A furanoditerpenoid from the liverwort Jamesoniella autumnalis

A new furanoditerpenoid, jamesoniellide C, has been isolated from the liverwort Jamesoniella autumnalis. The structure of jamesoniellide C was established by spectroscopic methods, including X-ray analysis which also established its relative stereochemistry

A case study of a transported bromine explosion event in the Canadian high arctic

Ozone depletion events in the polar troposphere have been linked to extremely high concentrations of bromine, known as bromine explosion events (BEE). However, the optimum meteorological conditions for the occurrence of these events remain uncertain. On 4–5 April 2011, a combination of both blowing snow and a stable shallow boundary layer was observed during a BEE at Eureka, Canada (86.4°W, 80.1°N). Measurements made by a Multi-Axis Differential Optical Absorption Spectroscopy spectrometer were used to retrieve BrO profiles and partial columns. During this event, the near-surface BrO volume mixing ratio increased to ~20 parts per trillion by volume, while ozone was depleted to ~1 ppbv from the surface to 700 m. Back trajectories and Global Ozone Monitoring Experiment-2 satellite tropospheric BrO columns confirmed that this event originated from a bromine explosion over the Beaufort Sea. From 30 to 31 March, meteorological data showed high wind speeds (24 m/s) and elevated boundary layer heights (~800 m) over the Beaufort Sea. Long-distance transportation (~1800 km over 5 days) to Eureka indicated strong recycling of BrO within the bromine plume. This event was generally captured by a global chemistry-climate model when a sea-salt bromine source from blowing snow was included. A model sensitivity study indicated that the surface BrO at Eureka was controlled by both local photochemistry and boundary layer dynamics. Comparison of the model results with both ground-based and satellite measurements confirmed that the BEE observed at Eureka was triggered by transport of enhanced BrO from the Beaufort Sea followed by local production/recycling under stable atmospheric shallow boundary layer conditions

Aircraft-based observations and high-resolution simulations of an Icelandic dust storm

The first aircraft-based observations of an Icelandic dust storm are presented. The measurements were carried out over the ocean near Iceland's south coast in February 2007. This dust event occurred in conjunction with an easterly barrier jet of more than 30 m s<sup>−1</sup>. The aircraft measurements show high particle mass mixing ratios in an area of low wind speeds in the wake of Iceland near the coast, decreasing abruptly towards the jet. Simulations from the Weather Research and Forecasting Model coupled with Chemistry (WRF/Chem) indicate that the measured high mass mixing ratios and observed low visibility inside the wake are due to dust transported from Icelandic sand fields towards the ocean. This is confirmed by meteorological station data. Glacial outwash terrains located near the Mýrdalsjökull glacier are among simulated dust sources. Sea salt aerosols produced by the impact of strong winds on the ocean surface started to dominate as the aircraft flew away from Iceland into the jet. The present results support recent studies which suggest that Icelandic deserts should be considered as important dust sources in global and regional climate models