Inter- and Intra-Chain Attractions in Solutions of Flexible Polyelectrolytes at Nonzero Concentration

Constant temperature molecular dynamics simulations were used to study solutions of flexible polyelectrolyte chains at nonzero concentrations with explicit counterions and unscreened coulombic interactions. Counterion condensation, measured via the self-diffusion coefficient of the counterions, is found to increase with polymer concentration, but contrary to the prediction of Manning theory, the renormalized charge fraction on the chains decreases with increasing Bjerrum length without showing any saturation. Scaling analysis of the radius of gyration shows that the chains are extended at low polymer concentrations and small Bjerrum lengths, while at sufficiently large Bjerrum lengths, the chains shrink to produce compact structures with exponents smaller than a gaussian chain, suggesting the presence of attractive intrachain interactions. A careful study of the radial distribution function of the center-of-mass of the polyelectrolyte chains shows clear evidence that effective interchain attractive interactions also exist in solutions of flexible polyelectrolytes, similar to what has been found for rodlike polyelectrolytes. Our results suggest that the broad maximum observed in scattering experiments is due to clustering of chains.Comment: 12 pages, REVTeX, 15 eps figure

Higgs-Yukawa model on the lattice

We present results from two projects on lattice calculations for the Higgs-Yukawa model. First we report progress on the search of first-order thermal phase transitions in the presence of a dimension-six operator, with the choices of bare couplings that lead to viable phenomenological predictions. In this project the simulations are performed using overlap fermions to implement the required chiral symmetry. Secondly, our study for applying finite-size scaling techniques near the Gaussian fixed point of the Higgs-Yukawa model is presented. We discuss the analytical formulae for the Higgs Yukawa model and show results for a first numerical study in the pure $O(4)$ scalar sector of the theory.Comment: 8 pages, 4 figures; Contribution to the proceedings of the 35th International Symposium on Lattice Field Theory, 18 - 24 June 2017, Granada, Spai

Near-ionization-threshold emission in atomic gases driven by intense sub-cycle pulses

We study theoretically the dipole radiation of a hydrogen atom driven by an intense sub-cycle pulse. The time-dependent Schr\"odinger equation for the system is solved by ab initio calculation to obtain the dipole response. Remarkably, a narrowband emission lasting longer than the driving pulse appears at a frequency just above the ionization threshold. An additional calculation using the strong field approximation also recovers this emission, which suggests that it corresponds to the oscillation of nearly-bound electrons that behave similarly to Rydberg electrons. The predicted phenomenon is unique to ultrashort driving pulses but not specific to any particular atomic structure.Comment: 8 pages, 2 figure

Temperature dependence of instantons in QCD

We investigate the temperature dependence of the instanton contents of gluon fields, using unquenched lattice QCD and the cooling method. The instanton size parameter deduced from the correlation function decreases from 0.44fm below the phase-transition temperature $T_c$ ($\approx 150$MeV) to 0.33fm at 1.3 $T_c$. The instanton charge distribution is Poissonian above $T_c$, but it deviates from the convoluted Poisson at low temperature. The topological susceptibility decreases rapidly below $T_c$, showing the apparent restoration of the $U(1)_A$ symmetry already at $T \approx T_c$.Comment: 8 pages TEX, 3 Postscript figures available at http://www.krl.caltech.edu/preprints/MAP.htm

Enhanced Fermi surface nesting in superconducting BaFe2_2(As1−x_{1-x}Px_x)2_2 revealed by de Haas-van Alphen effect

The three-dimensional Fermi surface morphology of superconducting BaFe_2(As_0.37}P_0.63)_2 with T_c=9K, is determined using the de Haas-van Alphen effect (dHvA). The inner electron pocket has a similar area and k_z interplane warping to the observed hole pocket, revealing that the Fermi surfaces are geometrically well nested in the (\pi,\pi) direction. These results are in stark contrast to the Fermiology of the non-superconducting phosphides (x=1), and therefore suggests an important role for nesting in pnictide superconductivity.Comment: 5 pages, 4 figure

Water Content and Superconductivity in Na0.3CoO2*yH2O

We report here the correlation between the water content and superconductivity in Na0.3CoO2*yH2O under the influences of elevated temperature and cold compression. The x-ray diffraction of the sample annealed at elevated temperatures indicates that intergrowths exist in the compound at equilibrium when 0.6 < y < 1.4. Its low-temperature diamagnetization varies linearly with y, but is insensitive to the intergrowth, indicative of quasi-2D superconductivity. The Tc-onset, especially, shifts only slightly with y. Our data from cold compressed samples, on the other hand, show that the water-loss non-proportionally suppresses the diamagnetization, which is suggestive of weak links.Comment: 10 pages, 10 figures; submitted to Physica C (August 13, 2003