Carbide Type Influence on Tribological Properties of Hard Faced Steel Layer Part II- Experimental Results

In this paper is presented a preceding procedure that should be conducted in order to successfully regenerate damaged forging dies by the hard facing process. After the tool damage types identification, as well as their causes, we have chosen the procedure and the parameters of hard facing that we further corrected by conducting the test hard facings on models. Thus, we were able to relate the experimental results outputs with the repair technology, taking as a criterion the quality of the surface layers wear resistance such as friction coefficient and width of hard faced zone, hardness and its distribution in cross section, then microstructure of characteristic of hard faced zones, etc. This research points out significancy of tribological properties of certain types of carbides and their effects on metal matrix, in which carbides are embedded. Our tribological investigations have shown that the working life of the hard faced tool can be longer than that of the new tool

Electronic Structure of the Complex Hydride NaAlH4

Density functional calculations of the electronic structure of the complex hydride NaAlH4 and the reference systems NaH and AlH3 are reported. We find a substantially ionic electronic structure for NaAlH4, which emphasizes the importance of solid state effects in this material. The relaxed hydrogen positions in NaAlH4 are in good agreement with recent experiment. The electronic structure of AlH3 is also ionic. Implications for the binding of complex hydrides are discussed.Comment: 4 pages, 5 figure

Multi-phonon scattering and Ti-induced hydrogen dynamics in sodium alanate

We use ab initio methods and neutron inelastic scattering (NIS) to study the structure, energetics, and dynamics of pure and Ti-doped sodium alanate (NaAlH_4), focusing on the possibility of substitutional Ti doping. The NIS spectrum is found to exhibit surprisingly strong and sharp two-phonon features. The calculations reveal that substitutional Ti doping is energetically possible. Ti prefers to substitute for Na and is a powerful hydrogen attractor that facilitates multiple Al--H bond breaking. Our results hint at new ways of improving the hydrogen dynamics and storage capacity of the alanates.Comment: 5 pages, with 4 postscript figures embedded. Uses REVTEX4 and graphicx macro

Carbide Type Influence on Tribological Properties of Hard Faced Steel Layer - Part I - Theoretical Considerations

This paper gives a theoretical review of influence of the most important alloying elements on steel, and review of the most important carbide-forming elements and states the conditions which elements should fulfill in order to be considered as carbide-forming. It primarily involves alloying elements which in the iron-carbon system can form simple, complex or special carbides, i.e. phases of interstitial and substitutive type. It also gives a review of carbide types that are formed during either production or reparatory hard facing of steel parts with different types of filler materials

Discovery of superstrong, fading, iron line emission and double-peaked Balmer lines of the galaxy SDSSJ0952+2143 - the light echo of a huge flare

We report the discovery of superstrong, fading, high-ionization iron line emission in the galaxy SDSSJ095209.56+214313.3 (SDSSJ0952+2143 hereafter), which must have been caused by an X-ray outburst of large amplitude. SDSSJ0952+2143 is unique in its strong multiwavelength variability; such a broadband emission-line and continuum response has not been observed before. The strong iron line emission is accompanied by unusual Balmer line emission with a broad base, narrow core and double-peaked narrow horns, and strong HeII emission. These lines, while strong in the SDSS spectrum taken in 2005, have faded away significantly in new spectra taken in December 2007. Comparison of SDSS, 2MASS, GALEX and follow-up GROND photometry reveals variability in the NUV, optical and NIR band. Taken together, these unusual observations can be explained by a giant outburst in the EUV--X-ray band, detected even in the optical and NIR. The intense and variable iron, Helium and Balmer lines represent the ``light echo'' of the flare, as it traveled through circumnuclear material. The outburst may have been caused by the tidal disruption of a star by a supermassive black hole. Spectroscopic surveys such as SDSS are well suited to detect emission-line light echoes of such rare flare events. Reverberation-mapping of these light echoes can then be used as a new and efficient probe of the physical conditions in the circumnuclear material in non-active or active galaxies.Comment: ApJ Letters, 678, L13 (May 1 issue); incl. 4 colour figures. This and related papers on tidal disruption flares also available at http://www.xray.mpe.mpg.de/~skomossa

Synthesis, Structural, DFT, and Cytotoxicity Studies of CuII and NiII Complexes with 3-Aminopyrazole Derivatives

