Development of polymer network of phenolic and epoxies resins mixed with linseed oil: pilot study

Epoxy resin was mixed with phenolic resins in different percentages by weight. Composite 40/60 means the proportion by weight of epoxy resin is 40 percent. It was found that only composites 50/50 and 40/60 could be cured in ambient conditions. Dynamic mechanical analysis showed that only these two composites form interpenetrating polymer network. The addition of linseed oil to the two resins results also in the formation of interpenetrating network irrespective of proportion by weight of the resins; the mechanical properties will only be better when the percentage by weight of epoxy resin is higher; the aim of reducing cost and at the same time maintaining the mechanical properties cannot be fully achieved because epoxy resin is much more expensive than its counterpart

Pulsed THz radiation due to phonon-polariton effect in [110] ZnTe crystal

Pulsed terahertz (THz) radiation, generated through optical rectification (OR) by exciting [110] ZnTe crystal with ultrafast optical pulses, typically consists of only a few cycles of electromagnetic field oscillations with a duration about a couple of picoseconds. However, it is possible, under appropriate conditions, to generate a long damped oscillation tail (LDOT) following the main cycles. The LDOT can last tens of picoseconds and its Fourier transform shows a higher and narrower frequency peak than that of the main pulse. We have demonstrated that the generation of the LDOT depends on both the duration of the optical pulse and its central wavelength. Furthermore, we have also performed theoretical calculations based upon the OR effect coupled with the phonon-polariton mode of ZnTe and obtained theoretical THz waveforms in good agreement with our experimental observation.Comment: 9 pages, 5 figure

Anomalous physical properties of underdoped weak-ferromagnetic superconductor RuSr2_2EuCu2_{2}O8_{8}

Similar to the optimal-doped, weak-ferromagnetic (WFM induced by canted antiferromagnetism, T$_{Curie}$ = 131 K) and superconducting (T$_{c}$ = 56 K) RuSr$_{2}$GdCu$_{2}$O$_{8}$, the underdoped RuSr$_{2}$EuCu$_{2}$O$_{8}$ (T$_{Curie}$ = 133 K, T$_{c}$ = 36 K) also exhibited a spontaneous vortex state (SVS) between 16 K and 36 K. The low field ($\pm$20 G) superconducting hysteresis loop indicates a weak and narrow Meissner state region of average lower critical field B$_{c1}^{ave}$(T) = B$_{c1}^{ave}$(0)[1 - (T/T$_{SVS}$)$^{2}$], with B$_{c1}^{ave}$(0) = 7 G and T$_{SVS}$ = 16 K. The vortex melting transition (T$_{melting}$ = 21 K) below T$_{c}$ obtained from the broad resistivity drop and the onset of diamagnetic signal indicates a vortex liquid region due to the coexistence and interplay between superconductivity and WFM order. No visible jump in specific heat was observed near T$_{c}$ for Eu- and Gd-compound. This is not surprising, since the electronic specific heat is easily overshadowed by the large phonon and weak-ferromagnetic contributions. Furthermore, a broad resistivity transition due to low vortex melting temperature would also lead to a correspondingly reduced height of any specific heat jump. Finally, with the baseline from the nonmagnetic Eu-compound, specific heat data analysis confirms the magnetic entropy associated with antiferromagnetic ordering of Gd$^{3+}$ (J = S = 7/2) at 2.5 K to be close to $\it{N_{A}k}$ ln8 as expected.Comment: 7 figure

Dynamical Linear Response of TDDFT with LDA+U Functional: strongly hybridized Frenkel excitons in NiO

Within the framework of time-dependent density-functional theory (TDDFT), we derive the dynamical linear response of LDA+U functional and benchmark it on NiO, a prototypical Mott insulator. Formulated using real-space Wannier functions, our computationally inexpensive framework gives detailed insights into the formation of tightly bound Frenkel excitons with reasonable accuracy. Specifically, a strong hybridization of multiple excitons is found to significantly modify the exciton properties. Furthermore, our study exposes a significant generic limitation of adiabatic approximation in TDDFT with hybrid functionals and in existing Bethe-Salpeter-equation approaches, advocating the necessity of strongly energy-dependent kernels in future development.Comment: 5 pages, 2 figure