27,804 research outputs found

    Parallel field magnetoresistance in topological insulator thin films

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    We report that the finite thickness of three-dimensional topological insulator (TI) thin films produces an observable magnetoresistance (MR) in phase coherent transport in parallel magnetic fields. The MR data of Bi2Se3 and (Bi,Sb)2Te3 thin films are compared with existing theoretical models of parallel field magnetotransport. We conclude that the TI thin films bring parallel field transport into a unique regime in which the coupling of surface states to bulk and to opposite surfaces is indispensable for understanding the observed MR. The {\beta} parameter extracted from parallel field MR can in principle provide a figure of merit for searching TI compounds with more insulating bulk than existing materials.Comment: 6 pages, 4 figure

    Low temperature reforming of biogas over K-, Mg- and Ce-promoted Ni/Al<sub>2</sub>O<sub>3</sub> catalysts for the production of hydrogen rich syngas: Understanding the plasma-catalytic synergy

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    Plasma-catalytic biogas reforming over Ni-X/Al2O3 catalyst (X = K, Mg and Ce) has been carried out in a coaxial dielectric barrier discharge (DBD) plasma reactor at 160 °C. Three different process modes: plasma-alone, catalysis-alone and plasma-catalysis have been investigated to get new insights into the synergistic effect resulted from the interaction of the plasma with the promoted Ni catalysts. Compared to the biogas reforming using either plasma-alone or catalysis-alone mode at the same temperature (160 °C), the combination of the plasma with the Ni-based catalysts exhibited a low temperature synergistic effect, as evidenced from the much higher reforming performance of the plasma-catalytic process compared to that of the sum of the individual processes (plasma-alone and catalysis-alone). The addition of promoters (K, Mg and Ce) into the Ni/Al2O3 catalyst enhanced the conversion of CH4, the yield of H2 and the energy efficiency of the plasma process. In this study, the behaviour of K, Mg and Ce promoters in the low temperature plasma-catalytic biogas reforming was clearly different from that in high temperature thermal catalytic process in terms of the conversion of CH4 and carbon deposition, which could be ascribed to the temperature-dependent character of the promotors. In the plasma-catalytic biogas reforming, the Ni-K/Al2O3 catalyst showed the best performance, enhancing the conversion of both CO2 and CH4, the yield of H2, CO and C2–C4 alkanes and the energy efficiency of the plasma process. The highest conversion of CO2 (22.8%) and CH4 (31.6%) was achieved by placing the K-promoted catalyst in the plasma reforming process. The Mg-promoted catalyst remarkably increased the H2/CO molar ratio in the gas products (up to 2.2) due to the decreased CO2 conversion. In addition, compared to the un-promoted Ni/Al2O3 catalyst, although the use of the promoted catalysts increased the carbon deposition on the surface of the spent catalysts by 22%–26%, the total amount of deposited carbon was still less than that reported in high temperature catalytic dry reforming processes. More than 80% of the increased carbonaceous species was in the form of reactive carbon species, which can be easily oxidized by CO2 and O atoms and maintain the stability of the catalysts during the reforming reaction.</p

    Superconducting properties of nanocrystalline MgB2_2 thin films made by an in situ annealing process

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    We have studied the structural and superconducting properties of MgB2_2 thin films made by pulsed laser deposition followed by in situ annealing. The cross-sectional transmission electron microscopy reveals a nanocrystalline mixture of textured MgO and MgB2_2 with very small grain sizes. A zero-resistance transition temperature (Tc0T_{c0}) of 34 K and a zero-field critical current density (JcJ_c) of 1.3×1061.3 \times 10^6 A/cm2^2 were obtained. The irreversibility field was \sim 8 T at low temperatures, although severe pinning instability was observed. These bulk-like superconducting properties show that the in situ deposition process can be a viable candidate for MgB2_2 Josephson junction technologies

    A new metric for rotating charged Gauss-Bonnet black holes in AdS spaces

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    This paper presents a new metric for slowly rotating charged Gauss-Bonnet black holes in higher dimensional anti-de Sitter spaces. Taking the angular momentum parameter aa up to second order, the slowly rotating charged black hole solutions are obtained by working directly in the action.Comment: 11 pages and accepted by Chin. Phys.

    Photodynamic inactivation of Candida albicans by hematoporphyrin monomethyl ether

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    AIM: To evaluate the capacity of hematoporphyrin monomethyl ether (HMME) in the presence of light to cause photodynamic inactivation (PDI) of Candida albicans. MATERIALS & METHODS: HMME photoactivity was evaluated against azole-susceptible and -resistant C. albicans. The mechanisms by which PDI of C. albicans occurred were also investigated. RESULTS: HMME-mediated PACT caused a dose-dependent inactivation of azole-susceptible and -resistant C. albicans. Incubation with 10 μM HMME and irradiation with 72 J cm(-2) light decreased the viability of C. albicans by 7 log10, induced damage of genomic DNA, led to loss of cellular proteins and damaged the cell wall, membrane and intracellular targets. CONCLUSION: Candida albicans can be effectively inactivated by HMME in the presence of light, and HMME-mediated PACT shows its potential as an antifungal treatment

    Formation of a Double Diamond Cubic Phase by Thermotropic Liquid Crystalline Self-Assembly of Bundled Bolaamphiphiles

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    A quaternary amphiphile with swallow-tail side groups displays a new bicontinuous thermotropic cubic phase with symmetry Pn3‾ m and formed by two interpenetrating networks where cylindrical segments are linked by H bonds at tetrahedral junctions. Each network segment contains two bundles, each containing 12 rod-like mesogens, lying along the segment axis. This assembly leads to the first thermotropic structure of the "double diamond" type. A quantitative geometric model is proposed to explain the occurrence of this rare phase

    Superconductivity in Ti-doped Iron-Arsenide Compound Sr4Cr0.8Ti1.2O6Fe2As2

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    Superconductivity was achieved in Ti-doped iron-arsenide compound Sr4Cr0.8Ti1.2O6Fe2As2 (abbreviated as Cr-FeAs-42622). The x-ray diffraction measurement shows that this material has a layered structure with the space group of \emph{P4/nmm}, and with the lattice constants a = b = 3.9003 A and c = 15.8376 A. Clear diamagnetic signals in ac susceptibility data and zero-resistance in resistivity data were detected at about 6 K, confirming the occurrence of bulk superconductivity. Meanwhile we observed a superconducting transition in the resistive data with the onset transition temperature at 29.2 K, which may be induced by the nonuniform distribution of the Cr/Ti content in the FeAs-42622 phase, or due to some other minority phase.Comment: 3 pages, 3 figure
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