Oscillatory and propagating modes of temperature variability at the 3–3.5- and 4–4.5-yr time scales in the Upper Southwest Pacific Ocean

This paper investigates oscillatory and propagating patterns of normalized surface and subsurface temperature anomalies (from the seasonal cycle) in the southwest Pacific Ocean using an extended empirical orthogonal function (EEOF) analysis. The temperature data (and errors) are from the Digital Atlas of Southwest Pacific upper Ocean Temperatures (DASPOT). These data are 3 monthly in time (January, April, July, and October), 2° X 2° in space, and 5 m in the vertical to 450-m depths. The temperature anomalies in the EEOF analysis are normalized by the objective mapping temperature errors at each grid point. They are also Butterworth filtered in the 3–7-yr band to examine interannual variations in the temperature field. The oscillating and propagating patterns of the modes are examined across four vertical levels: the surface, and 100-, 250-, and 450-m depths. The dominant mode EEOF (70% of the total variance of the filtered data) oscillates in a 4–4.5-yr quasi-periodic manner that is consistent with El Niño–Southern Oscillation (ENSO). Anomalies peak first at the surface in the subtropics between New Caledonia and Fiji (centered around 17°S, 177°E), then 6 months later in the tropical far west centered around the Solomon Islands (5°S, 153°–157°E), with a maximum at the base of the mixed layer (100 m) and upper thermocline (250 m), and then eastward in the northeast of the southwest Pacific region (0°–10°S, 160°E–180°). Mode 2 (25% variance of the filtered data) has a periodicity of 3–3.5 yr, with centers of action in all four vertical levels. The mode-2 patterns are consistent with variations in the subtropical gyre circulation, including the East Australian Current and its separation, and are continuous with the Tasman Front. Two spatial dipoles are apparent: (i) one in sea surface temperature (SST) at about 5°S, straddling west–east either side of the Solomon Islands, consistent with the classic Pacific-wide ENSO SST anomaly mode, and (ii) a subsurface dipole pattern, with centers in the Solomon Islands region at 100- and 250-m depths, and the western Tasman Sea (27°–33°S, 157°–161°E) at 250- and 450-m depths, consistent with dynamic changes in the gyre intensity

Improving hydrogen yields, and hydrogen: Steam ratio in the chemical looping production of hydrogen using Ca<inf>2</inf>Fe<inf>2</inf>O<inf>5</inf>

A thermodynamic property of Ca2Fe2O5 was exploited to improve the efficiency of the steam-iron process to produce hydrogen. The ability of reduced Ca2Fe2O5 to convert a higher fraction of steam to hydrogen than chemically unmodified Fe was demonstrated in a packed bed. At 1123 K, the use of Ca2Fe2O5 achieved an equilibrium conversion of steam to hydrogen of 75%, in agreement with predicted thermodynamics and substantially higher than that theoretically achievable by iron oxide, viz. 62%. Furthermore, in Ca2Fe2O5, the full oxidation from Fe(0) to Fe(III) can be utilised for hydrogen production – an improvement from the Fe to Fe3O4 transition for unmodified iron. Thermodynamic considerations demonstrated in this study allow for the rational design of oxygen carriers in the future. Modifications of reactors to capitalise on this new material are discussed.Dr Matthew T. Dunstan is acknowledged for help with the XRD analysis. M.S.C.C acknowledges financial support from an EPSRC Doctoral Training Grant. W.L and Y.Y acknowledge funding from the National Research Foundation (NRF), Prime Minister’s Office, Singapore under its Campus for Research Excellence and Technological Enterprise (CREATE) programme.This is the final version of the article. It first appeared from Elsevier via http://dx.doi.org/10.1016/j.cej.2016.03.13

Chemical looping epoxidation

Chemical looping epoxidation of ethylene was demonstrated, whereby the sole oxidant was a solid oxygen carrier, 15 wt% Ag supported on SrFeO3. Ethylene reacted with a bed of carrier particles, without any O2(g) in the feed, to produce ethylene oxide (EO) and CO2. Following the reduction by the C2H4 of the SrFeO3, it was regenerated by passing air through the bed. The rate of reoxidation was slow, with full regeneration being achieved only by prolonged oxidation at elevated temperatures. A striking synergy between Ag and SrFeO3 was observed solely when they were in intimate contact, suggesting a basis for a proposed reaction mechanism

No Black Hole Theorem in Three-Dimensional Gravity

A common property of known black hole solutions in (2+1)-dimensional gravity is that they require a negative cosmological constant. In this letter, it is shown that a (2+1)-dimensional gravity theory which satisfies the dominant energy condition forbids the existence of a black hole to explain the above situation.Comment: 3 pages, no figures, to be published in Physical Review Letter

Middle East respiratory syndrome coronavirus (MERS-CoV) in dromedary camels in Nigeria, 2015

Evidence of current and past Middle East respiratory syndrome coronavirus (MERS-CoV) infection in dromedary camels slaughtered at an abattoir in Kano, Nigeria in January 2015, was sought by reverse transcription-quantitative polymerase chain reaction (RT-qPCR) and serology. MERS-CoV RNA was detected in 14 (11%) of 132 nasal swabs and antibody in 126 (96%) of 131 serum samples. Phylogenetic analyses demonstrate that the viruses in Nigeria are genetically distinct from those reported in the Arabian peninsula.published_or_final_versio

