Relationships of trace gases and aerosols and the emission characteristics at Lin'an, a rural site in eastern China, during spring 2001

We present measurements of trace gases and fine aerosols obtained from a rural site in eastern China during 18 February to 30 April 2001. The field program aimed to characterize the variations in aerosol and gaseous pollutant concentrations and the emission signatures from the inland region of eastern China in the spring season. The data included O3, CO, NO, NOy*, SO2, methane, C2-C8 nonmethane hydrocarbons (NMHCs), C 1-C2 halocarbons, and the chemical composition of PM2.5. The average hourly mixing ratios (±standard deviation) of CO, SO2, and NOy* were 677 (±315) ppbv, 15.9 (±14.6) ppbv, and 13.8 (±7.2) ppbv, respectively. The mean daytime ozone mixing ratio was 41 (± 19) ppbv. The most abundant NMHC was ethane (3189 ± 717 pptv), followed by ethyne (2475 ± 1395 pptv), ethene (1679 ± 1455 pptv), and toluene (1529 ± 1608 pptv). Methyl chloride was the most abundant halocarbon (1108 ± 653 pptv). The average concentrations of particulate organic matter (POM, as organic carbon, OC, times 1.4) and elemental carbon (EC) in PM2.5 were 21.5 (±7) μg/m3 and 2.5 (±0.7) μg/m3, respectively, and sulfate and nitrate levels were 17.3 (±6.6) and 6.5 (±4) μg/m3, respectively. CO showed moderate to good correlation with NOy* (r2 = 0.59), OC (r2 = 0.65), CH3Cl (r2 = 0.59), soluble potassium (r2 = 0.53), and many NMHCs, indicating contributions from the burning of biofuel/biomass. CO also correlated with an industrial tracer, C2Cl4, indicative of some influence from industrial sources. SO2, on the other hand, correlated well with EC (r2 = 0.56), reflecting the contribution from the burning of coal. Ammonium was sufficiently abundant to fully neutralize sulfate and nitrate, indicating that there were strong emissions of ammonia from agricultural activities. Silicon and calcium had poor correlations with iron and aluminum, revealing the presence of source(s) for Si and Ca other than from soil. Examination of C2H2/CO, C3H8/C 2H6, nitrate/(nitrate + NOy* , and sulfate/(SO2 + sulfate) suggested that relatively fresh air masses had been sampled at the study site in the spring season. Comparison of the observed ratios/slopes with those derived from emission inventories showed that while the observed SO2/NO y* ratio (1.29 ppbv/ppbv) in March was comparable (within 20%) to the inventory-derived ratio for the study region, the measured CO/NOy* slope (37 ppbv/ppbv) was about 200% larger. The observed slope of CO relative to NMHC (including ethane, propane, butanes, ethene, and ethyne) also indicated the presence of excess CO, compared to the ratios from the inventories. These results strongly suggest that emissions of CO in eastern China have been underrepresented. The findings of this study highlight the importance of characterizing trace gases and aerosols within source regions of the Asian continent. The springtime results were also compared with data previously collected at the site in 1999-2000 and with those obtained on the Transport and Chemical Evolution over the Pacific (TRACE-P) aircraft and from a coastal site in South China for the same study period. Copyright 2004 by the American Geophysical Union

Quantum Lightning Never Strikes the Same State Twice

Public key quantum money can be seen as a version of the quantum no-cloning theorem that holds even when the quantum states can be verified by the adversary. In this work, investigate quantum lightning, a formalization of "collision-free quantum money" defined by Lutomirski et al. [ICS'10], where no-cloning holds even when the adversary herself generates the quantum state to be cloned. We then study quantum money and quantum lightning, showing the following results: - We demonstrate the usefulness of quantum lightning by showing several potential applications, such as generating random strings with a proof of entropy, to completely decentralized cryptocurrency without a block-chain, where transactions is instant and local. - We give win-win results for quantum money/lightning, showing that either signatures/hash functions/commitment schemes meet very strong recently proposed notions of security, or they yield quantum money or lightning. - We construct quantum lightning under the assumed multi-collision resistance of random degree-2 systems of polynomials. - We show that instantiating the quantum money scheme of Aaronson and Christiano [STOC'12] with indistinguishability obfuscation that is secure against quantum computers yields a secure quantum money schem

Interrelation between the pseudogap and the incoherent quasi-particle features of high-Tc superconductors

Using a scenario of a hybridized mixture of localized bipolarons and conduction electrons, we demonstrate for the latter the simultaneous appearance of a pseudogap and of strong incoherent contributions to their quasi-particle spectrum which arise from phonon shake-off effects. This can be traced back to temporarily fluctuating local lattice deformations, giving rise to a double-peak structure in the pair distribution function, which should be a key feature in testing the origin of these incoherent contributions, recently seen in angle-resolved photoemission spectroscopy (ARPES).Comment: 4 pages, 3 figures, to be published in Phys. Rev. Let

