Electron transport through rectifying self-assembled monolayer diodes on silicon: Fermi level pinning at the molecule-metal interface

We report the synthesis and characterization of molecular rectifying diodes on silicon using sequential grafting of self-assembled monolayers of alkyl chains bearing a pi group at their outer end (Si/sigma-pi/metal junctions). We investigate the structure-performance relationships of these molecular devices and we examine to what extent the nature of the pi end-group (change in the energy position of their molecular orbitals) drives the properties of these molecular diodes. For all the pi-groups investigated here, we observe rectification behavior. These results extend our preliminary work using phenyl and thiophene groups (S. Lenfant et al., Nano Letters 3, 741 (2003)).The experimental current-voltage curves are analyzed with a simple analytical model, from which we extract the energy position of the molecular orbital of the pi-group in resonance with the Fermi energy of the electrodes. We report the experimental studies of the band lineup in these silicon/alkyl-pi conjugated molecule/metal junctions. We conclude that Fermi level pinning at the pi-group/metal interface is mainly responsible for the observed absence of dependence of the rectification effect on the nature of the pi-groups, even though they were chosen to have significant variations in their electronic molecular orbitalsComment: To be published in J. Phys. Chem.

Polypyrrole-Fe2O3 nanohybrid materials for electrochemical storage

We report on the synthesis and electrochemical characterization of nanohybrid polypyrrole (PPy) (PPy/Fe2O3) materials for electrochemical storage applications. We have shown that the incorporation of nanoparticles inside the PPy notably increases the charge storage capability in comparison to the “pure” conducting polymer. Incorporation of large anions, i.e., paratoluenesulfonate, allows a further improvement in the capacity. These charge storage modifications have been attributed to the morphology of the composite in which the particle sizes and the specific surface area are modified with the incorporation of nanoparticles. High capacity and stability have been obtained in PC/NEt4BF4 (at 20 mV/s), i.e., 47 mAh/g, with only a 3% charge loss after one thousand cyles. The kinetics of charge–discharge is also improved by the hybrid nanocomposite morphology modifications, which increase the rate of insertion–expulsion of counter anions in the bulk of the film. A room temperature ionic liquid such as imidazolium trifluoromethanesulfonimide seems to be a promising electrolyte because it further increases the capacity up to 53 mAh/g with a high stability during charge–discharge processes

Centrality Behaviour of J/ψ\psi Production in Na50

The J/$\psi$ production in 158 A GeV Pb-Pb interactions is studied, in the dimuon decay channel, as a function of centrality, as measured with the electromagnetic or with the very forward calorimeters. After a first sharp variation at mid centrality, both patterns continue to fall down and exhibit a curvature change at high centrality values. This trend excludes any conventional hadronic model and is in agreement with a deconfined quark-gluon phase scenario. We report also preliminary results on the measured charged multiplicity, as given by a dedicated detector.Comment: 5 pages, 7 figures (in eps) talk given at XXXI International Symposium on Multiparticle Dynamics, Sep. 1-7, 2001, Datong China URL http://ismd31.ccnu.edu.cn

Accelerating the adoption of Industry 4.0 supporting technologies in manufacturing engineering courses

[EN] Universities are one of the fundamental actors to guarantee the dissemination of knowledge and the development of competences related to the Industry of the Future (IoF) or Industry 4.0. Computer Aided (CAX) and Product Lifecycle Management (PLM) technologies are key part in the IoF. With this aim, it was launch a project focused on Manufacturing and partially funded by La Fondation Dassault Systèmes. This communication presents a review on CAX-PLM training, four initiatives already in place in universities participating in the project, the project scope, the approach to integrate with the industrial context, the working method to consider different competence profiles and the development framework.The authors express their gratitude to the other project colleagues and to La Fondation Dassault Systèmes for its funding support.Ríos, J.; Mas, F.; Marcos, M.; Vila, C.; Ugarte, D.; Chevrot, T. (2017). Accelerating the adoption of Industry 4.0 supporting technologies in manufacturing engineering courses. MATERIALS SCIENCE FORUM. 903:100-111. https://doi.org/10.4028/www.scientific.net/MSF.903.100S10011190

Anomalous J/ψJ/\psi suppression in Pb-Pb interactions at 158 GeV per nucleon

The Drell-Yan and J/psi cross-sections measured in Pb-Pb collisions are compared with the values extrapolated from the results obtained in proton and light ion induced reactions. While the Drell-Yan production exhibits the normal expected behaviour, the yield of J/psi in Pb-Pb interactions is abnormally low, as it lies 9 standard deviations below the expected value. Moreover, the departure from the expected behaviour increases significantly from peripheral to central collisions. (C) 1997 Elsevier Science B.V

Charmonium production in Pb-Pb collisions

NA50The elaboration of specific media-planning is necessary to communicate with an opinion leader. Opinion leaders in 27 product categories are selected from a 10,000 sample of French representative consumers. Magazine is the favorite media of opinion leaders; the more important is the number of product categories in which a consumer is leaders, the greater the media consumption. Leaders do not systematically prefer the Internet, their preference appears to be category specific. However, a second study conducted among 600 brand website visitors shows that brand sites represent a major information source for the leaders

Scaling of charged particle multiplicity in Pb-Pb collisions at SPS energies

The charged particle multiplicity distribution $dN_{ch}/d\eta$ has been measured by the NA50 experiment in Pb--Pb collisions at the CERN SPS. Measurements were done at incident energies of 40 and 158 GeV per nucleon over a broad impact parameter range. The multiplicity distributions are studied as a function of centrality using the number of participating nucleons ($N_{part}$), or the number of binary nucleon--nucleon collisions ($N_{coll}$). Their values at midrapidity exhibit a power law scaling behaviour given by $N_{part}^{1.00}$ and $N_{coll}^{0.75}$ at 158 GeV. Compatible results are found for the scaling behaviour at 40 GeV. The width of the $dN_{ch}/d\eta$ distributions is larger at 158 than at 40 GeV/nucleon and decreases slightly with centrality at both energies. Our results are compared to similar studies performed by other experiments both at the CERN SPS and at RHIC.

Low mass dimuon production in proton and ion induced interactions at SPS

The low mass dimuon spectra collected in p-U collisions by the NA38 experiment significantly exceeds the total cross section expected from previous analysis, done by other experiments. The `excess' events have a harder \pt\ distribution than the muon pairs from $\eta$ and $\omega$ Dalitz decays, expected to dominate the mass window 0.4--0.65~GeV/$c^2$. We conjecture that the excess events might be due to \qqbar\ annihilations, negligible at low \pt\ but made visible by the \mt\ cut applied in the NA38 data. Taking this assumption to parametrise the p-U spectra, we proceed with the analysis of the S-Cu, S-U and Pb-Pb data, collected by the NA38 and NA50 experiments, where we find that the measured mass spectra does not seem to exceed the expected low mass `cocktail' by more than 20\,\%