Buttressing staples with cholecyst-derived extracellular matrix (CEM) reinforces staple lines in an ex vivo peristaltic inflation model

This is the author's accepted manuscript. The final published article is available from the link below. Copyright @ Springer Science + Business Media, LLC 2008Background - Staple line leakage and bleeding are the most common problems associated with the use of surgical staplers for gastrointestinal resection and anastomotic procedures. These complications can be reduced by reinforcing the staple lines with buttressing materials. The current study reports the potential use of cholecyst-derived extracellular matrix (CEM) in non-crosslinked (NCEM) and crosslinked (XCEM) forms, and compares their mechanical performance with clinically available buttress materials [small intestinal submucosa (SIS) and bovine pericardium (BP)] in an ex vivo small intestine model. Methods - Three crosslinked CEM variants (XCEM0005, XCEM001, and XCEM0033) with different degree of crosslinking were produced. An ex vivo peristaltic inflation model was established. Porcine small intestine segments were stapled on one end, using buttressed or non-buttressed surgical staplers. The opened, non-stapled ends were connected to a peristaltic pump and pressure transducer and sealed. The staple lines were then exposed to increased intraluminal pressure in a peristaltic manner. Both the leak and burst pressures of the test specimens were recorded. Results - The leak pressures observed for non-crosslinked NCEM (137.8 ± 22.3 mmHg), crosslinked XCEM0005 (109.1 ± 14.1 mmHg), XCEM001 (150.1 ± 16.0 mmHg), XCEM0033 (98.8 ± 10.5 mmHg) reinforced staple lines were significantly higher when compared to non-buttressed control (28.3 ± 10.8 mmHg) and SIS (one and four layers) (62.6 ± 11.8 and 57.6 ± 12.3 mmHg, respectively) buttressed staple lines. NCEM and XCEM were comparable to that observed for BP buttressed staple lines (138.8 ± 3.6 mmHg). Only specimens with reinforced staple lines were able to achieve high intraluminal pressures (ruptured at the intestinal mesentery), indicating that buttress reinforcements were able to withstand pressure higher than that of natural tissue (physiological failure). Conclusions - These findings suggest that the use of CEM and XCEM as buttressing materials is associated with reinforced staple lines and increased leak pressures when compared to non-buttressed staple lines. CEM and XCEM were found to perform comparably with clinically available buttress materials in this ex vivo model.Enterprise Irelan

Modifications of the BTZ black hole by a dilaton/scalar

We investigate some modifications of the static BTZ black hole solution due to a chosen asymptotically constant dilaton/scalar. New classes of static black hole solutions are obtained. One of the solutions contains the Martinez-Zanelli conformal black hole solution as a special case. Using quasilocal formalism, we calculate their mass for a finite spatial region that contains the black hole. Their temperatures are also computed. Finally, using some of the curvature singularities as examples, we investigate whether a quantum particle behaves singularly or not.Comment: 18 pages, Latex, in press in Phys. Rev.

A systematic review of current knowledge of HIV epidemiology and of sexual behaviour in Nepal

OBJECTIVE: To systematically review information on HIV epidemiology and on sexual behaviour in Nepal with a view to identifying gaps in current knowledge. METHODS: Systematic review covering electronic databases, web-based information, personal contact with experts and hand searching of key journals. RESULTS: HIV-1 seroprevalence has been rising rapidly in association with high-risk behaviours, with current levels of 40% amongst the nation's injecting drug users and approaching 20% amongst Kathmandu's female commercial sex workers (FCSWs). HIV seroprevalence remains low in the general population (0.29% of 15–49 year olds). There are significant methodological limitations in many of the seroprevalence studies identified, and these estimates need to be treated with caution. There are extensive migration patterns both within the country and internationally which provide the potential for considerable sexual networking. However, studies of sexual behaviour have focused on FCSWs and the extent of sexual networks within the general population is largely unknown. CONCLUSIONS: Whilst some of the ingredients are present for an explosive HIV epidemic in Nepal, crucial knowledge on sexual behaviour in the general population is missing. Research on sexual networking is urgently required to guide HIV control in Nepal. There is also a need for further good-quality epidemiological studies of HIV seroprevalence

Prediction of lethal and synthetically lethal knock-outs in regulatory networks

The complex interactions involved in regulation of a cell's function are captured by its interaction graph. More often than not, detailed knowledge about enhancing or suppressive regulatory influences and cooperative effects is lacking and merely the presence or absence of directed interactions is known. Here we investigate to which extent such reduced information allows to forecast the effect of a knock-out or a combination of knock-outs. Specifically we ask in how far the lethality of eliminating nodes may be predicted by their network centrality, such as degree and betweenness, without knowing the function of the system. The function is taken as the ability to reproduce a fixed point under a discrete Boolean dynamics. We investigate two types of stochastically generated networks: fully random networks and structures grown with a mechanism of node duplication and subsequent divergence of interactions. On all networks we find that the out-degree is a good predictor of the lethality of a single node knock-out. For knock-outs of node pairs, the fraction of successors shared between the two knocked-out nodes (out-overlap) is a good predictor of synthetic lethality. Out-degree and out-overlap are locally defined and computationally simple centrality measures that provide a predictive power close to the optimal predictor.Comment: published version, 10 pages, 6 figures, 2 tables; supplement at http://www.bioinf.uni-leipzig.de/publications/supplements/11-01