Metal-insulator crossover in the Boson-Fermion model in infinite dimensions

The Boson-Fermion model, describing a mixture of tightly bound electron pairs and quasi-free electrons hybridized with each other via a charge exchange term, is studied in the limit of infinite dimensions, using the Non-Crossing Approximation within the Dynamical Mean Field Theory. It is shown that a metal-insulator crossover, driven by strong pair fluctuations, takes place as the temperature is lowered. It manifests itself in the opening of a pseudogap in the electron density of states, accompanied by a corresponding effect in the optical and dc conductivity.Comment: 4 pages, 3 figures, to be published in Phys. Rev. Let

Graph Adaptive Knowledge Transfer for Unsupervised Domain Adaptation

Unsupervised domain adaptation has caught appealing attentions as it facilitates the unlabeled target learning by borrowing existing well-established source domain knowledge. Recent practice on domain adaptation manages to extract effective features by incorporating the pseudo labels for the target domain to better solve cross-domain distribution divergences. However, existing approaches separate target label optimization and domain-invariant feature learning as different steps. To address that issue, we develop a novel Graph Adaptive Knowledge Transfer (GAKT) model to jointly optimize target labels and domain-free features in a unified framework. Specifically, semi-supervised knowledge adaptation and label propagation on target data are coupled to benefit each other, and hence the marginal and conditional disparities across different domains will be better alleviated. Experimental evaluation on two cross-domain visual datasets demonstrates the effectiveness of our designed approach on facilitating the unlabeled target task learning, compared to the state-of-the-art domain adaptation approaches

Phenomenology of Photoemission Lineshapes of High Tc Superconductors

We introduce a simple phenomenological form for the self-energy which allows us to extract important information from angle resolved photoemission data on the high Tc superconductor Bi2212. First, we find a rapid suppression of the single particle scattering rate below Tc for all doping levels. Second, we find that in the overdoped materials the gap Delta at all k-points on the Fermi surface has significant temperature dependence and vanishes near Tc. In contrast, in the underdoped samples such behavior is found only at k-points close to the diagonal. Near (pi,0), Delta is essentially T-independent in the underdoped samples. The filling-in of the pseudogap with increasing T is described by a broadening proportional to T-Tc, which is naturally explained by pairing correlations above Tc.Comment: 4 pages, revtex, 3 encapsulated postscript figure

Collective Modes and the Superconducting State Spectral Function of Bi2212

Photoemission spectra of the high temperature superconductor Bi2212 near (pi,0) show a dramatic change when cooling below Tc: the broad peak in the normal state turns into a sharp low energy peak followed by a higher binding energy hump. Recent experiments find that this low energy peak persists over a significant range in momentum space. We show in this paper that these data are well described by a simple model of electrons interacting with a collective mode which appears only below Tc.Comment: 4 pages, revtex, 4 encapsulated postscript figure

Pseudogap in 1d revisited

Two decades ago, Sadovskii found an exact solution of a model describing a pseudogap in electron energy spectrum (first introduced by Lee, Rice and Anderson). The discovery of a pseudogap in high-Tc superconductors has revived the interest to his exact solution. I review the model with the emphasis on physical content, point out an error in the original Sadovskii's solution and explain which problem he actually solved. A recent incorporation of Sadovskii's ideas into a description of "hot spots" on the Fermi surface in cuprate superconductors (Schmalian, Pines and Stojkovic) is briefly discussed.Comment: Final version to appear in PR

Induced local spin-singlet amplitude and pseudogap in high TcT_{c} cuprates

In this paper we show that local spin-singlet amplitude with d-wave symmetry, , can be induced by short-range spin correlations even in the absence of pairing interactions. Fluctuation theory is formulated to make connection between pseudogap temperature $T^{*}$, pseudogap size $\Delta_{pg}$ and . In the present scenario for the pseudogap, the normal state pseudogap is caused by the induced local spin-singlet amplitude due to short-range spin correlations, which compete in the low energy sector with superconducting correlations to make $T_{c}$ go to zero near half-filling. Calculated $T^{*}$ falls from a high value onto the $T_{c}$ line and closely follows mean-field N\'{e}el temperature $T_{N}^{MF}$. The calculated $\Delta_{pg}$ is in good agreement with experimental results. We propose an experiment in which the present scenario can be critically tested.Comment: 5 pages, 3 figure

Bosonic Mode Mixing in the Superconducting State Spectral Function of Bi_2Sr_2CaCu_2O_{8+delta}

Photoemission spectra of Bi_2Sr_2CaCu_2O_{8+delta} below T_c show two features near the (pi,0) point of the zone: a sharp peak at low energy and a higher binding energy hump. We find that the sharp peak persists at low energy even as one moves towards (0,0), while the broad hump shows significant dispersion which correlates well with the normal state dispersion. We argue that these features are naturally explained by the mixing of electrons with a bosonic mode which appears only below T_c, and speculate that the latter may be related to the resonance seen in recent neutron data.Comment: 4 pages, revtex, 4 postscript figure