Electronic structure of Fe and magnetism in the 3d/5d3d/5d double perovskites Ca2_2FeReO6_6 and Ba2_2FeReO6_6

The Fe electronic structure and magnetism in (i) monoclinic Ca$_2$FeReO$_6$ with a metal-insulator transition at $T_{MI} \sim 140$ K and (ii) quasi-cubic half-metallic Ba$_2$FeReO$_6$ ceramic double perovskites are probed by soft x-ray absorption spectroscopy (XAS) and magnetic circular dichroism (XMCD). These materials show distinct Fe $L_{2,3}$ XAS and XMCD spectra, which are primarily associated with their different average Fe oxidation states (close to Fe$^{3+}$ for Ca$_2$FeReO$_6$ and intermediate between Fe$^{2+}$ and Fe$^{3+}$ for Ba$_2$FeReO$_6$) despite being related by an isoelectronic (Ca$^{2+}$/Ba$^{2+}$) substitution. For Ca$_2$FeReO$_6$, the powder-averaged Fe spin moment along the field direction ($B = 5$ T), as probed by the XMCD experiment, is strongly reduced in comparison with the spontaneous Fe moment previously obtained by neutron diffraction, consistent with a scenario where the magnetic moments are constrained to remain within an easy plane. For $B=1$ T, the unsaturated XMCD signal is reduced below $T_{MI}$ consistent with a magnetic transition to an easy-axis state that further reduces the powder-averaged magnetization in the field direction. For Ba$_2$FeReO$_6$, the field-aligned Fe spins are larger than for Ca$_2$FeReO$_6$ ($B=5$ T) and the temperature dependence of the Fe magnetic moment is consistent with the magnetic ordering transition at $T_C^{Ba} = 305$ K. Our results illustrate the dramatic influence of the specific spin-orbital configuration of Re $5d$ electrons on the Fe $3d$ local magnetism of these Fe/Re double perovskites.Comment: 7 pages, 3 figure

On the Balance of Intercalation and Conversion Reactions in Battery Cathodes

We present a thermodynamic analysis of the driving forces for intercalation and conversion reactions in battery cathodes across a range of possible working ion, transition metal, and anion chemistries. Using this body of results, we analyze the importance of polymorph selection as well as chemical composition on the ability of a host cathode to support intercalation reactions. We find that the accessibility of high energy charged polymorphs in oxides generally leads to larger intercalation voltages favoring intercalation reactions, whereas sulfides and selenides tend to favor conversion reactions. Furthermore, we observe that Cr-containing cathodes favor intercalation more strongly than those with other transition metals. Finally, we conclude that two-electron reduction of transition metals (as is possible with the intercalation of a $2+$ ion) will favor conversion reactions in the compositions we studied

The Yoneda algebra of a graded Ore extension

Let A be a connected-graded algebra with trivial module k, and let B be a graded Ore extension of A. We relate the structure of the Yoneda algebra E(A) := Ext_A(k,k) to E(B). Cassidy and Shelton have shown that when A satisfies their K_2 property, B will also be K_2. We prove the converse of this result.Comment: 9 page

Magnetic properties of Hydrogenated Li and Co doped ZnO nanoparticles

The effect of hydrogenation on magnetic properties of Zn0.85Co0.05Li0.10O nanoparticles is presented. It was found that the sample hydrided at room temperature (RT) showed weak ferromagnetism (FM) while that hydrided at 400oC showed robust ferromagnetism at room temperature. In both cases reheating the sample at 400oC in air converts it back into paramagnetic state (P) completely. The characterization of samples by X-ray and electron diffraction (ED) showed that room temperature ferromagnetism observed in the samples hydrogenated at RT is intrinsic in nature whereas that observed in the samples hydrogenated at 400oC is partly due to the cobalt metal clusters.Comment: 10 pages, 3 figure

Holistic generational offsets: Fostering a primitive online abstraction for human vs. machine cognition

We propose a unified architecture for next generation cognitive, low cost, mobile internet. The end user platform is able to scale as per the application and network requirements. It takes computing out of the data center and into end user platform. Internet enables open standards, accessible computing and applications programmability on a commodity platform. The architecture is a super-set to present day infrastructure web computing. The Java virtual machine (JVM) derives from the stack architecture. Applications can be developed and deployed on a multitude of host platforms. O(1) O(N). Computing and the internet today are more accessible and available to the larger community. Machine learning has made extensive advances with the availability of modern computing. It is used widely in NLP, Computer Vision, Deep learning and AI. A prototype device for mobile could contain N compute and N MB of memory.Comment: 11 pages, extended architecture details, added references. arXiv admin note: text overlap with arXiv:1809.0779

An Efficient Method for Band Structure Calculations in 3D Photonic Crystals

A method for computing band structures for three-dimensional photonic crystals is described. The method combines a mixed finite element discretization on a uniform grid with a fast Fourier transform preconditioner and a preconditioned subspace iteration algorithm. Numerical examples illustrating the behavior of the method are presented

Angular Resolution of an EAS Array for Gamma Ray Astronomy at Energies Greater Than 5 x 10 (13) Ev

A 24 detector extensive air shower array is being operated at Ootacamund (2300 m altitude, 11.4 deg N latitude) in southern India for a study of arrival directions of showers of energies greater than 5 x 10 to the 13th power eV. Various configurations of the array of detectors have been used to estimate the accuracy in determination of arrival angle of showers with such an array. These studies show that it is possible to achieve an angular resolution of better than 2 deg with the Ooty array for search for point sources of Cosmic gamma rays at energies above 5 x 10 to the 13th power eV