Template synthesis of N,N 0-bis(4-acetyl-5-methylpyrazole-3-yl)formamidine (ampf) was performed starting from 4-acetyl-3- amino-5-methylpyrazole (aamp) andCH(OC2H5)3 in methanol in the presence of CuCl2, Cu(NO3)2, orNi(NO3)2. The ligand was isolated in coordinated form as [Cu(ampf )Cl2], [Cu(ampf )(MeOH)(NO3)2]MeOH, and [Ni(ampf )(MeOH)2(NO3)]NO3 correspondingly. The compounds were characterized by elemental analysis, Fourier-transform IRand electronic spectroscopy, thermal analysis, single-crystal X-ray diffraction, and quantumchemical (density functional theory) calculations. The density functional theory calculations provided information on the metal�ligand interactions in the complexes and assisted the assignment of the FT-IR spectra. The antiproliferative activity of the complexes and the ligand precursor, aamp, was tested against human myelogenous leukaemia K562, colon adenocarcinoma HT29, and cervix carcinoma HeLa.JRC.E.3 - Materials researc

A tidal disruption-like X-ray flare from the quiescent galaxy SDSS J120136.02+300305.5

SDSS J120136.02+300305.5 was detected in an XMM-Newton slew from June 2010 with a flux 56 times higher than an upper limit from ROSAT, corresponding to Lx~3x10^44 ergs/s. It has the optical spectrum of a quiescent galaxy (z=0.146). Overall the X-ray flux has evolved consistently with the canonical t^-5/3 model, expected for returning stellar debris from a tidal disruption event, fading by a factor ~300 over 300 days. In detail the source is very variable and became invisible to Swift between 27 and 48 days after discovery, perhaps due to self-absorption. The X-ray spectrum is soft but is not the expected tail of optically thick thermal emission. It may be fit with a Bremsstrahlung or double-power-law model and is seen to soften with time and declining flux. Optical spectra taken 12 days and 11 months after discovery indicate a deficit of material in the broad line and coronal line regions of this galaxy, while a deep radio non-detection implies that a jet was not launched during this event.Comment: Accepted for publication in Astronomy and Astrophysics. 11 pages, 11 figure

Massive Black Hole Binary Inspirals: Results from the LISA Parameter Estimation Taskforce

The LISA Parameter Estimation (LISAPE) Taskforce was formed in September 2007 to provide the LISA Project with vetted codes, source distribution models, and results related to parameter estimation. The Taskforce's goal is to be able to quickly calculate the impact of any mission design changes on LISA's science capabilities, based on reasonable estimates of the distribution of astrophysical sources in the universe. This paper describes our Taskforce's work on massive black-hole binaries (MBHBs). Given present uncertainties in the formation history of MBHBs, we adopt four different population models, based on (i) whether the initial black-hole seeds are small or large, and (ii) whether accretion is efficient or inefficient at spinning up the holes. We compare four largely independent codes for calculating LISA's parameter-estimation capabilities. All codes are based on the Fisher-matrix approximation, but in the past they used somewhat different signal models, source parametrizations and noise curves. We show that once these differences are removed, the four codes give results in extremely close agreement with each other. Using a code that includes both spin precession and higher harmonics in the gravitational-wave signal, we carry out Monte Carlo simulations and determine the number of events that can be detected and accurately localized in our four population models.Comment: 14 pages, 2 figures, 5 tables, minor changes to match version to be published in the proceedings of the 7th LISA Symposium. For more information see the Taskforce's wiki at http://www.tapir.caltech.edu/dokuwiki/lisape:hom

Robertson Intelligent States

Diagonalization of uncertainty matrix and minimization of Robertson inequality for n observables are considered. It is proved that for even n this relation is minimized in states which are eigenstates of n/2 independent complex linear combinations of the observables. In case of canonical observables this eigenvalue condition is also necessary. Such minimizing states are called Robertson intelligent states (RIS). The group related coherent states (CS) with maximal symmetry (for semisimple Lie groups) are particular case of RIS for the quadratures of Weyl generators. Explicit constructions of RIS are considered for operators of su(1,1), su(2), h_N and sp(N,R) algebras. Unlike the group related CS, RIS can exhibit strong squeezing of group generators. Multimode squared amplitude squeezed states are naturally introduced as sp(N,R) RIS. It is shown that the uncertainty matrices for quadratures of q-deformed boson operators a_{q,j} (q > 0) and of any k power of a_j = a_{1,j} are positive definite and can be diagonalized by symplectic linear transformations. PACS numbers: 03.65.Fd, 42.50.DvComment: 23 pages, LaTex. Minor changes in text and references. Accepted in J. Phys.