Low-lying Lambda Baryons from the Lattice

In a lattice QCD calculation with two light dynamical Chirally Improved (CI) quarks we determine ground state and some excited state masses in all four Lambda baryon channels 1/2^\pm and 3/2^\pm. We perform an infinite volume extrapolation and confirm the widely discussed Lambda(1405). We also analyze the amount of octet-singlet mixing, which is helpful in comparing states with the quark model.Comment: 6 pages, 6 figures, accepted for publication in PR

QCD with Two Light Dynamical Chirally Improved Quarks: Baryons

We present a study of baryon ground states and low lying excitations of non-strange and strange baryons. The results are based on seven gauge field ensembles with two dynamical light Chirally Improved (CI) quarks corresponding to pion masses between 255 and 596 MeV and a strange valence quark with mass fixed by the Omega baryon. The lattice spacing varies between 0.1324 and 0.1398 fm. Given in lattice units, the bulk of our results are for size 16^3\times 32, for two ensembles with light pion masses (255 and 330 MeV) we also use 24^3\times 48 lattices and perform an infinite volume extrapolation. We derive energy levels for the spin 1/2 and 3/2 channels for both parities. In general, our results in the infinite volume limit compare well with experiment. We analyze the flavor symmetry content by identifying the singlet/octet/decuplet contributions of the resulting eigenstates. The ground states compositions agree with quark model expectations. In some cases the excited states, however, disagree and we discuss possible reasons.Comment: 22 pages, 27 figure

Excited light and strange hadrons from the lattice with two Chirally Improved quarks

Results for excited light and strange hadrons from the lattice with two flavors of Chirally Improved sea quarks are presented. We perform simulations at several values of the pion mass ranging from 250 to 600 MeV and extrapolate to the physical pion mass. The variational method is applied to extract excited energy levels but also to discuss the content of the states. Among others, we explore the flavor singlet/octet content of Lambda states. In general, our results agree well with experiment, in particular we confirm the Lambda(1405) and its dominant flavor singlet structure.Comment: Contribution to the XV International Conference on Hadron Spectroscopy "Hadron 2013", 4-8 November 2013, Nara, Japa

Minimal qubit tomography

We present, and analyze thoroughly, a highly symmetric and efficient scheme for the determination of a single-qubit state, such as the polarization properties of photons emitted by a single-photon source. In our scheme there are only four measured probabilities, just enough for the determination of the three parameters that specify the qubit state, whereas the standard procedure would measure six probabilities.Comment: 14 pages, 10 figures; final versio

The multiferroic phase of DyFeO3_{3}:an ab--initio study

By performing accurate ab-initio density functional theory calculations, we study the role of $4f$ electrons in stabilizing the magnetic-field-induced ferroelectric state of DyFeO$_{3}$. We confirm that the ferroelectric polarization is driven by an exchange-strictive mechanism, working between adjacent spin-polarized Fe and Dy layers, as suggested by Y. Tokunaga [Phys. Rev. Lett, \textbf{101}, 097205 (2008)]. A careful electronic structure analysis suggests that coupling between Dy and Fe spin sublattices is mediated by Dy-$d$ and O-$2p$ hybridization. Our results are robust with respect to the different computational schemes used for $d$ and $f$ localized states, such as the DFT+$U$ method, the Heyd-Scuseria-Ernzerhof (HSE) hybrid functional and the GW approach. Our findings indicate that the interaction between the $f$ and $d$ sublattice might be used to tailor ferroelectric and magnetic properties of multiferroic compounds.Comment: 6 pages, 4 figures-Revised versio

QCD with two light dynamical chirally improved quarks: Mesons

We present results for the spectrum of light and strange mesons on configurations with two flavors of mass-degenerate Chirally Improved sea quarks. The calculations are performed on seven ensembles of lattice size 16^3x32 at three different gauge couplings and with pion masses ranging from 250 to 600 MeV. To reliably extract excited states, we use the variational method with an interpolator basis containing both gaussian and derivative quark sources. Both conventional and exotic channels up to spin 2 are considered. Strange quarks are treated within the partially quenched approximation. For kaons we investigate the mixing of interpolating fields corresponding to definite C-parity in the SU(3) limit. This enlarged basis allows for an improved determination of the low-lying kaon spectrum. In addition to masses we also extract the ratio of the pseudoscalar decay constants of the kaon and pion and obtain F_K/F_\pi=1.215(41). The results presented here include some ensembles from previous publications and the corresponding results supersede the previously published values.Comment: 18 pages, 16 figures, table referencing correcte

Heterogeneous Pd catalysts as emulsifiers in Pickering emulsions for integrated multistep synthesis in flow chemistry

Within the “Compartmentalised Smart Factory” approach of the ONE-FLOW project the implementation of different catalysts in “compartments” provided by Pickering emulsions and their application in continuous flow is targeted. We present here the development of heterogeneous Pd-catalysts that are ready to be used in combination with biocatalysts for catalytic cascade syntheses of active pharmaceutical ingredients (APIs). In particular, we focus on the application of the catalytic systems for Suzuki-Miyaura cross coupling reactions, which is the key step in the syntheses of the targeted APIs valsartan and sacubitril. An immobilised enzyme will accomplish the final product formation via hydrolysis. In order to create large interfacial area for the catalytic reactions and to keep the reagents separated until required, the catalyst particles are used to stabilise Pickering emulsions of oil and water. A set of Ce-Sn-Pd-oxides with the molecular formula Ce0.99-xSnxPd0.01O2-(x= 0-0.99) has been prepared utilising a simple single-step solution combustion method. The high applicability of the catalysts for different functional groups and their minimal leaching behaviour is demonstrated with various Suzuki-Miyaura cross coupling reactions in batch as well as in continuous flow employing the so-called “Plug & Play reactor”. Finally, we demonstrate the use of these particles as the sole emulsifier of oil + water emulsions for a range of oils