Ion-exchange synthesis and superconductivity at 8.6 K of Na2Cr3As3 with quasi-one-dimensional crystal structure

A new Cr-based quasi-one-dimensional superconductor Na2Cr3As3 was synthesized by an ion-exchange method in sodium naphthalenide solution. The crystals are thread-like and the structure was analyzed by X-ray diffraction with a noncentrosymmetric hexagonal space group P-6m2 (No. 187), in which the (Cr3As3)2- linear chains are separated by Na+ ions, and the refined lattice parameters are a = 9.239(2) {\AA} and c = 4.209(6) {\AA}. The measurements for electrical resistivity, magnetic susceptibility, and heat capacity reveal a superconducting transition with unconventional characteristic at the Tc of 8.6 K, which exceeds that of all previously reported Cr-based superconductors

Transition of stoichiometricSr2VO3FeAs to a superconducting state at 37.2 K

The superconductor Sr4V2O6Fe2As2 with transition temperature at 37.2 K has been fabricated. It has a layered structure with the space group of p4/nmm, and with the lattice constants a = 3.9296Aand c = 15.6732A. The observed large diamagnetization signal and zero-resistance demonstrated the bulk superconductivity. The broadening of resistive transition was measured under different magnetic fields leading to the discovery of a rather high upper critical field. The results also suggest a large vortex liquid region which reflects high anisotropy of the system. The Hall effect measurements revealed dominantly electron-like charge carriers in this material. The superconductivity in the present system may be induced by oxygen deficiency or the multiple valence states of vanadium.Comment: 5 pages, 4 figure