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Quantum–classical correspondence in spin–boson equilibrium states at arbitrary coupling

The equilibrium properties of nanoscale systems can deviate significantly from standard thermodynamics due to their coupling to an environment. We investigate this here for the θ-angled spin–boson model, where we first derive a compact and general form of the classical equilibrium state including environmental corrections to all orders. Secondly, for the quantum spin–boson model we prove, by carefully taking a large spin limit, that Bohr’s quantum–classical correspondence persists at all coupling strengths. This shows, for the first time, the validity of the quantum–classical correspondence for an open system and gives insight into the regimes where the quantum system is well-approximated by a classical one. Finally, we provide the first classification of the coupling parameter regimes for the spin–boson model, from weak to ultrastrong, both for the quantum case and the classical setting. Our results shed light on the interplay of quantum and mean force corrections in equilibrium states of the spin–boson model, and will help draw the quantum to classical boundary in a range of fields, such as magnetism and exciton dynamics

Optimal finite-time heat engines under constrained control

This is the final version. Available on open access from the American Physical Society via the DOI in this recordWe optimize finite-time stochastic heat engines with a periodically scaled Hamiltonian under experimentally motivated constraints on the bath temperature T and the scaling parameter λ. We present a general geometric proof that maximum-efficiency protocols for T and λ are piecewise constant, alternating between the maximum and minimum allowed values. When λ is restricted to a small range and the system is close to equilibrium at the ends of the isotherms, a similar argument shows that this protocol also maximizes output power. These results are valid for arbitrary dynamics. We illustrate them for an overdamped Brownian heat engine, which can experimentally be realized using optical tweezers with stiffness λ.China Scholarship CouncilFundational Questions InstituteCaixa FoundationGovernment of SpainFundacio CellexFundacio Mir-PuigGeneralitat de Catalunya (CERCA)Engineering and Physical Sciences Research Council (EPSRC)Royal SocietySwiss National Science FoundationHumboldt foundationCzech Science Foundatio

Thermodynamics and optimal protocols of multidimensional quadratic Brownian systems

This is the final version. Available on open access from IOP Publishing via the DOI in this recordData availability statement; All data that support the findings of this study are included within the article (and any supplementary files).We characterize finite-time thermodynamic processes of multidimensional quadratic overdamped systems. Analytic expressions are provided for heat, work, and dissipation for any evolution of the system covariance matrix. The Bures-Wasserstein metric between covariance matrices naturally emerges as the local quantifier of dissipation. General principles of how to apply these geometric tools to identify optimal protocols are discussed. Focusing on the relevant slow-driving limit, we show how these results can be used to analyze cases in which the experimental control over the system is partial.Humboldt FoundationCzech Science Foundation'la Caixa' FoundationGovernment of SpainSevero OchoaFundacio CellexFundacio Mir-PuigGeneralitat de CatalunyaFundational Questions Institute FundEngineering and Physical Sciences Research Council (EPSRC)China Scholarship CouncilSwiss National Science Foundatio

Stability of long-sustained oscillations induced by electron tunneling

Self-oscillations are the result of an efficient mechanism generating periodic motion from a constant power source. In quantum devices, these oscillations may arise due to the interaction between single electron dynamics and mechanical motion. Due to the complexity of this mechanism, these self-oscillations may irrupt, vanish, or exhibit a bistable behavior causing hysteresis cycles. We observe these hysteresis cycles and characterize the stability of different regimes in single and double quantum dot configurations. In particular cases, we find these oscillations stable for over 20 seconds, many orders of magnitude above electronic and mechanical characteristic timescales, revealing the robustness of the mechanism at play. The experimental results are reproduced by our theoretical model that provides a complete understanding of bistability in nanoelectromechanical devices.Comment: 11 pages, 10 figures, includes the complete paper and the Supplemental Materia

Large-scale unit commitment under uncertainty: an updated literature survey

The Unit Commitment problem in energy management aims at finding the optimal production schedule of a set of generation units, while meeting various system-wide constraints. It has always been a large-scale, non-convex, difficult problem, especially in view of the fact that, due to operational requirements, it has to be solved in an unreasonably small time for its size. Recently, growing renewable energy shares have strongly increased the level of uncertainty in the system, making the (ideal) Unit Commitment model a large-scale, non-convex and uncertain (stochastic, robust, chance-constrained) program. We provide a survey of the literature on methods for the Uncertain Unit Commitment problem, in all its variants. We start with a review of the main contributions on solution methods for the deterministic versions of the problem, focussing on those based on mathematical programming techniques that are more relevant for the uncertain versions of the problem. We then present and categorize the approaches to the latter, while providing entry points to the relevant literature on optimization under uncertainty. This is an updated version of the paper "Large-scale Unit Commitment under uncertainty: a literature survey" that appeared in 4OR 13(2), 115--171 (2015); this version has over 170 more citations, most of which appeared in the last three years, proving how fast the literature on uncertain Unit Commitment evolves, and therefore the interest in this subject