Shear Force Fiber Spinning: Process Parameter and Polymer Solution Property Considerations

For application of polymer nanofibers (e.g., sensors, and scaffolds to study cell behavior) it is important to control the spatial orientation of the fibers. We compare the ability to align and pattern fibers using shear force fiber spinning, i.e. contacting a drop of polymer solution with a rotating collector to mechanically draw a fiber, with electrospinning onto a rotating drum. Using polystyrene as a model system, we observe that the fiber spacing using shear force fiber spinning was more uniform than electrospinning with the rotating drum with relative standard deviations of 18% and 39%, respectively. Importantly, the approaches are complementary as the fiber spacing achieved using electrospinning with the rotating drum was ~10 microns while fiber spacing achieved using shear force fiber spinning was ~250 microns. To expand to additional polymer systems, we use polymer entanglement and capillary number. Solution properties that favor large capillary numbers (\u3e50) prevent droplet breakup to facilitate fiber formation. Draw-down ratio was useful for determining appropriate process conditions (flow rate, rotational speed of the collector) to achieve continuous formation of fibers. These rules of thumb for considering the polymer solution properties and process parameters are expected to expand use of this platform for creating hierarchical structures of multiple fiber layers for cell scaffolds and additional applications

Nucleation of quark matter in neutron stars cores

We consider the general conditions of quark droplets formation in high density neutron matter. The growth of the quark bubble (assumed to contain a sufficiently large number of particles) can be described by means of a Fokker-Planck equation. The dynamics of the nucleation essentially depends on the physical properties of the medium it takes place. The conditions for quark bubble formation are analyzed within the frameworks of both dissipative and non-dissipative (with zero bulk and shear viscosity coefficients) approaches. The conversion time of the neutron star to a quark star is obtained as a function of the equation of state of the neutron matter and of the microscopic parameters of the quark nuclei. As an application of the obtained formalism we analyze the first order phase transition from neutron matter to quark matter in rapidly rotating neutron stars cores, triggered by the gravitational energy released during the spinning down of the neutron star. The endothermic conversion process, via gravitational energy absorption, could take place, in a very short time interval, of the order of few tens seconds, in a class of dense compact objects, with very high magnetic fields, called magnetars.Comment: 31 pages, 2 figures, to appear in Ap

NbTiN superconducting nanowire detectors for visible and telecom wavelengths single photon counting on Si3N4 photonic circuits

We demonstrate niobium titanium nitride superconducting nanowires patterned on stoichiometric silicon nitride waveguides for detecting visible and infrared photons. The use of silicon nitride on insulator on silicon substrates allows us to simultaneously realize photonic circuits for visible and infrared light and integrate them with nanowire detectors directly on-chip. By implementing a traveling wave detector geometry in this material platform, we achieve efficient single photon detection for both wavelength regimes. Our detectors are an ideal match for integrated quantum optics as they provide crucial functionality on a wideband transparent waveguide material.Comment: 5 pages, 3 figure

Development of hot drawing process for nitinol tube

In recent years, Nitinol, near-equiatomic nickel-titanium alloys, have found growing applications in medical technology and joining technology, due to their special characteristics such as shape memory, superplasticity and biocompatibility. The production of Nitinol tube cost-effectively remains a technical challenge. In this paper, we describe a hot drawing process for Nitinol tube production. A Nitinol tube blank and a metal core are assembled together. The assembly is hot drawn for several passes to a final diameter. The metal core is then plastically stretched to reduce its diameter and removed from the tube. Hot drawing process has been applied to Ni50.7Ti and Ni47Ti44Nb9 alloys. Nitinol tubes of 13.6 mm outer diameter and 1 mm wall thickness have been successfully produced from a tube blank of 20 mm outer diameter and 3.5 mm thickness

Novel Precursors for Boron Nanotubes: The Competition of Two-Center and Three-Center Bonding in Boron Sheets

We present a new class of boron sheets, composed of triangular and hexagonal motifs, that are more stable than structures considered to date and thus are likely to be the precursors of boron nanotubes. We describe a simple and clear picture of electronic bonding in boron sheets and highlight the importance of three-center bonding and its competition with two-center bonding, which can also explain the stability of recently discovered boron fullerenes. Our findings call for reconsideration of the literature on boron sheets, nanotubes, and clusters.Comment: 4 pages, 4 figures, 1 tabl

Diving Deep into Sentiment: Understanding Fine-tuned CNNs for Visual Sentiment Prediction

Visual media are powerful means of expressing emotions and sentiments. The constant generation of new content in social networks highlights the need of automated visual sentiment analysis tools. While Convolutional Neural Networks (CNNs) have established a new state-of-the-art in several vision problems, their application to the task of sentiment analysis is mostly unexplored and there are few studies regarding how to design CNNs for this purpose. In this work, we study the suitability of fine-tuning a CNN for visual sentiment prediction as well as explore performance boosting techniques within this deep learning setting. Finally, we provide a deep-dive analysis into a benchmark, state-of-the-art network architecture to gain insight about how to design patterns for CNNs on the task of visual sentiment prediction.Comment: Preprint of the paper accepted at the 1st Workshop on Affect and Sentiment in Multimedia (ASM), in ACM MultiMedia 2015. Brisbane, Australi

Superconducting correlations in ultra-small metallic grains

To describe the crossover from the bulk BCS superconductivity to a fluctuation-dominated regime in ultrasmall metallic grains, new order parameters and correlation functions, such as ``parity gap'' and ``pair-mixing correlation function'', have been recently introduced. In this paper, we discuss the small-grain behaviour of the Penrose-Onsager-Yang off-diagonal long-range order (ODLRO) parameter in a pseudo-spin representation. Relations between the ODLRO parameter and those mentioned above are established through analytical and numerical calculations.Comment: 7 pages, 1 figur