Differences in Iron Removal from Carbon Nanoonions and Multiwall Carbon Nanotubes for Analytical Purpose

The paper describes the differences between wet iron removal from carbon nanoonions and from multiwall carbon nanotubes for analytical purpose. Nowadays, both carbon nanoonions and multiwall carbon nanotubes are one of the most interesting materials with applicability in electronics, medicine and biotechnology. Medical applications of those nanomaterials require not only recognition of their structure but also measurement of metal impurities concentration. Inductively coupled plasma optical emission spectrometry as a method for Fe-determination requires liquid samples. Hence, we propose various protocols for leaching of iron from studied materials. Our results proved that structure of nanomaterials have an impact on the efficiency of iron removal

Strong, Light, Multifunctional Fibers of Carbon Nanotubes with Ultrahigh Conductivity

Broader applications of carbon nanotubes to real-world problems have largely gone unfulfilled because of difficult material synthesis and laborious processing. We report high-performance multifunctional carbon nanotube (CNT) fibers that combine the specific strength, stiffness, and thermal conductivity of carbon fibers with the specific electrical conductivity of metals. These fibers consist of bulk-grown CNTs and are produced by high-throughput wet spinning, the same process used to produce high-performance industrial fibers. These scalable CNT fibers are positioned for high-value applications, such as aerospace electronics and field emission, and can evolve into engineered materials with broad long-term impact, from consumer electronics to long-range power transmission

DESKRIPSI KESALAHAN SISWA DALAM MENYELESAIKAN SOAL-SOAL HIDROLISIS GARAM DI KELAS XI IPA SMA KATOLIK TALINO

 AbstrackThe aims of this examination was to describe student errors when solving problem in salt hydrolysis in XI sains Class SMA Catholic Talino Sungai Ambawang and to explain cause of the errors. This examination is use description method with study case. The subject is student in XI sains class. Instrument to collect the data is question test and interview.  The question test is use essay test. The result of this examination is show us that student errors in esenstial concept (65,29%), errors in comprehend contact between concept (53,54%) and error in comprehend when using concept to solve problems (58,68%). The reason of that errors have two factors that is internal and eksternal factor.Keyword: Description, Errors, Salt Hydrolisis

The true amphipathic nature of graphene flakes: a versatile 2D stabilizer

The fundamental colloidal properties of pristine graphene flakes remain incompletely understood, with conflicting reports about their chemical character, hindering potential applications that could exploit the extraordinary electronic, thermal, and mechanical properties of graphene. Here, the true amphipathic nature of pristine graphene flakes is demonstrated through wet‐chemistry testing, optical microscopy, electron microscopy, and density functional theory, molecular dynamics, and Monte Carlo calculations, and it is shown how this fact paves the way for the formation of ultrastable water/oil emulsions. In contrast to commonly used graphene oxide flakes, pristine graphene flakes possess well‐defined hydrophobic and hydrophilic regions: the basal plane and edges, respectively, the interplay of which allows small flakes to be utilized as stabilizers with an amphipathic strength that depends on the edge‐to‐surface ratio. The interactions between flakes can be also controlled by varying the oil‐to‐water ratio. In addition, it is predicted that graphene flakes can be efficiently used as a new‐generation stabilizer that is active under high pressure, high temperature, and in saline solutions, greatly enhancing the efficiency and functionality of applications based on this materia

Differences in Iron Removal from Carbon Nanoonions and Multiwall Carbon Nanotubes for Analytical Purpose

The paper describes the differences between wet iron removal from carbon nanoonions and from multiwall carbon nanotubes for analytical purpose. Nowadays, both carbon nanoonions and multiwall carbon nanotubes are one of the most interesting materials with applicability in electronics, medicine and biotechnology. Medical applications of those nanomaterials require not only recognition of their structure but also measurement of metal impurities concentration. Inductively coupled plasma optical emission spectrometry as a method for Fe-determination requires liquid samples. Hence, we propose various protocols for leaching of iron from studied materials. Our results proved that structure of nanomaterials have an impact on the efficiency of iron removal

Towards the superlubricity of polymer-steel interfaces with ionic liquids and carbon nanotubes

Frictional losses are responsible for significant energy waste in many practical applications, and superlubricity with a coefficient of friction lower than 0.01 is the goal of tribologists. In this paper, metal-on-polymer contact was analysed and close to superlubricity conditions for this material configuration were explored. A new lubricant has been proposed hinge on the phosphorus-based ionic liquid and carbon nanotubes as thickeners. Additionally, carbon nanotube mesh was doped with copper nanoparticles that allowed for the close to superlubricity state in a mild steel/polymer contact configuration under low normal load conditions. The adsorption of phosphorus onto metallic and polymer surfaces has been reported in EDS analysis. The formulation of the new lubricant allowed for stable dispersion with a carbon nanotube content as low as 0.1% wt. The carbon nanotubes and Cu nanoparticles have been analysed using TEM and SEM imaging. A tribological test in a block-on-ring system has been carried out. The wear of material, topography, and surface free energy have been analysed along with SEM/EDS images to explore the underlying mechanisms of friction and wear.Comment: 18 page

Electrophoretic deposition of layer-by-layer unsheathed carbon nanotubes - A step towards steerable surface roughness and wettability

