First measurements of 15N fractionation in N2H+ toward high-mass star forming cores

We report on the first measurements of the isotopic ratio 14N/15N in N2H+ toward a statistically significant sample of high-mass star forming cores. The sources belong to the three main evolutionary categories of the high-mass star formation process: high-mass starless cores, high-mass protostellar objects, and ultracompact HII regions. Simultaneous measurements of 14N/15N in CN have been made. The 14N/15N ratios derived from N2H+ show a large spread (from ~180 up to ~1300), while those derived from CN are in between the value measured in the terrestrial atmosphere (~270) and that of the proto-Solar nebula (~440) for the large majority of the sources within the errors. However, this different spread might be due to the fact that the sources detected in the N2H+ isotopologues are more than those detected in the CN ones. The 14N/15N ratio does not change significantly with the source evolutionary stage, which indicates that time seems to be irrelevant for the fractionation of nitrogen. We also find a possible anticorrelation between the 14N/15N (as derived from N2H+) and the H/D isotopic ratios. This suggests that 15N enrichment could not be linked to the parameters that cause D enrichment, in agreement with the prediction by recent chemical models. These models, however, are not able to reproduce the observed large spread in 14N/15N, pointing out that some important routes of nitrogen fractionation could be still missing in the models.Comment: 2 Figures, accepted for publication in ApJ

H_2D^+ in the High-mass Star-forming Region Cygnus X

H_2D^+ is a primary ion that dominates the gas-phase chemistry of cold dense gas. Therefore, it is hailed as a unique tool in probing the earliest, prestellar phase of star formation. Observationally, its abundance and distribution is, however, just beginning to be understood in low-mass prestellar and cluster-forming cores. In high-mass star-forming regions, H_2D^+ has been detected only in two cores, and its spatial distribution remains unknown. Here, we present the first map of the ortho-H_2D^+J_(k^+,k^-) = 1_(1,0) → 1_(1,1) and N_2H^+ 4-3 transition in the DR21 filament of Cygnus X with the James Clerk Maxwell Telescope, and N_2D^+ 3-2 and dust continuum with the Submillimeter Array. We have discovered five very extended (≤34, 000 AU diameter) weak structures in H2D+ in the vicinity of, but distinctly offset from, embedded protostars. More surprisingly, the H_2D^+ peak is not associated with either a dust continuum or N_2D^+ peak. We have therefore uncovered extended massive cold dense gas that was undetected with previous molecular line and dust continuum surveys of the region. This work also shows that our picture of the structure of cores is too simplistic for cluster-forming cores and needs to be refined: neither dust continuum with existing capabilities nor emission in tracers like N_2D^+ can provide a complete census of the total prestellar gas in such regions. Sensitive H_2D^+ mapping of the entire DR21 filament is likely to discover more of such cold quiescent gas reservoirs in an otherwise active high-mass star-forming region

The Deuterium Fractionation Timescale in Dense Cloud Cores: A Parameter Space Exploration

The deuterium fraction [N$_2$D$^+$]/[N$_2$H$^+$], may provide information about the ages of dense, cold gas structures, important to compare with dynamical models of cloud core formation and evolution. Here we introduce a complete chemical network with species containing up to three atoms, with the exception of the Oxygen chemistry, where reactions involving H$_3$O$^+$ and its deuterated forms have been added, significantly improving the consistency with comprehensive chemical networks. Deuterium chemistry and spin states of H$_2$ and H$_3^+$ isotopologues are included in this primarily gas-phase chemical model. We investigate dependence of deuterium chemistry on model parameters: density ($n_{\rm H}$), temperature, cosmic ray ionization rate, and gas-phase depletion factor of heavy elements ($f_{\rm D}$). We also explore the effects of time-dependent freeze-out of gas-phase species and dynamical evolution of density at various rates relative to free-fall collapse. For a broad range of model parameters, the timescales to reach large values of $D_{\rm frac}^{\rm N_2H^+} \gtrsim 0.1$, observed in some low- and high-mass starless cores, are relatively long compared to the local free-fall timescale. These conclusions are unaffected by introducing time-dependent freeze-out and considering models with evolving density, unless the initial $f_{\rm D} \gtrsim$ 10. For fiducial model parameters, achieving $D_{\rm frac}^{\rm N_2H^+} \gtrsim 0.1$ requires collapse to be proceeding at rates at least several times slower than that of free-fall collapse, perhaps indicating a dynamically important role for magnetic fields in the support of starless cores and thus the regulation of star formation.Comment: 23 pages, 18 figures, accepted by Ap

