27m a coming coming coming, as the angels clear the way, Farewell to the old Kentucky shore

Layered Al2O3-SiO2 and Al2O3-Ta2O5 thin-film composites for high dielectric strength, deposited by pulsed direct current and radio frequency magnetron sputtering

Multilayer thin films have the potential to act as high dielectric strength insulation for wire and microelectronics. In this study, films consisting of 2, 4 or 8 layers, composed of Al2O3 with SiO2 or Ta2O5, were prepared via pulsed direct current and radio frequency magnetron sputtering to a thickness of between 152 and 236 nm. The dielectric strengths of all films exceeded the 310 Vμm−1 achieved for PDC Al2O3. Maximum dielectric strengths were obtained for four layer composites; Al2O3-SiO2-Al2O3-SiO2 (466 Vμm−1) and Al2O3-Ta2O5-Al2O3-Ta2O5 (513 Vμm−1), each containing two PDC-Al2O3 and two RF-SiO2/Ta2O5 layers. Whilst the average dielectric strength was higher in the Ta2O5 composites, they suffered from higher leakage prior to breakdown with ca. 6.5 nA compared to ca. 0.1 nA for SiO2 composites. The mechanical properties of the composites were poorer due to increased intrinsic coating stress. Samples exhibited complete interfacial delamination with maximum coating adhesion strengths of 22 and 25 MPa. The variance resulted from larger coefficient of thermal expansion for Ta2O5 compared to SiO2. Sputtered composites of Al2O3 and either SiO2 or Ta2O5 had high breakdown strength with reasonable adhesion and could be suitable for insulating copper conductors in the aerospace and automotive industries

Functional material features of Bombyx mori silk light versus heavy chain proteins

Bombyx mori (BM) silk fibroin is composed of two different subunits; heavy chain and light chain fibroin linked by a covalent disulphide bond. Current methods of separating the two silk fractions is complicated and produces inadequate quantities of the isolated components for the study of the individual light and heavy chain silks with respect to new materials. We report a simple method of separating silk fractions using formic acid. The formic acid treatment partially releases predominately the light chain fragment (soluble fraction) and then the soluble fraction and insoluble fractions can be converted into new materials. The regenerated original (total) silk fibroin and the separated fractions (soluble vs. insoluble) had different molecular weights and showed distinctive pH stabilities against aggregation/precipitation based on particle charging. All silk fractions could be electrospun to give fibre mats with viscosity of the regenerated fractions being the controlling factor for successful electrospinning. The silk fractions could be mixed to give blends with different proportions of the two fractions to modify the diameter and uniformity of the electrospun fibres formed. The soluble fraction containing the light chain was able to modify the viscosity by thinning the insoluble fraction containing heavy chain fragments, perhaps analogous to its role in natural fibre formation where the light chain provides increased mobility and the heavy chain producing shear thickening effects. The simplicity of this new separation method should enable access to these different silk protein fractions and accelerate the identification of methods, modifications and potential applications of these materials in biomedical and industrial applications

Dielectric breakdown of alumina thin films produced by pulsed direct current magnetron sputtering

Alumina films (~2 μm thick) were deposited with a mixed Cu/Al interlayer onto copper. Direct current (DC)/Pulsed DC (PDC) magnetron sputtering techniques were independently compared for reactive alumina sputtering. In DC sputtered films, elemental aluminium of 9.2 at.% and nano-crystallites were present within the x-ray amorphous matrix, resulting from target arcing. Defects lead to premature dielectric breakdown/increased current leakage. PDC sputtering improved film quality by removing crystallites, metallic clusters and through thickness cracking. Time dependent dielectric breakdown (TDDB) measurements were carried out using conductive atomic force microscopy identified an improvement in dielectric strength (166 to 310 V μm−1) when switching from DC to PDC deposition power. TDDB suggested that at high applied field the dominant pre-breakdown conduction mechanism was Fowler-Nordheim tunnelling in DC films. Tensile pull-off adhesion ranged from 56 to 72 MPa and was highest following incorporation of an Cu/Al blended interfacial layer. Scratch testing indicated various cracking/buckling failures