It is well known that carbon nanotube (CNT) oxidation (usually with concentrated HNO3) is a major step before the electrophoretic deposition (EPD). However, the recent discovery of the “onion effect” proves that multiwalled carbon nanotubes are not only oxidized, but a simultaneous unsheathing process occurs. We present the first report concerning the influence of unsheathing on the properties of the thus-formed CNT surface layer. In our study we examine how the process of gradual oxidation/unsheathing of a series of multiwalled carbon nanotubes (MWCNTs) influences the morphology of the surface formed via EPD. Taking a series of well-characterized and gradually oxidized/unsheathing Nanocyl™ MWCNTs and performing EPD on a carbon fiber surface, we analyzed the morphology and wettability of the CNT surfaces. Our results show that the water contact angle could be gradually changed in a wide range (125–163°) and the major property determining its value was the diameter of aggregates formed before the deposition process in the solvent. Based on the obtained results we determined the parameters having a crucial influence on the morphology of created layers. Our results shed new light on the deposition mechanism and enable the preparation of surfaces with steerable roughness and wettability

En route to controlled catalytic CVD synthesis of densely packed and vertically aligned nitrogen-doped carbon nanotube arrays

The catalytic chemical vapour deposition (c-CVD) technique was applied in the synthesis of vertically aligned arrays of nitrogen-doped carbon nanotubes (N-CNTs). A mixture of toluene (main carbon source), pyrazine (1,4-diazine, nitrogen source) and ferrocene (catalyst precursor) was used as the injection feedstock. To optimize conditions for growing the most dense and aligned N-CNT arrays, we investigated the influence of key parameters, i.e., growth temperature (660, 760 and 860 °C), composition of the feedstock and time of growth, on morphology and properties of N-CNTs. The presence of nitrogen species in the hot zone of the quartz reactor decreased the growth rate of N-CNTs down to about one twentieth compared to the growth rate of multi-wall CNTs (MWCNTs). As revealed by electron microscopy studies (SEM, TEM), the individual N-CNTs (half as thick as MWCNTs) grown under the optimal conditions were characterized by a superior straightness of the outer walls, which translated into a high alignment of dense nanotube arrays, i.e., 5 × 108 nanotubes per mm2 (100 times more than for MWCNTs grown in the absence of nitrogen precursor). In turn, the internal crystallographic order of the N-CNTs was found to be of a ‘bamboo’-like or ‘membrane’-like (multi-compartmental structure) morphology. The nitrogen content in the nanotube products, which ranged from 0.0 to 3.0 wt %, was controlled through the concentration of pyrazine in the feedstock. Moreover, as revealed by Raman/FT-IR spectroscopy, the incorporation of nitrogen atoms into the nanotube walls was found to be proportional to the number of deviations from the sp2-hybridisation of graphene C-atoms. As studied by XRD, the temperature and the [pyrazine]/[ferrocene] ratio in the feedstock affected the composition of the catalyst particles, and hence changed the growth mechanism of individual N-CNTs into a ‘mixed base-and-tip’ (primarily of the base-type) type as compared to the purely ‘base’-type for undoped MWCNTs

The operational window of carbon nanotube electrical wires treated with strong acids and oxidants

Conventional metal wires suffer from a significant degradation or complete failure in their electrical performance, when subjected to harsh oxidizing environments, however wires constructed from Carbon Nanotubes (CNTs) have been found to actually improve in their electrical performance when subjected to these environments. These opposing reactions may provide new and interesting applications for CNT wires. Yet, before attempting to move to any real-world harsh environment applications, for the CNT wires, it is essential that this area of their operation be thoroughly examined. To investigate this, CNT wires were treated with multiple combinations of the strongest acids and halogens. The wires were then subjected to conductivity measurements, current carrying capacity tests, as well as Raman, microscopy and thermogravimetric analysis to enable the identification of both the limits of oxidative conductivity boosting and the onset of physical damage to the wires. These experiments have led to two main conclusions. Firstly, that CNT wires may operate effectively in harsh oxidizing environments where metal wires would easily fail and secondly, that the highest conductivity increase of the CNT wires can be achieved through a process of annealing, acetone and HCl purification followed by either H2O2 and HClO4 or Br2 treatment

Bio-based nanofluids of extraordinary stability and enhanced thermal conductivity as sustainable green heat transfer media

Nanofluids (NFs) as a new generation of heat transfer media can be applied inter alia as engine coolants, in the microelectronic industry for the cooling of electronic components and systems, and in solar panels. In the present study, the extraordinarily, that is, more than 1 year, stable NFs composed of multi-walled carbon nanotubes (MWCNTs), biomass-derived 1,2- propanediol or 1,3-propanediol, and poly(N-vinylpyrrolidone) were created and studied. The thermal conductivity and density of NFs did not change over 8 months, and NFs did not sediment over 14 months. The real image of NFs determined using transmission electron cryo-microscopy allowed us to prove that the extraordinary stability and enhanced thermal conductivity were resulted by fully individualized MWCNTs in the continuous phase and MWCNTs stabilized in dispersions by shorter carbon nanoparticles and mostly homogenous poly(N-vinylpyrrolidone) coating. The maximum enhancement in thermal conductivity was 22 and 20% for NFs composed of 2 wt % MWCNTs in comparison with that of pure 1,2-propanediol and 1,3-propanediol, respectively. The improved thermal properties were accompanied by the practically Newtonian nature of all NFs. The cytotoxicity test on normal human dermal fibroblasts indicated that the use of diols diminished the toxicity of MWCNTs. Finally, the thermal conductivity and Prandtl number of bio-based NFsas compared with those of commercial heat transfer fluids DOWCAL 200 and DOWCAL Npredestine them as superb green heat transfer media in sustainable energy systems