Structure, Dynamics and Deuterium Fractionation of Massive Pre-Stellar Cores

High levels of deuterium fraction in N$_2$H$^+$ are observed in some pre-stellar cores. Single-zone chemical models find that the timescale required to reach observed values ($D_{\rm frac}^{{\rm N}_2{\rm H}^+} \equiv {\rm N}_2{\rm D}^+/{\rm N}_2{\rm H}^+ \gtrsim 0.1$) is longer than the free-fall time, possibly ten times longer. Here, we explore the deuteration of turbulent, magnetized cores with 3D magnetohydrodynamics simulations. We use an approximate chemical model to follow the growth in abundances of N$_2$H$^+$ and N$_2$D$^+$. We then examine the dynamics of the core using each tracer for comparison to observations. We find that the velocity dispersion of the core as traced by N$_2$D$^+$ appears slightly sub-virial compared to predictions of the Turbulent Core Model of McKee & Tan, except at late times just before the onset of protostar formation. By varying the initial mass surface density, the magnetic energy, the chemical age, and the ortho-to-para ratio of H$_2$, we also determine the physical and temporal properties required for high deuteration. We find that low initial ortho-to-para ratios ($\lesssim 0.01$) and/or multiple free-fall times ($\gtrsim 3$) of prior chemical evolution are necessary to reach the observed values of deuterium fraction in pre-stellar cores.Comment: 20 pages, 18 figures; accepted for publication in Ap

The dynamical properties of dense filaments in the infrared dark cloud G035.39-00.33

Infrared Dark Clouds (IRDCs) are unique laboratories to study the initial conditions of high-mass star and star cluster formation. We present high-sensitivity and high-angular resolution IRAM PdBI observations of N2H+ (1-0) towards IRDC G035.39-00.33. It is found that G035.39-00.33 is a highly complex environment, consisting of several mildly supersonic filaments (sigma_NT/c_s ~1.5), separated in velocity by <1 km s^-1 . Where multiple spectral components are evident, moment analysis overestimates the non-thermal contribution to the line-width by a factor ~2. Large-scale velocity gradients evident in previous single-dish maps may be explained by the presence of substructure now evident in the interferometric maps. Whilst global velocity gradients are small (<0.7 km s^-1 pc^-1), there is evidence for dynamic processes on local scales (~1.5-2.5 km s^-1 pc^-1 ). Systematic trends in velocity gradient are observed towards several continuum peaks. This suggests that the kinematics are influenced by dense (and in some cases, starless) cores. These trends are interpreted as either infalling material, with accretion rates ~(7 \pm 4)x10^-5 M_sun yr^-1 , or expanding shells with momentum ~24 \pm 12 M_sun km s^-1 . These observations highlight the importance of high-sensitivity and high-spectral resolution data in disentangling the complex kinematic and physical structure of massive star forming regions.Comment: 25 pages, 23 figures, accepted for publication in MNRA

The importance of thinking styles in predicting binge eating

Impulsivity, Body Mass Index, negative emotions and irrational food beliefs are often reported as predictors of binge eating. In the current study we explored the role played by two thinking styles, namely food thought suppression and desire thinking, in predicting binge eating among young adults controlling for established predictors of this condition. A total of 338 university students (268 females) participated in this study by completing a battery of questionnaires measuring the study variables. Path analysis revealed that impulsivity was not associated with binge eating, that Body Mass Index and negative emotions predicted binge eating, and that irrational food beliefs only influenced binge eating via food thought suppression and desire thinking. In conclusion, thinking styles appear an important predictor of binge eating and they should be taken into consideration when developing clinical interventions for binge eating

Chemical evolution in the environment of intermediate mass young stellar objects: NGC7129--FIRS2 and LkHα\alpha234

