Terrestrial exposure of a fresh Martian meteorite causes rapid changes in hydrogen isotopes and water concentrations

Determining the hydrogen isotopic compositions and H2O contents of meteorites and their components is important for addressing key cosmochemical questions about the abundance and source(s) of water in planetary bodies. However, deconvolving the effects of terrestrial contamination from the indigenous hydrogen isotopic compositions of these extraterrestrial materials is not trivial, because chondrites and some achondrites show only small deviations from terrestrial values such that even minor contamination can mask the indigenous values. Here we assess the effects of terrestrial weathering and contamination on the hydrogen isotope ratios and H2O contents of meteoritic minerals through monitored terrestrial weathering of Tissint, a recent Martian fall. Our findings reveal the rapidity with which this weathering affects nominally anhydrous phases in extraterrestrial materials, which illustrates the necessity of sampling the interiors of even relatively fresh meteorite falls and underlines the importance of sample return missions

Characterising the CI and CI-like carbonaceous chondrites using thermogravimetric analysis and infrared spectroscopy

The CI and CI-like chondrites provide a record of aqueous alteration in the early solar system. However, the CI-like chondrites differ in having also experienced a late stage period of thermal metamorphism. In order to constrain the nature and extent of the aqueous and thermal alteration, we have investigated the bulk mineralogy and abundance of H2O in the CI and CI-like chondrites using thermogravimetric analysis and infrared spectroscopy. The CI chondrites Ivuna and Orgueil show significant mass loss (28.5–31.8 wt.%) upon heating to 1000 °C due to dehydration and dehydroxylation of abundant phyllosilicates and Fe-(oxy)hydroxides and the decomposition of Fe-sulphides, carbonates and organics. Infrared spectra for Ivuna and Orgueil have a prominent 3-μm feature due to bound −OH/H2O in phyllosilicates and Fe-(oxy)hydroxides and only a minor 11-μm feature from anhydrous silicates. These characteristics are consistent with previous studies indicating that the CI chondrites underwent near-complete aqueous alteration. Similarities in the total abundance of H2O and 3 μm/11 μm ratio suggest that there is no difference in the relative degree of hydration experienced by Ivuna and Orgueil. In contrast, the CI-like chondrites Y-82162 and Y-980115 show lower mass loss (13.8–18.8 wt.%) and contain >50 % less H2O than the CI chondrites. The 3-μm feature is almost absent from spectra of Y-82162 and Y-980115 but the 11-μm feature is intense. The CI-like chondrites experienced thermal metamorphism at temperatures >500 °C that initially caused dehydration and dehydroxylation of phyllosilicates before partial recrystallization back into anhydrous silicates. The surfaces of many C-type asteroids were probably heated through impact metamorphism and/or solar radiation, so thermally altered carbonaceous chondrites are likely good analogues for samples that will be returned by the Hayabusa-2 and OSIRIS-REx missions

Reactive ammonia in the solar protoplanetary disk and the origin of Earth’s nitrogen

Terrestrial nitrogen isotopic compositions are distinct from solar and cometary values and similar to those of primitive meteorites, suggesting that Earth's atmospheric nitrogen originates from a primordial cosmochemical source(1,2). Prebiotic organic compounds containing nitrogen that formed in the solar protoplanetary disk, such as amino acids, may have contributed to the emergence of life on Earth(3,4). However, the original reservoirs of these volatile compounds and the processes involved in their distribution and chemical modification before accretion remain unclear. Here we report the occurrence of the mineral carlsbergite (chromium nitride) within nanocrystalline sulphide inclusions of primitive chondritic meteorites using transmission electron microscopy and secondary ion mass spectrometry. The characteristics and occurrence of carlsbergite are consistent with precipitation from a chromium-bearing metal in the presence of reactive ammonia. The carlsbergite crystals have nitrogen isotopic compositions that differ from ammonia in cometary ices, but are similar to Earth's atmospheric nitrogen. We suggest that the reactive ammonia proposed to have initiated formation of the carlsbergite came from ices within regions of the protoplanetary disk that were affected by the distal wakes of shock waves. Our findings imply that these primordial ammonia-bearing ices were a nitrogen reservoir within the formation region of the chondritic meteorite parent bodies and could have been a source of volatiles for the early Earth

Macromolecular organic compounds from the depths of Enceladus

Abstract Saturn’s moon Enceladus harbours a global water ocean¹, which lies under an ice crust and above a rocky core². Through warm cracks in the crust³ a cryo-volcanic plume ejects ice grains and vapour into space⁴–⁷ that contain materials originating from the ocean⁸,⁹. Hydrothermal activity is suspected to occur deep inside the porous core¹⁰–¹², powered by tidal dissipation¹³. So far, only simple organic compounds with molecular masses mostly below 50 atomic mass units have been observed in plume material⁶,¹⁴,¹⁵. Here we report observations of emitted ice grains containing concentrated and complex macromolecular organic material with molecular masses above 200 atomic mass units. The data constrain the macromolecular structure of organics detected in the ice grains and suggest the presence of a thin organic-rich film on top of the oceanic water table, where organic nucleation cores generated by the bursting of bubbles allow the probing of Enceladus’ organic inventory in enhanced concentrations