We have carried out a molecular survey of the Class 0 IM protostar NGC 7129 -- FIRS 2 (hereafter FIRS 2) and the Herbig Be star LkH$\alpha$ 234 with the aim of studying the chemical evolution of the envelopes of intermediate-mass (IM) young stellar objects (YSOs). Both objects have similar luminosities (~500 Lsun) and are located in the same molecular cloud which minimizes the chemical differences due to different stellar masses or initial cloud conditions. Moreover, since they are located at the same distance, we have the same spatial resolution in both objects. A total of 17 molecular species (including rarer isotopes) have been observed in both objects and the structure of their envelopes and outflows is determined with unprecedent detail. Our results show that the protostellar envelopes are dispersed and warmed up during the evolution to become a pre-main sequence star. In fact, the envelope mass decreases by a factor >5 from FIRS 2 to LkH$\alpha$234, while the kinetic temperature increases from ~13K to 28K. On the other hand, there is no molecular outflow associated with LkH$\alpha$234. The molecular outflow seems to stop before the star becomes visible. These physical changes strongly affect the chemistry of their envelopes. Based on our results in FIRS2 and LkH$\alpha$ 234, we propose some abundance ratios that can be used as chemical clocks for the envelopes of IM YSOs. The SiO/CS, CN/N2H+, HCN/N2H+, DCO+/HCO+ and D2CO/DCO+ ratios are good diagnostics of the protostellar evolutionary stage.Comment: 24 pages, 17 figure

HSCO+^+ and DSCO+^+: a multi-technique approach in the laboratory for the spectroscopy of interstellar ions

Protonated molecular species have been proven to be abundant in the interstellar gas. This class of molecules is also pivotal for the determination of important physical parameters for the ISM evolution (e.g. gas ionisation fraction) or as tracers of non-polar, hence not directly observable, species. The identification of these molecular species through radioastronomical observations is directly linked to a precise laboratory spectral characterisation. The goal of the present work is to extend the laboratory measurements of the pure rotational spectrum of the ground electronic state of protonated carbonyl sulfide (HSCO$^+$) and its deuterium substituted isotopomer (DSCO$^+$). At the same time, we show how implementing different laboratory techniques allows the determination of different spectroscopical properties of asymmetric-top protonated species. Three different high-resolution experiments were involved to detected for the first time the $b-$type rotational spectrum of HSCO$^+$, and to extend, well into the sub-millimeter region, the $a-$type spectrum of the same molecular species and DSCO$^+$. The electronic ground-state of both ions have been investigated in the 273-405 GHz frequency range, allowing the detection of 60 and 50 new rotational transitions for HSCO$^+$ and DSCO$^+$, respectively. The combination of our new measurements with the three rotational transitions previously observed in the microwave region permits the rest frequencies of the astronomically most relevant transitions to be predicted to better than 100 kHz for both HSCO$^+$ and DSCO$^+$ up to 500 GHz, equivalent to better than 60 m/s in terms of equivalent radial velocity. The present work illustrates the importance of using different laboratory techniques to spectroscopically characterise a protonated species at high frequency, and how a similar approach can be adopted when dealing with reactive species.Comment: 7 pages, 4 figures. Accepted for publication in Astronomy and Astrophysic

Rotational spectroscopy of the HCCO and DCCO radicals in the millimeter and submillimeter range

The ketenyl radical, HCCO, has recently been detected in the ISM for the first time. Further astronomical detections of HCCO will help us understand its gas-grain chemistry, and subsequently revise the oxygen-bearing chemistry towards dark clouds. Moreover, its deuterated counterpart, DCCO, has never been observed in the ISM. HCCO and DCCO still lack a broad spectroscopic investigation, although they exhibit a significant astrophysical relevance. In this work we aim to measure the pure rotational spectra of the ground state of HCCO and DCCO in the millimeter and submillimeter region, considerably extending the frequency range covered by previous studies. The spectral acquisition was performed using a frequency-modulation absorption spectrometer between 170 and 650 GHz. The radicals were produced in a low-density plasma generated from a select mixture of gaseous precursors. For each isotopologue we were able to detect and assign more than 100 rotational lines. The new lines have significantly enhanced the previous data set allowing the determination of highly precise rotational and centrifugal distortion parameters. In our analysis we have taken into account the interaction between the ground electronic state and a low-lying excited state (Renner-Teller pair) which enables the prediction and assignment of rotational transitions with $K_a$ up to 4. The present set of spectroscopic parameters provides highly accurate, millimeter and submillimeter rest-frequencies of HCCO and DCCO for future astronomical observations. We also show that towards the pre-stellar core L1544, ketenyl peaks in the region where $c$-$\mathrm{C_3H_2}$ peaks, suggesting that HCCO follows a predominant hydrocarbon chemistry, as already proposed by recent gas-grain chemical models